Organic electroluminescent materials and devices

ABSTRACT

A compound having the formula:Formula I is disclosed. The compound is useful as emitters in OLEDs.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation application of copending U.S. patent application Ser. No. 15/918,179, filed Mar. 12, 2018, which claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Application No. 62/479,730, filed Mar. 31, 2017 and U.S. Provisional Application No. 62/478,072, filed Mar. 29, 2017, the entire contents of which are incorporated herein by reference.

FIELD

The present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.

BACKGROUND

Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.

OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.

One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs. The white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.

One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)₃, which has the following structure:

In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.

As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.

As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.

As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.

More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.

SUMMARY

A compound having the formula:

Formula I is disclosed. In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution. X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, alyloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. Any substitutions are optionally joined or fused into a ring. n is 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof. R has at least five carbon atoms.

An OLED is also disclosed, where the OLED comprises: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:

Formula I. In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution. X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. Any substitutions are optionally joined or fused into a ring. n is 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof. R has at least five carbon atoms.

A consumer product comprising the OLED is also disclosed.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.

FIG. 3 is a diagram showing how the substituent R group in the inventive compound aligns with the transition dipolar moment of the metallated complex.

DETAILED DESCRIPTION

Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.

The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.

More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.

FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.

More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2 .

Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2 . For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.

Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.

Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. A consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.

The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.

The term “halo,” “halogen,” or “halide” as used herein includes fluorine, chlorine, bromine, and iodine.

The term “alkyl” as used herein contemplates both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group may be optionally substituted.

The term “cycloalkyl” as used herein contemplates cyclic alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 10 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.

The term “alkenyl” as used herein contemplates both straight and branched chain alkene radicals. Preferred alkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl group may be optionally substituted.

The term “alkynyl” as used herein contemplates both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.

The terms “aralkyl” or “arylalkyl” as used herein are used interchangeably and contemplate an alkyl group that has as a substituent an aromatic group. Additionally, the aralkyl group may be optionally substituted.

The term “heterocyclic group” as used herein contemplates aromatic and non-aromatic cyclic radicals. Hetero-aromatic cyclic radicals also means heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers, such as tetrahydrofuran, tetrahydropyran, and the like. Additionally, the heterocyclic group may be optionally substituted.

The term “aryl” or “aromatic group” as used herein contemplates single-ring groups and polycyclic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is aromatic, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, pelylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.

The term “heteroaryl” as used herein contemplates single-ring hetero-aromatic groups that may include from one to five heteroatoms. The term heteroaryl also includes polycyclic hetero-aromatic systems having two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocalbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted.

The alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl may be unsubstituted or may be substituted with one or more substituents selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, cyclic amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

As used herein, “substituted” indicates that a substituent other than H is bonded to the relevant position, such as carbon. Thus, for example, where R¹ is mono-substituted, then one R¹ must be other than H. Similarly, where R¹ is di-substituted, then two of R¹ must be other than H. Similarly, where R¹ is unsubstituted, R¹ is hydrogen for all available positions. The maximum number of substitutions possible in a structure will depend on the number of atoms with available valencies.

The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective fragment can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.

It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.

Disclosed herein are novel polycyclic substituents. Phosphorescent emitters with these substituents show higher external quantum efficiency (EQE) in devices. In the field of organic chemistry, a polycyclic compound is an organic chemical featuring several closed rings of atoms, primarily carbon. These ring substructures comprise cycloalkanes, aromatics, and other ring types. They come in sizes of three atoms and upward, and in combinations of linkages that include tethering (such as in bialy's), fusing (edge-to-edge, such as in anthracene and steroids), links via a single atom (such as in spiro compounds), and bridged cyclics such as adamantane. The term “polycyclic” is used in this disclosure to include rings including many rings as well as structures such as bicyclic, tricyclic, and tetracyclic.

According to an aspect of the present disclosure, heteroleptic tris-cyclometalated Iridium (III) complexes that has a high efficiency in OLED device are disclosed.

A compound is disclosed having the formula [L_(A)]_(3-n)Ir[L_(B)]_(n), having the structure:

Formula I. In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution. X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″. Each of R′, R″, R¹, R², R³, R⁴, and R⁵ is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, alyloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. Any substitutions are optionally joined or fused into a ring. n is 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof. R has at least five carbon atoms.

In some embodiments, each of R′, R″, R¹, R², R³, R⁴, and R⁵ is independently selected from the group consisting of hydrogen, deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, and combinations thereof.

In some embodiments, R has at least six carbon atoms. In some embodiments, R has at least seven carbon atoms.

In some embodiments, n is 2. In some embodiments, X is O.

In some embodiments, R comprises a cycloalkyl or heterocycloalkyl. In some embodiments, R¹, R², R³, R⁴, and R⁵ are each independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, aryl, and combinations thereof.

In some embodiments, R is selected from the group consisting of:

In some embodiments of the compound, the compound is selected from the group consisting

wherein R⁶ is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In some embodiments of the compound, L_(A) is selected from the group consisting of L_(A1) to L_(A371) having a structure according to

in which R, R¹, R^(A), R^(B), R^(E), R^(D), and R^(E) are defined as provided below:

L_(Ai), where i is R¹ R R^(A) R^(B) R^(C) R^(D) R^(E) 1. H R^(A1) H H H H H 2. H R^(A2) H H H H H 3. H R^(A3) H H H H H 4. H R^(A4) H H H H H 5. H R^(A5) H H H H H 6. H R^(A6) H H H H H 7. H R^(A7) H H H H H 8. H R^(A8) H H H H H 9. H R^(A9) H H H H H 10. H R^(A10) H H H H H 11. H R^(A11) H H H H H 12. H R^(A12) H H H H H 13. H R^(A13) H H H H H 14. H R^(A14) H H H H H 15. H R^(A15) H H H H H 16. H R^(A16) H H H H H 17. H R^(A17) H H H H H 18. H R^(A18) H H H H H 19. H R^(A19) H H H H H 20. H R^(A20) H H H H H 21. H R^(A21) H H H H H 22. H R^(A22) H H H H H 23. H R^(A23) H H H H H 24. H R^(A24) H H H H H 25. H R^(A25) H H H H H 26. H R^(A26) H H H H H 27. H R^(A27) H H H H H 28. H R^(A28) H H H H H 29. H R^(A29) H H H H H 30. H R^(A30) H H H H H 31. H R^(A31) H H H H H 32. H R^(A32) H H H H H 33. H R^(A33) H H H H H 34. H R^(A34) H H H H H 35. H R^(A35) H H H H H 36. H R^(A36) H H H H H 37. H R^(A37) H H H H H 38. H R^(A38) H H H H H 39. H R^(A39) H H H H H 40. H R^(A40) H H H H H 41. H R^(A41) H H H H H 42. H R^(A42) H H H H H 43. H R^(A43) H H H H H 44. H R^(A44) H H H H H 45. H R^(A45) H H H H H 46. H R^(A46) H H H H H 47. H R^(A47) H H H H H 48. H R^(A48) H H H H H 49. H R^(A49) H H H H H 50. H R^(A50) H H H H H 51. H R^(A51) H H H H H 52. H R^(A52) H H H H H 53. H R^(A53) H H H H H 54. H R^(A54) H H H H H 55. H R^(A55) H H H H H 56. H R^(A56) H H H H H 57. H R^(A57) H H H H H 58. H R^(A58) H H H H H 59. H R^(A59) H H H H H 60. H R^(A60) H H H H H 61. H R^(A61) H H H H H 62. H R^(A62) H H H H H 63. H R^(A63) H H H H H 64. H R^(A64) H H H H H 65. H R^(A65) H H H H H 66. H R^(A66) H H H H H 67. H R^(A67) H H H H H 68. H R^(A68) H H H H H 69. H R^(A69) H H H H H 70. H R^(A70) H H H H H 71. H R^(A71) H H H H H 72. H R^(A72) H H H H H 73. H R^(A73) H H H H H 74. H R^(A74) H H H H H 75. H R^(A75) H H H H H 76. H R^(A76) H H H H H 77. H R^(A77) H H H H H 78. H R^(A78) H H H H H 79. H R^(A79) H H H H H 80. H R^(A80) H H H H H 81. H R^(A81) H H H H H 82. H R^(A82) H H H H H 83. H R^(A83) H H H H H 84. H R^(A84) H H H H H 85. H R^(A85) H H H H H 86. H R^(A86) H H H H H 87. H R^(A87) H H H H H 88. H R^(A88) H H H H H 89. H R^(A89) H H H H H 90. H R^(A90) H H H H H 91. H R^(A91) H H H H H 92. H R^(A92) H H H H H 93. H R^(A93) H H H H H 94. CD₃ R^(A1) H H H H H 95. CD₃ R^(A2) H H H H H 96. CD₃ R^(A3) H H H H H 97. CD₃ R^(A4) H H H H H 98. CD₃ R^(A5) H H H H H 99. CD₃ R^(A6) H H H H H 100. CD₃ R^(A7) H H H H H 101. CD₃ R^(A8) H H H H H 102. CD₃ R^(A9) H H H H H 103. CD₃ R^(A10) H H H H H 104. CD₃ R^(A11) H H H H H 105. CD₃ R^(A12) H H H H H 106. CD₃ R^(A13) H H H H H 107. CD₃ R^(A14) H H H H H 108. CD₃ R^(A15) H H H H H 109. CD₃ R^(A16) H H H H H 110. CD₃ R^(A17) H H H H H 111. CD₃ R^(A18) H H H H H 112. CD₃ R^(A19) H H H H H 113. CD₃ R^(A20) H H H H H 114. CD₃ R^(A21) H H H H H 115. CD₃ R^(A22) H H H H H 116. CD₃ R^(A23) H H H H H 117. CD₃ R^(A24) H H H H H 118. CD₃ R^(A25) H H H H H 119. CD₃ R^(A26) H H H H H 120. CD₃ R^(A27) H H H H H 121. CD₃ R^(A28) H H H H H 122. CD₃ R^(A29) H H H H H 123. CD₃ R^(A30) H H H H H 124. CD₃ R^(A31) H H H H H 125. CD₃ R^(A32) H H H H H 126. CD₃ R^(A33) H H H H H 127. CD₃ R^(A34) H H H H H 128. CD₃ R^(A35) H H H H H 129. CD₃ R^(A36) H H H H H 130. CD₃ R^(A37) H H H H H 131. CD₃ R^(A38) H H H H H 132. CD₃ R^(A39) H H H H H 133. CD₃ R^(A40) H H H H H 134. CD₃ R^(A41) H H H H H 135. CD₃ R^(A42) H H H H H 136. CD₃ R^(A43) H H H H H 137. CD₃ R^(A44) H H H H H 138. CD₃ R^(A45) H H H H H 139. CD₃ R^(A46) H H H H H 140. CD₃ R^(A47) H H H H H 141. CD₃ R^(A48) H H H H H 142. CD₃ R^(A49) H H H H H 143. CD₃ R^(A50) H H H H H 144. CD₃ R^(A51) H H H H H 145. CD₃ R^(A52) H H H H H 146. CD₃ R^(A53) H H H H H 147. CD₃ R^(A54) H H H H H 148. CD₃ R^(A55) H H H H H 149. CD₃ R^(A56) H H H H H 150. CD₃ R^(A57) H H H H H 151. CD₃ R^(A58) H H H H H 152. CD₃ R^(A59) H H H H H 153. CD₃ R^(A60) H H H H H 154. CD₃ R^(A61) H H H H H 155. CD₃ R^(A62) H H H H H 156. CD₃ R^(A63) H H H H H 157. CD₃ R^(A64) H H H H H 158. CD₃ R^(A65) H H H H H 159. CD₃ R^(A66) H H H H H 160. CD₃ R^(A67) H H H H H 161. CD₃ R^(A68) H H H H H 162. CD₃ R^(A69) H H H H H 163. CD₃ R^(A70) H H H H H 164. CD₃ R^(A71) H H H H H 165. CD₃ R^(A72) H H H H H 166. CD₃ R^(A73) H H H H H 167. CD₃ R^(A74) H H H H H 168. CD₃ R^(A75) H H H H H 169. CD₃ R^(A76) H H H H H 170. CD₃ R^(A77) H H H H H 171. CD₃ R^(A78) H H H H H 172. CD₃ R^(A79) H H H H H 173. CD₃ R^(A80) H H H H H 174. CD₃ R^(A81) H H H H H 175. CD₃ R^(A82) H H H H H 176. CD₃ R^(A83) H H H H H 177. CD₃ R^(A84) H H H H H 178. CD₃ R^(A85) H H H H H 179. CD₃ R^(A86) H H H H H 180. CD₃ R^(A87) H H H H H 181. CD₃ R^(A88) H H H H H 182. CD₃ R^(A89) H H H H H 183. CD₃ R^(A90) H H H H H 184. CD₃ R^(A91) H H H H H 185. CD₃ R^(A92) H H H H H 186. CD₃ R^(A93) H H H H H 187. H R^(A1) H CD₃ H H H 188. H R^(A2) H CD₃ H H H 189. H R^(A3) H CD₃ H H H 190. H R^(A4) H CD₃ H H H 191. H R^(A5) H CD₃ H H H 192. H R^(A6) H CD₃ H H H 193. H R^(A7) H CD₃ H H H 194. H R^(A8) H CD₃ H H H 195. H R^(A10) H CD₃ H H H 196. H R^(A11) H CD₃ H H H 197. H R^(A12) H CD₃ H H H 198. H R^(A13) H CD₃ H H H 199. H R^(A14) H CD₃ H H H 200. H R^(A15) H CD₃ H H H 201. H R^(A16) H CD₃ H H H 202. H R^(A17) H CD₃ H H H 203. H R^(A18) H CD₃ H H H 204. H R^(A19) H CD₃ H H H 205. H R^(A20) H CD₃ H H H 206. H R^(A21) H CD₃ H H H 207. H R^(A22) H CD₃ H H H 208. H R^(A23) H CD₃ H H H 209. H R^(A24) H CD₃ H H H 210. H R^(A25) H CD₃ H H H 211. H R^(A26) H CD₃ H H H 212. H R^(A27) H CD₃ H H H 213. H R^(A28) H CD₃ H H H 214. H R^(A29) H CD₃ H H H 215. H R^(A30) H CD₃ H H H 216. H R^(A31) H CD₃ H H H 217. H R^(A32) H CD₃ H H H 218. H R^(A33) H CD₃ H H H 219. H R^(A34) H CD₃ H H H 220. H R^(A35) H CD₃ H H H 221. H R^(A36) H CD₃ H H H 222. H R^(A37) H CD₃ H H H 223. H R^(A38) H CD₃ H H H 224. H R^(A39) H CD₃ H H H 225. H R^(A40) H CD₃ H H H 226. H R^(A41) H CD₃ H H H 227. H R^(A42) H CD₃ H H H 228. H R^(A43) H CD₃ H H H 229. H R^(A44) H CD₃ H H H 230. H R^(A45) H CD₃ H H H 231. H R^(A46) H CD₃ H H H 232. H R^(A47) H CD₃ H H H 233. H R^(A48) H CD₃ H H H 234. H R^(A49) H CD₃ H H H 235. H R^(A50) H CD₃ H H H 236. H R^(A51) H CD₃ H H H 237. H R^(A52) H CD₃ H H H 238. H R^(A53) H CD₃ H H H 239. H R^(A54) H CD₃ H H H 240. H R^(A55) H CD₃ H H H 241. H R^(A56) H CD₃ H H H 242. H R^(A57) H CD₃ H H H 243. H R^(A58) H CD₃ H H H 244. H R^(A59) H CD₃ H H H 245. H R^(A60) H CD₃ H H H 246. H R^(A61) H CD₃ H H H 247. H R^(A62) H CD₃ H H H 248. H R^(A63) H CD₃ H H H 249. H R^(A64) H CD₃ H H H 250. H R^(A65) H CD₃ H H H 251. H R^(A66) H CD₃ H H H 252. H R^(A67) H CD₃ H H H 253. H R^(A68) H CD₃ H H H 254. H R^(A69) H CD₃ H H H 255. H R^(A70) H CD₃ H H H 256. H R^(A71) H CD₃ H H H 257. H R^(A72) H CD₃ H H H 258. H R^(A73) H CD₃ H H H 259. H R^(A74) H CD₃ H H H 260. H R^(A75) H CD₃ H H H 261. H R^(A76) H CD₃ H H H 262. H R^(A77) H CD₃ H H H 263. H R^(A78) H CD₃ H H H 264. H R^(A79) H CD₃ H H H 265. H R^(A80) H CD₃ H H H 266. H R^(A81) H CD₃ H H H 267. H R^(A82) H CD₃ H H H 268. H R^(A83) H CD₃ H H H 269. H R^(A84) H CD₃ H H H 270. H R^(A85) H CD₃ H H H 271. H R^(A86) H CD₃ H H H 272. H R^(A87) H CD₃ H H H 273. H R^(A88) H CD₃ H H H 274. H R^(A89) H CD₃ H H H 275. H R^(A90) H CD₃ H H H 276. H R^(A91) H CD₃ H H H 277. H R^(A92) H CD₃ H H H 278. H R^(A93) H CD₃ H H H 279. CD₃ R^(A1) H CD₃ H H H 280. CD₃ R^(A2) H CD₃ H H H 281. CD₃ R^(A3) H CD₃ H H H 282. CD₃ R^(A4) H CD₃ H H H 283. CD₃ R^(A5) H CD₃ H H H 284. CD₃ R^(A6) H CD₃ H H H 285. CD₃ R^(A7) H CD₃ H H H 286. CD₃ R^(A8) H CD₃ H H H 287. CD₃ R^(A9) H CD₃ H H H 288. CD₃ R^(A10) H CD₃ H H H 289. CD₃ R^(A11) H CD₃ H H H 290. CD₃ R^(A12) H CD₃ H H H 291. CD₃ R^(A13) H CD₃ H H H 292. CD₃ R^(A14) H CD₃ H H H 293. CD₃ R^(A15) H CD₃ H H H 294. CD₃ R^(A16) H CD₃ H H H 295. CD₃ R^(A17) H CD₃ H H H 296. CD₃ R^(A18) H CD₃ H H H 297. CD₃ R^(A19) H CD₃ H H H 298. CD₃ R^(A20) H CD₃ H H H 299. CD₃ R^(A21) H CD₃ H H H 300. CD₃ R^(A22) H CD₃ H H H 301. CD₃ R^(A23) H CD₃ H H H 302. CD₃ R^(A24) H CD₃ H H H 303. CD₃ R^(A25) H CD₃ H H H 304. CD₃ R^(A26) H CD₃ H H H 305. CD₃ R^(A27) H CD₃ H H H 306. CD₃ R^(A28) H CD₃ H H H 307. CD₃ R^(A29) H CD₃ H H H 308. CD₃ R^(A30) H CD₃ H H H 309. CD₃ R^(A31) H CD₃ H H H 310. CD₃ R^(A32) H CD₃ H H H 311. CD₃ R^(A33) H CD₃ H H H 312. CD₃ R^(A34) H CD₃ H H H 313. CD₃ R^(A35) H CD₃ H H H 314. CD₃ R^(A36) H CD₃ H H H 315. CD₃ R^(A37) H CD₃ H H H 316. CD₃ R^(A38) H CD₃ H H H 317. CD₃ R^(A39) H CD₃ H H H 318. CD₃ R^(A40) H CD₃ H H H 319. CD₃ R^(A41) H CD₃ H H H 320. CD₃ R^(A42) H CD₃ H H H 321. CD₃ R^(A43) H CD₃ H H H 322. CD₃ R^(A44) H CD₃ H H H 323. CD₃ R^(A45) H CD₃ H H H 324. CD₃ R^(A46) H CD₃ H H H 325. CD₃ R^(A47) H CD₃ H H H 326. CD₃ R^(A48) H CD₃ H H H 327. CD₃ R^(A49) H CD₃ H H H 328. CD₃ R^(A50) H CD₃ H H H 329. CD₃ R^(A51) H CD₃ H H H 330. CD₃ R^(A52) H CD₃ H H H 331. CD₃ R^(A53) H CD₃ H H H 332. CD₃ R^(A54) H CD₃ H H H 333. CD₃ R^(A55) H CD₃ H H H 334. CD₃ R^(A56) H CD₃ H H H 335. CD₃ R^(A57) H CD₃ H H H 336. CD₃ R^(A58) H CD₃ H H H 337. CD₃ R^(A59) H CD₃ H H H 338. CD₃ R^(A60) H CD₃ H H H 339. CD₃ R^(A61) H CD₃ H H H 340. CD₃ R^(A62) H CD₃ H H H 341. CD₃ R^(A63) H CD₃ H H H 342. CD₃ R^(A64) H CD₃ H H H 343. CD₃ R^(A65) H CD₃ H H H 344. CD₃ R^(A66) H CD₃ H H H 345. CD₃ R^(A67) H CD₃ H H H 346. CD₃ R^(A68) H CD₃ H H H 347. CD₃ R^(A69) H CD₃ H H H 348. CD₃ R^(A70) H CD₃ H H H 349. CD₃ R^(A71) H CD₃ H H H 350. CD₃ R^(A72) H CD₃ H H H 351. CD₃ R^(A73) H CD₃ H H H 352. CD₃ R^(A74) H CD₃ H H H 353. CD₃ R^(A75) H CD₃ H H H 354. CD₃ R^(A76) H CD₃ H H H 355. CD₃ R^(A77) H CD₃ H H H 356. CD₃ R^(A78) H CD₃ H H H 357. CD₃ R^(A79) H CD₃ H H H 358. CD₃ R^(A80) H CD₃ H H H 359. CD₃ R^(A81) H CD₃ H H H 360. CD₃ R^(A82) H CD₃ H H H 361. CD₃ R^(A83) H CD₃ H H H 362. CD₃ R^(A84) H CD₃ H H H 363. CD₃ R^(A85) H CD₃ H H H 364. CD₃ R^(A86) H CD₃ H H H 365. CD₃ R^(A87) H CD₃ H H H 366. CD₃ R^(A88) H CD₃ H H H 367. CD₃ R^(A89) H CD₃ H H H 368. CD₃ R^(A90) H CD₃ H H H 369. CD₃ R^(A91) H CD₃ H H H 370. CD₃ R^(A92) H CD₃ H H H 371. CD₃ R^(A93) H CD₃ H H H

In some embodiments of the compound, L_(B) is selected from the group consisting of L_(B1) to L_(B1471) having a structure according to

wherein R_(B1), R^(B2), R^(B3), and R^(B4) are defined as provided below:

L_(Bi), where i is R^(B1) R^(B2) R^(B3) R^(B4) 1. H H H H 2. CH₃ H H H 3. H CH₃ H H 4. H H CH₃ H 5. CH₃ CH₃ H CH₃ 6. CH₃ H CH₃ H 7. CH₃ H H CH₃ 8. H CH₃ CH₃ H 9. H CH₃ H CH₃ 10. H H CH₃ CH₃ 11. CH₃ CH₃ CH₃ H 12. CH₃ CH₃ H CH₃ 13. CH₃ H CH₃ CH₃ 14. H CH₃ CH₃ CH₃ 15. CH₃ CH₃ CH₃ CH₃ 16. CH₂CH₃ H H H 17. CH₂CH₃ CH₃ H CH₃ 18. CH₂CH₃ H CH₃ H 19. CH₂CH₃ H H CH₃ 20. CH₂CH₃ CH₃ CH₃ H 21. CH₂CH₃ CH₃ H CH₃ 22. CH₂CH₃ H CH₃ CH₃ 23. CH₂CH₃ CH₃ CH₃ CH₃ 24. H CH₂CH₃ H H 25. CH₃ CH₂CH₃ H CH₃ 26. H CH₂CH₃ CH₃ H 27. H CH₂CH₃ H CH₃ 28. CH₃ CH₂CH₃ CH₃ H 29. CH₃ CH₂CH₃ H CH₃ 30. H CH₂CH₃ CH₃ CH₃ 31. CH₃ CH₂CH₃ CH₃ CH₃ 32. H H CH₂CH₃ H 33. CH₃ H CH₂CH₃ H 34. H CH₃ CH₂CH₃ H 35. H H CH₂CH₃ CH₃ 36. CH₃ CH₃ CH₂CH₃ H 37. CH₃ H CH₂CH₃ CH₃ 38. H CH₃ CH₂CH₃ CH₃ 39. CH₃ CH₃ CH₂CH₃ CH₃ 40. CH(CH₃)₂ H H H 41. CH(CH₃)₂ CH₃ H CH₃ 42. CH(CH₃)₂ H CH₃ H 43. CH(CH₃)₂ H H CH₃ 44. CH(CH₃)₂ CH₃ CH₃ H 45. CH(CH₃)₂ CH₃ H CH₃ 46. CH(CH₃)₂ H CH₃ CH₃ 47. CH(CH₃)₂ CH₃ CH₃ CH₃ 48. H CH(CH₃)₂ H H 49. CH₃ CH(CH₃)₂ H CH₃ 50. H CH(CH₃)₂ CH₃ H 51. H CH(CH₃)₂ H CH₃ 52. CH₃ CH(CH₃)₂ CH₃ H 53. CH₃ CH(CH₃)₂ H CH₃ 54. H CH(CH₃)₂ CH₃ CH₃ 55. CH₃ CH(CH₃)₂ CH₃ CH₃ 56. H H CH(CH₃)₂ H 57. CH₃ H CH(CH₃)₂ H 58. H CH₃ CH(CH₃)₂ H 59. H H CH(CH₃)₂ CH₃ 60. CH₃ CH₃ CH(CH₃)₂ H 61. CH₃ H CH(CH₃)₂ CH₃ 62. H CH₃ CH(CH₃)₂ CH₃ 63. CH₃ CH₃ CH(CH₃)₂ CH₃ 64. CH₂CH(CH₃)₂ H H H 65. CH₂CH(CH₃)₂ CH₃ H CH₃ 66. CH₂CH(CH₃)₂ H CH₃ H 67. CH₂CH(CH₃)₂ H H CH₃ 68. CH₂CH(CH₃)₂ CH₃ CH₃ H 69. CH₂CH(CH₃)₂ CH₃ H CH₃ 70. CH₂CH(CH₃)₂ H CH₃ CH₃ 71. CH₂CH(CH₃)₂ CH₃ CH₃ CH₃ 72. H CH₂CH(CH₃)₂ H H 73. CH₃ CH₂CH(CH₃)₂ H CH₃ 74. H CH₂CH(CH₃)₂ CH₃ H 75. H CH₂CH(CH₃)₂ H CH₃ 76. CH₃ CH₂CH(CH₃)₂ CH₃ H 77. CH₃ CH₂CH(CH₃)₂ H CH₃ 78. H CH₂CH(CH₃)₂ CH₃ CH₃ 79. CH₃ CH₂CH(CH₃)₂ CH₃ CH₃ 80. H H CH₂CH(CH₃)₂ H 81. CH₃ H CH₂CH(CH₃)₂ H 82. H CH₃ CH₂CH(CH₃)₂ H 83. H H CH₂CH(CH₃)₂ CH₃ 84. CH₃ CH₃ CH₂CH(CH₃)₂ H 85. CH₃ H CH₂CH(CH₃)₂ CH₃ 86. H CH₃ CH₂CH(CH₃)₂ CH₃ 87. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃ 88. C(CH₃)₃ H H H 89. C(CH₃)₃ CH₃ H CH₃ 90. C(CH₃)₃ H CH₃ H 91. C(CH₃)₃ H H CH₃ 92. C(CH₃)₃ CH₃ CH₃ H 93. C(CH₃)₃ CH₃ H CH₃ 94. C(CH₃)₃ H CH₃ CH₃ 95. C(CH₃)₃ CH₃ CH₃ CH₃ 96. H C(CH₃)₃ H H 97. CH₃ C(CH₃)₃ H CH₃ 98. H C(CH₃)₃ CH₃ H 99. H C(CH₃)₃ H CH₃ 100. CH₃ C(CH₃)₃ CH₃ H 101. CH₃ C(CH₃)₃ H CH₃ 102. H C(CH₃)₃ CH₃ CH₃ 103. CH₃ C(CH₃)₃ CH₃ CH₃ 104. H H C(CH₃)₃ H 105. CH₃ H C(CH₃)₃ H 106. H CH₃ C(CH₃)₃ H 107. H H C(CH₃)₃ CH₃ 108. CH₃ CH₃ C(CH₃)₃ H 109. CH₃ H C(CH₃)₃ CH₃ 110. H CH₃ C(CH₃)₃ CH₃ 111. CH₃ CH₃ C(CH₃)₃ CH₃ 112. CH₂C(CH₃)₃ H H H 113. CH₂C(CH₃)₃ CH₃ H CH₃ 114. CH₂C(CH₃)₃ H CH₃ H 115. CH₂C(CH₃)₃ H H CH₃ 116. CH₂C(CH₃)₃ CH₃ CH₃ H 117. CH₂C(CH₃)₃ CH₃ H CH₃ 118. CH₂C(CH₃)₃ H CH₃ CH₃ 119. CH₂C(CH₃)₃ CH₃ CH₃ CH₃ 120. H CH₂C(CH₃)₃ H H 121. CH₃ CH₂C(CH₃)₃ H CH₃ 122. H CH₂C(CH₃)₃ CH₃ H 123. H CH₂C(CH₃)₃ H CH₃ 124. CH₃ CH₂C(CH₃)₃ CH₃ H 125. CH₃ CH₂C(CH₃)₃ H CH₃ 126. H CH₂C(CH₃)₃ CH₃ CH₃ 127. CH₃ CH₂C(CH₃)₃ CH₃ CH₃ 128. H H CH₂C(CH₃)₃ H 129. CH₃ H CH₂C(CH₃)₃ H 130. H CH₃ CH₂C(CH₃)₃ H 131. H H CH₂C(CH₃)₃ CH₃ 132. CH₃ CH₃ CH₂C(CH₃)₃ H 133. CH₃ H CH₂C(CH₃)₃ CH₃ 134. H CH₃ CH₂C(CH₃)₃ CH₃ 135. CH₃ CH₃ CH₂C(CH₃)₃ CH₃ 136.

H H H 137.

CH₃ H CH₃ 138.

H CH₃ H 139.

H H CH₃ 140.

CH₃ CH₃ H 141.

CH₃ H CH₃ 142.

H CH₃ CH₃ 143.

CH₃ CH₃ CH₃ 144. H

H H 145. CH₃

H CH₃ 146. H

CH₃ H 147. H

H CH₃ 148. CH₃

CH₃ H 149. CH₃

H CH₃ 150. H

CH₃ CH₃ 151. CH₃

CH₃ CH₃ 152. H H

H 153. CH₃ H

H 154. H CH₃

H 155. H H

CH₃ 156. CH₃ CH₃

H 157. CH₃ H

CH₃ 158. H CH₃

CH₃ 159. CH₃ CH₃

CH₃ 160.

H H H 161.

CH₃ H CH₃ 162.

H CH₃ H 163.

H H CH₃ 164.

CH₃ CH₃ H 165.

CH₃ H CH₃ 166.

H CH₃ CH₃ 167.

CH₃ CH₃ CH₃ 168. H

H H 169. CH₃

H CH₃ 170. H

CH₃ H 171. H

H CH₃ 172. CH₃

CH₃ H 173. CH₃

H CH₃ 174. H

CH₃ CH₃ 175. CH₃

CH₃ CH₃ 176. H H

H 177. CH₃ H

H 178. H CH₃

H 179. H H

CH 180. CH₃ CH₃

H 181. CH₃ H

CH₃ 182. H CH₃

CH₃ 183. CH₃ CH₃

CH₃ 184.

H H H 185.

CH₃ H CH₃ 186.

H CH₃ H 187.

H H CH₃ 188.

CH₃ CH₃ H 189.

CH₃ H CH₃ 190.

H CH₃ CH₃ 191.

CH₃ CH₃ CH₃ 192. H

H H 193. CH₃

H CH₃ 194. H

CH₃ H 195. H

H CH₃ 196. CH₃

CH₃ H 197. CH₃

H CH₃ 198. H

CH₃ CH₃ 199. CH₃

CH₃ CH₃ 200. H H

H 201. CH₃ H

H 202. H CH₃

H 203. H H

CH₃ 204. CH₃ CH₃

H 205. CH₃ H

CH₃ 206. H CH₃

CH₃ 207. CH₃ CH₃

CH₃ 208.

H H H 209.

CH₃ H CH₃ 210.

H CH₃ H 211.

H H CH₃ 212.

CH₃ CH₃ H 213.

CH₃ H CH₃ 214.

H CH₃ CH₃ 215.

CH₃ CH₃ CH₃ 216. H

H H 217. CH₃

H CH₃ 218. H

CH₃ H 219. H

H CH₃ 220. CH₃

CH₃ H 221. CH₃

H CH₃ 222. H

CH₃ CH₃ 223. CH₃

CH₃ CH₃ 224. H H

H 225. CH₃ H

H 226. H CH₃

H 227. H H

CH₃ 228. CH₃ CH₃

H 229. CH₃ H

CH₃ 230. H CH₃

CH₃ 231. CH₃ CH₃

CH₃ 232.

H H H 233.

CH₃ H CH₃ 234.

H CH₃ H 235.

H H CH₃ 236.

CH₃ CH₃ H 237.

CH₃ H CH₃ 238.

H CH₃ CH₃ 239.

CH₃ CH₃ CH₃ 240. H

H H 241. CH₃

H CH₃ 242. H

CH₃ H 243. H

H CH₃ 244. CH₃

CH₃ H 245. CH₃

H CH₃ 246. H

CH₃ CH₃ 247. CH₃

CH₃ CH₃ 248. H H

H 249. CH₃ H

H 250. H CH₃

H 251. H H

CH₃ 252. CH₃ CH₃

H 253. CH₃ H

CH₃ 254. H CH₃

CH₃ 255. CH₃ CH₃

CH₃ 256.

H H H 257.

CH₃ H CH₃ 258.

H CH₃ H 259.

H H CH₃ 260.

CH₃ CH₃ H 261.

CH₃ H CH₃ 262.

H CH₃ CH₃ 263.

CH₃ CH₃ CH₃ 264. H

H H 265. CH₃

H CH₃ 266. H

CH₃ H 267. H

H CH₃ 268. CH₃

CH₃ H 269. CH₃

H CH₃ 270. H

CH₃ CH₃ 271. CH₃

CH₃ CH₃ 272. H H

H 273. CH₃ H

H 274. H CH₃

H 275. H H

CH₃ 276. CH₃ CH₃

H 277. CH₃ H

CH₃ 278. H CH₃

CH₃ 279. CH₃ CH₃

CH₃ 280. CH(CH₃)₂ H CH₂CH₃ H 281. CH(CH₃)₂ H CH(CH₃)₂ H 282. CH(CH₃)₂ H CH₂CH(CH₃)₂ H 283. CH(CH₃)₂ H C(CH₃)₃ H 284. CH(CH₃)₂ H CH₂C(CH₃)₃ H 285. CH(CH₃)₂ H

H 286. CH(CH₃)₂ H

H 287. CH(CH₃)₂ H

H 288. CH(CH₃)₂ H

H 289. CH(CH₃)₂ H

H 290. CH(CH₃)₂ H

H 291. C(CH₃)₃ H CH₂CH₃ H 292. C(CH₃)₃ H CH(CH₃)₂ H 293. C(CH₃)₃ H CH₂CH(CH₃)₂ H 294. C(CH₃)₃ H C(CH₃)₃ H 295. C(CH₃)₃ H CH₂C(CH₃)₃ H 296. C(CH₃)₃ H

H 297. C(CH₃)₃ H

H 298. C(CH₃)₃ H

H 299. C(CH₃)₃ H

H 300. C(CH₃)₃ H

H 301. C(CH₃)₃ H

H 302. CH₂C(CH₃)₃ H CH₂CH₃ H 303. CH₂C(CH₃)₃ H CH(CH₃)₂ H 304. CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H 305. CH₂C(CH₃)₃ H C(CH₃)₃ H 306. CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H 307. CH₂C(CH₃)₃ H

H 308. CH₂C(CH₃)₃ H

H 309. CH₂C(CH₃)₃ H

H 310. CH₂C(CH₃)₃ H

H 311. CH₂C(CH₃)₃ H

H 312. CH₂C(CH₃)₃ H

H 313.

H CH₂CH₃ H 314.

H CH(CH₃)₂ H 315.

H CH₂CH(CH₃)₂ H 316.

H C(CH₃)₃ H 317.

H CH₂C(CH₃)₃ H 318.

H

H 319.

H

H 320.

H

H 321.

H

H 322.

H

H 323.

H

H 324.

H CH₂CH₃ H 325.

H CH(CH₃)₂ H 326.

H CH₂CH(CH₃)₂ H 327.

H C(HC₃)₃ H 328.

H CH₂C(CH₃)₃ H 329.

H

H 330.

H

H 331.

H

H 332.

H

H 333.

H

H 334.

H

H 335.

H CH₂CH(CH₃)₂ H 336.

H C(CH₃)₃ H 337.

H CH₂C(CH₃)₃ H 338.

H CH₂CH₂CF₃ H 339.

H CH₂C(CH₃)₂CF₃ H 340.

H

H 341.

H

H 342.

H

H 343.

H

H 344.

H

H 345.

H

H 346.

H CH₂CH(CH₃)₂ H 347.

H C(CH₃)₃ H 348.

H CH₂C(CH₃)₃ H 349.

H

H 350.

H

H 351.

H

H 352.

H

H 353.

H

H 354.

H

H 355.

H CH₂CH(CH₃)₂ H 356.

H C(CH₃)₃ H 357.

H CH₂C(CH₃)₃ H 358.

H

H 359.

H

H 360.

H

H 361.

H

H 362.

H

H 363.

H

H 364. H H H H 365. CD₃ H H H 366. H CD₃ H H 367. H H CD₃ H 368. CD₃ CD₃ H CD₃ 369. CD₃ H CD₃ H 370. CD₃ H H CD₃ 371. H CD₃ CH₃ H 372. H CD₃ H CD₃ 373. H H CD₃ CD₃ 374. CD₃ CD₃ CD₃ H 375. CD₃ CD₃ H CD₃ 376. CD₃ H CD₃ CD₃ 377. H CD₃ CD₃ CD₃ 378. CD₃ CD₃ CD₃ CD₃ 379. CD₂CH₃ H H H 380. CD₂CH₃ CD₃ H CD₃ 381. CD₂CH₃ H CD₃ H 382. CD₂CH₃ H H CD₃ 383. CD₂CH₃ CD₃ CD₃ H 384. CD₂CH₃ CD₃ H CD₃ 385. CD₂CH₃ H CD₃ CD₃ 386. CD₂CH₃ CD₃ CD₃ CD₃ 387. H CD₂CH₃ H H 388. CH₃ CD₂CH₃ H CD₃ 389. H CD₂CH₃ CD₃ H 390. H CD₂CH₃ H CD₃ 391. CD₃ CD₂CH₃ CD₃ H 392. CD₃ CD₂CH₃ H CD₃ 393. H CD₂CH₃ CD₃ CD₃ 394. CD₃ CD₂CH₃ CD₃ CD₃ 395. H H CD₂CH₃ H 396. CD₃ H CD₂CH₃ H 397. H CD₃ CD₂CH₃ H 398. H H CD₂CH₃ CD₃ 399. CD₃ CD₃ CD₂CH₃ H 400. CD₃ H CD₂CH₃ CD₃ 401. H CD₃ CD₂CH₃ CD₃ 402. CD₃ CD₃ CD₂CH₃ CD₃ 403. CD(CH₃)₂ H H H 404. CD(CH₃)₂ CD₃ H CD₃ 405. CD(CH₃)₂ H CD₃ H 406. CD(CH₃)₂ H H CD₃ 407. CD(CH₃)₂ CD₃ CD₃ H 408. CD(CH₃)₂ CD₃ H CD₃ 409. CD(CH₃)₂ H CD₃ CD₃ 410. CD(CH₃)₂ CD₃ CD₃ CD₃ 411. H CD(CH₃)₂ H H 412. CD₃ CD(CH₃)₂ H CD₃ 413. H CD(CH₃)₂ CD₃ H 414. H CD(CH₃)₂ H CD₃ 415. CD₃ CD(CH₃)₂ CD₃ H 416. CD₃ CD(CH₃)₂ H CD₃ 417. H CD(CH₃)₂ CD₃ CD₃ 418. CD₃ CD(CH₃)₂ CD₃ CD₃ 419. H H CD(CH₃)₂ H 420. CD₃ H CD(CH₃)₂ H 421. H CD₃ CD(CH₃)₂ H 422. H H CD(CH₃)₂ CD₃ 423. CD₃ CD₃ CD(CH₃)₂ H 424. CD₃ H CD(CH₃)₂ CD₃ 425. H CD₃ CD(CH₃)₂ CD₃ 426. CD₃ CD₃ CD(CH₃)₂ CD₃ 427. CD(CD₃)₂ H H H 428. CD(CD₃)₂ CD₃ H CD₃ 429. CD(CD₃)₂ H CD₃ H 430. CD(CD₃)₂ H H CD₃ 431. CD(CD₃)₂ CD₃ CD₃ H 432. CD(CD₃)₂ CD₃ H CD₃ 433. CD(CD₃)₂ H CD₃ CD₃ 434. CD(CD₃)₂ CD₃ CD₃ CD₃ 435. H CD(CD₃)₂ H H 436. CH₃ CD(CD₃)₂ H CD₃ 437. H CD(CD₃)₂ CD₃ H 438. H CD(CD₃)₂ H CD₃ 439. CD₃ CD(CD₃)₂ CD₃ H 440. CD₃ CD(CD₃)₂ H CD₃ 441. H CD(CD₃)₂ CD₃ CD₃ 442. CD₃ CD(CD₃)₂ CD₃ CD₃ 443. H H CD(CD₃)₂ H 444. CD₃ H CD(CD₃)₂ H 445. H CD₃ CD(CD₃)₂ H 446. H H CD(CD₃)₂ CD₃ 447. CD₃ CD₃ CD(CD₃)₂ H 448. CD₃ H CD(CD₃)₂ CD₃ 449. H CD₃ CD(CD₃)₂ CD₃ 450. CD₃ CD₃ CD(CD₃)₂ CD₃ 451. CD₂CH(CH₃)₂ H H H 452. CD₂CH(CH₃)₂ CD₃ H CD₃ 453. CD₂CH(CH₃)₂ H CD₃ H 454. CD₂CH(CH₃)₂ H H CD₃ 455. CD₂CH(CH₃)₂ CD₃ CD₃ H 456. CD₂CH(CH₃)₂ CD₃ H CD₃ 457. CD₂CH(CH₃)₂ H CD₃ CD₃ 458. CD₂CH(CH₃)₂ CD₃ CD₃ CD₃ 459. H CD₂CH(CH₃)₂ H H 460. CD₃ CD₂CH(CH₃)₂ H CD₃ 461. H CD₂CH(CH₃)₂ CD₃ H 462. H CD₂CH(CH₃)₂ H CD₃ 463. CD₃ CD₂CH(CH₃)₂ CD₃ H 464. CD₃ CD₂CH(CH₃)₂ H CD₃ 465. H CD₂CH(CH₃)₂ CD₃ CD₃ 466. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃ 467. H H CD₂CH(CH₃)₂ H 468. CD₃ H CD₂CH(CH₃)₂ H 469. H CD₃ CD₂CH(CH₃)₂ H 470. H H CD₂CH(CH₃)₂ CD₃ 471. CD₃ CD₃ CD₂CH(CH₃)₂ H 472. CD₃ H CD₂CH(CH₃)₂ CD₃ 473. H CD₃ CD₂CH(CH₃)₂ CD₃ 474. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃ 475. CD₂C(CH₃)₃ H H H 476. CD₂C(CH₃)₃ CD₃ H CD₃ 477. CD₂C(CH₃)₃ H CD₃ H 478. CD₂C(CH₃)₃ H H CD₃ 479. CD₂C(CH₃)₃ CD₃ CD₃ H 480. CD₂C(CH₃)₃ CD₃ H CD₃ 481. CD₂C(CH₃)₃ H CD₃ CD₃ 482. CD₂C(CH₃)₃ CH₃ CD₃ CD₃ 483. H CD₂C(CH₃)₃ H H 484. CD₃ CD₂C(CH₃)₃ H CD₃ 485. H CD₂C(CH₃)₃ CD₃ H 486. H CD₂C(CH₃)₃ H CD₃ 487. CD₃ CD₂C(CH₃)₃ CD₃ H 488. CD₃ CD₂C(CH₃)₃ H CD₃ 489. H CD₂C(CH₃)₃ CD₃ CD₃ 490. CD₃ CD₂C(CH₃)₃ CD₃ CD₃ 491. H H CD₂C(CH₃)₃ H 492. CD₃ H CD₂C(CH₃)₃ H 493. H CD₃ CD₂C(CH₃)₃ H 494. H H CD₂C(CH₃)₃ CD₃ 495. CD₃ CD₃ CD₂C(CH₃)₃ H 496. CD₃ H CD₂C(CH₃)₃ CD₃ 497. H CD₃ CD₂C(CH₃)₃ CD₃ 498. CD₃ CD₃ CD₂C(CH₃)₃ CD₃ 499.

H H H 500.

CD₃ H CD₃ 501.

H CD₃ H 502.

H H CD₃ 503.

CD₃ CD₃ H 504.

CD₃ H CD₃ 505.

H CD₃ CD₃ 506.

CD₃ CD CD₃ 507. H

H H 508. CD₃

H CD₃ 509. H

CD₃ H 510. H

H CD₃ 511. CD₃

CD H 512. CD₃

H CD₃ 513. H

CD₃ CD₃ 514. CD₃

CD CD₃ 515. H H

H 516. CD₃ H

H 517. H CD₃

H 518. H H

CD₃ 519. CD₃ CD₃

H 520. CD₃ H

CD₃ 521. H CD₃

CD₃ 522. CD₃ CD₃

CD₃ 523.

H H H 524.

CD₃ H CD₃ 525.

H CD₃ H 526.

H H CD₃ 527.

CD₃ CD₃ H 528.

CD₃ H CD₃ 529.

H CD₃ CD₃ 530.

CD₃ CD₃ CD₃ 531. H

H H 532. CH₃

H CD₃ 533. H

CD₃ H 534. H

H CD₃ 535. CD₃

CD₃ H 536. CD₃

H CD₃ 537. H

CD CD₃ 538. CH₃

CD₃ CD₃ 539. H H

H 540. CD₃ H

H 541. H CD₃

H 542. H H

CD₃ 543. CD₃ CD₃

H 544. CD₃ H

CD₃ 545. H CD₃

CD₃ 546. CD₃ CD₃

CD₃ 547.

H H H 548.

CD₃ H CD₃ 549.

H CD₃ H 550.

H H CD₃ 551.

CD₃ CD₃ H 552.

CD₃ H CD₃ 553.

H CD₃ CD₃ 554.

CD₃ CD₃ CD₃ 555. H

H H 556. CD₃

H CD₃ 557. H

CD₃ H 558. H

H CD₃ 559. CD₃

CD₃ H 560. CD₃

H CD₃ 561. H

CD₃ CD₃ 562. CD₃

CD₃ CD₃ 563. H H

H 564. CD₃ H

H 565. H CD₃

H 566. H H

CD₃ 567. CD₃ CD₃

H 568. CD₃ H

CD₃ 569. H CD₃

CD₃ 570. CD₃ CD₃

CD₃ 571.

H H H 572.

CD₃ H CD₃ 573.

H CD₃ H 574.

H H CD₃ 575.

CD₃ CD₃ H 576.

CD₃ H CD₃ 577.

H CD₃ CD₃ 578.

CD₃ CD₃ CD₃ 579. H

H H 580. CD₃

H CD₃ 581. H

CD₃ H 582. H

H CD₃ 583. CD₃

CD₃ H 584. CD₃

H CD₃ 585. H

CD₃ CD₃ 586. CD₃

CD₃ CD 587. H H

H 588. CD₃ H

H 589. H CD

H 590. H H

CD₃ 591. CD₃ CD₃

H 592. CD H

CD₃ 593. H CD₃

CD₃ 594. CD₃ CD₃

CD₃ 595.

H H H 596.

CD₃ H CD₃ 597.

H CD₃ H 598.

H H CD 599.

CD₃ CD₃ H 600.

CD₃ H CD₃ 601.

H CD₃ CD₃ 602.

CD₃ CD₃ CD₃ 603. H

H H 604. CD₃

H CD₃ 605. H

CD₃ H 606. H

H CD₃ 607. CD₃

CD₃ H 608. CD₃

H CD₃ 609. H

CD₃ CD₃ 610. CD₃

CD₃ CD₃ 611. H H

H 612. CD₃ H

H 613. H CD₃

H 614. H H

CD₃ 615. CD₃ CD₃

H 616. CD₃ H

CD₃ 617. H CD₃

CD₃ 618. CD₃ CD₃

CD₃ 619.

H H H 620.

CD₃ H CD₃ 621.

H CD₃ H 622.

H H CD₃ 623.

CH₃ CH₃ H 624.

CD₃ H CD₃ 625.

H CD₃ CD₃ 626.

CD₃ CD₃ CD₃ 627. H

H H 628. CD₃

H CD₃ 629. H

CD₃ H 630. H

H CD₃ 631. CD₃

CD₃ H 632. CD₃

H CD₃ 633. H

CD₃ CD₃ 634. CD₃

CD₃ CD₃ 635. H H

H 636. CD₃ H

H 637. H CD₃

H 638. H H

CH₃ 639. CD₃ CD₃

H 640. CD₃ H

CD₃ 641. H CD₃

CD₃ 642. CD₃ CD₃

CD₃ 643. CD(CH₃)₂ H CD₂CH₃ H 644. CD(CH₃)₂ H CD(CH₃)₂ H 645. CD(CH₃)₂ H CD₂CH(CH₃)₂ H 646. CD(CH₃)₂ H C(CH₃)₃ H 647. CD(CH₃)₂ H CD₂C(CH₃)₃ H 648. CD(CH₃)₂ H

H 649. CD(CH₃)₂ H

H 650. CD(CH₃)₂ H

H 651. CD(CH₃)₂ H

H 652. CD(CH₃)₂ H

H 653. CD(CH₃)₂ H

H 654. C(CH₃)₃ H CD₂CH₃ H 655. C(CH₃)₃ H CD(CH₃)₂ H 656. C(CH₃)₃ H CD₂CH(CH₃)₂ H 657. C(CH₃)₃ H C(CH₃)₃ H 658. C(CH₃)₃ H CD₂C(CH₃)₃ H 659. C(CH₃)₃ H

H 660. C(CH₃)₃ H

H 661. C(CH₃)₃ H

H 662. C(CH₃)₃ H

H 663. C(CH₃)₃ H

H 664. C(CH₃)₃ H

H 665. CD₂C(CH₃)₃ H CD₂CH₃ H 666. CD₂C(CH₃)₃ H CD(CH₃)₂ H 667. CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H 668. CD₂C(CH₃)₃ H C(CH₃)3 H 669. CD₂C(CH₃)₃ H CD₂C(CH₃)₃ H 670. CD₂C(CH₃)₃ H

H 671. CD₂C(CH₃)₃ H

H 672. CD₂C(CH₃)₃ H

H 673. CD₂C(CH₃)₃ H

H 674. CD₂C(CH₃)₃ H

H 675. CD₂C(CH₃)₃ H

H 676.

H CD₂CH₃ H 677.

H CD(CH₃)₂ H 678.

H CD₂CH(CH₃)₂ H 679.

H C(CH₃)₃ H 680.

H CD₂C(CH₃)₃ H 681.

H

H 682.

H

H 683.

H

H 684.

H

H 685.

H

H 686.

H

H 687.

H CD₂CH₃ H 688.

H CD(CH₃)₂ H 689.

H CD₂CH(CH₃)₂ H 690.

H C(CH₃)₃ H 691.

H CD₂C(CH₃)₃ H 692.

H CD₂CH₂CF₃ H 693.

H CD₂C(CH₃)₂CF₃ H 694.

H

H 695.

H

H 696.

H

H 697.

H

H 698.

H

H 699.

H

H 700.

H CD₂CH₃ H 701.

H CD(CH₃)₂ H 702.

H CD₂CH(CH₃)₂ H 703.

H C(CH₃)₃ H 704.

H CD₂C(CH₃)₃ H 705.

H CD₂CH₂CF₃ H 706.

H CD₂C(CH₃)₂CF₃ H 707.

H

H 708.

H

H 709.

H

H 710.

H

H 711.

H

H 712.

H

H 713.

H CD₂CH₃ H 714.

H CD(CH₃)₂ H 715.

H CD₂CH(CH₃)₂ H 716.

H C(CH₃)₃ H 717.

H CD₂C(CH₃)₃ H 718.

H CD₂CH₂CF₃ H 719.

H CD₂C(CH₃)₂CF₃ H 720.

H

H 721.

H

H 722.

H

H 723.

H

H 724.

H

H 725.

H

H 726.

H CD₂CH₃ H 727.

H CD(CH₃)₂ H 728.

H CD₂CH(CH₃)₂ H 729.

H C(CH₃)₃ H 730.

H CD₂C(CH₃)₃ H 731.

H CD₂CH₂CF H 732.

H CD₂C(CH₃)₂CF H 733.

H

H 734.

H

H 735.

H

H 736.

H

H 737.

H

H 738. H H H H 739. CH₃ Ph H H 740. H Ph H H 741. H Ph CH₃ H 742. CH₃ Ph H CH₃ 743. CH₃ Ph CH₃ H 744. CH₃ Ph H CH₃ 745. H Ph CH₃ H 746. H Ph H CH₃ 747. H Ph CH₃ CH₃ 748. CH₃ Ph CH₃ H 749. CH₃ Ph H CH₃ 750. CH₃ Ph CH₃ CH₃ 751. H Ph CH₃ CH₃ 752. CH₃ Ph CH₃ CH₃ 753. CH₂CH₃ Ph H H 754. CH₂CH₃ Ph H CH₃ 755. CH₂CH₃ Ph CH₃ H 756. CH₂CH₃ Ph H CH₃ 757. CH₂CH₃ Ph CH₃ H 758. CH₂CH₃ Ph H CH₃ 759. CH₂CH₃ Ph CH₃ CH₃ 760. CH₂CH₃ Ph CH₃ CH₃ 761. H Ph H H 762. CH₃ Ph H CH₃ 763. H Ph CH₃ H 764. H Ph H CH 765. CH₃ Ph CH₃ H 766. CH₃ Ph H CH₃ 767. H Ph CH₃ CH₃ 768. CH₃ Ph CH₃ CH₃ 769. H Ph CH₂CH₃ H 770. CH₃ Ph CH₂CH₃ H 771. H Ph CH₂CH₃ H 772. H Ph CH₂CH CH₃ 773. CH₃ Ph CH₂CH₃ H 774. CH₃ Ph CH₂CH₃ CH₃ 775. H Ph CH₂CH₃ CH₃ 776. CH₃ Ph CH₂CH₃ CH₃ 777. CH(CH₃)₂ Ph H H 778. CH(CH₃)₂ Ph H CH₃ 779. CH(CH₃)₂ Ph CH₃ H 780. CH(CH₃)₂ Ph H CH₃ 781. CH(CH₃)₂ Ph CH₃ H 782. CH(CH₃)₂ Ph H CH₃ 783. CH(CH₃)₂ Ph CH₃ CH₃ 784. CH(CH₃)₂ Ph CH₃ CH₃ 785. H Ph H H 786. CH₃ Ph H CH₃ 787. H Ph CH₃ H 788. H Ph H CH₃ 789. CH₃ Ph CH₃ H 790. CH₃ Ph H CH₃ 791. H Ph CH₃ CH₃ 792. CH₃ Ph CH₃ CH₃ 793. H Ph CH(CH₃)₂ H 794. CH₃ Ph CH(CH₃)₂ H 795. H Ph CH(CH₃)₂ H 796. H Ph CH(CH₃)₂ CH₃ 797. CH₃ Ph CH(CH₃)₂ H 798. CH₃ Ph CH(CH₃)₂ CH₃ 799. H Ph CH(CH₃)₂ CH₃ 800. CH₃ Ph CH(CH₃)₂ CH₃ 801. CH₂CH(CH₃)₂ Ph H H 802. CH₂CH(CH₃)₂ Ph H CH₃ 803. CH₂CH(CH₃)₂ Ph CH₃ H 804. CH₂CH(CH₃)₂ Ph H CH₃ 805. CH₂CH(CH₃)₂ Ph CH₃ H 806. CH₂CH(CH₃)₂ Ph H CH₃ 807. CH₂CH(CH₃)₂ Ph CH₃ CH₃ 808. CH₂CH(CH₃)₂ Ph CH₃ CH₃ 809. H Ph H H 810. CH₃ Ph H CH₃ 811. H Ph CH₃ H 812. H Ph H CH₃ 813. CH₃ Ph CH₃ H 814. CH₃ Ph H CH₃ 815. H Ph CH₃ CH₃ 816. CH₃ Ph CH₃ CH₃ 817. H Ph CH₂CH(CH₃)₂ H 818. CH₃ Ph CH₂CH(CH₃)₂ H 819. H Ph CH₂CH(CH₃)₂ H 820. H Ph CH₂CH(CH₃)₂ CH₃ 821. CH₃ Ph CH₂CH(CH₃)₂ H 822. CH₃ Ph CH₂CH(CH₃)₂ CH₃ 823. H Ph CH₂CH(CH₃)₂ CH₃ 824. CH₃ Ph CH₂CH(CH₃)₂ CH₃ 825. C(CH₃)₃ Ph H H 826. C(CH₃)₃ Ph H CH₃ 827. C(CH₃)₃ Ph CH₃ H 828. C(CH₃)₃ Ph H CH₃ 829. C(CH₃)₃ Ph CH₃ H 830. C(CH₃)₃ Ph H CH₃ 831. C(CH₃)₃ Ph CH₃ CH₃ 832. C(CH₃)₃ Ph CH₃ CH₃ 833. H Ph H H 834. CH₃ Ph H CH₃ 835. H Ph CH₃ H 836. H Ph H CH₃ 837. CH₃ Ph CH₃ H 838. CH₃ Ph H CH₃ 839. H Ph CH₃ CH₃ 840. CH₃ Ph CH₃ CH₃ 841. H Ph C(CH₃)₃ H 842. CH₃ Ph C(CH₃)₃ H 843. H Ph C(CH₃)₃ H 844. H Ph C(CH₃)₃ CH₃ 845. CH₃ Ph C(CH₃)₃ H 846. CH₃ Ph C(CH₃)₃ CH₃ 847. H Ph C(CH₃)₃ CH₃ 848. CH₃ Ph C(CH₃)₃ CH₃ 849. CH₂C(CH₃)₃ Ph H H 850. CH₂C(CH₃)₃ Ph H CH₃ 851. CH₂C(CH₃)₃ Ph CH₃ H 852. CH₂C(CH₃)₃ Ph H CH₃ 853. CH₂C(CH₃)₃ Ph CH₃ H 854. CH₂C(CH₃)₃ Ph H CH₃ 855. CH₂C(CH₃)₃ Ph CH₃ CH₃ 856. CH₂C(CH₃)₃ Ph CH₃ CH₃ 857. H Ph H H 858. CH₃ Ph H CH₃ 859. H Ph CH₃ H 860. H Ph H CH₃ 861. CH₃ Ph CH₃ H 862. CH₃ Ph H CH₃ 863. H Ph CH₃ CH₃ 864. CH₃ Ph CH₃ CH₃ 865. H Ph CH₂C(CH₃)₃ H 866. CH₃ Ph CH₂C(CH₃)₃ H 867. H Ph CH₂C(CH₃)₃ H 868. H Ph CH₂C(CH₃)₃ CH₃ 869. CH₃ Ph CH₂C(CH₃)₃ H 870. CH₃ Ph CH₂C(CH₃)₃ CH₃ 871. H Ph CH₂C(CH₃)₃ CH₃ 872. CH₃ Ph CH₂C(CH₃)₃ CH₃ 873.

Ph H H 874.

Ph H CH₃ 875.

Ph CH₃ H 876.

Ph H CH₃ 877.

Ph CH₃ H 878.

Ph H CH₃ 879.

Ph CH₃ CH₃ 880.

Ph CH₃ CH₃ 881. H Ph H H 882. CH₃ Ph H CH₃ 883. H Ph CH₃ H 884. H Ph H CH₃ 885. CH₃ Ph CH₃ H 886. CH₃ Ph H CH₃ 887. H Ph CH₃ CH₃ 888. CH₃ Ph CH₃ CH₃ 889. H Ph

H 890. CH₃ Ph

H 891. H Ph

H 892. H Ph

CH₃ 893. CH₃ Ph

H 894. CH₃ Ph

CH₃ 895. H Ph

CH₃ 896. CH₃ Ph

CH 897.

Ph H H 898.

Ph H CH₃ 899.

Ph CH₃ H 900.

Ph H CH 901.

Ph CH₃ H 902.

Ph H CH₃ 903.

Ph CH₃ CH₃ 904.

Ph CH₃ CH₃ 905. H Ph H H 906. CH₃ Ph H CH₃ 907. H Ph CH₃ H 908. H Ph H CH₃ 909. CH₃ Ph CH H 910. CH₃ Ph H CH₃ 911. H Ph CH₃ CH₃ 912. CH₃ Ph CH₃ CH₃ 913. H Ph

H 914. CH₃ Ph

H 915. H Ph

H 916. H Ph

CH 917. CH₃ Ph

H 918. CH₃ Ph

CH₃ 919. H Ph

CH 920. CH₃ Ph

CH 921.

Ph H H 922.

Ph H CH₃ 923.

Ph CH H 924.

Ph H CH₃ 925.

Ph CH₃ H 926.

Ph H CH₃ 927.

Ph CH₃ CH₃ 928.

Ph CH₃ CH₃ 929. H Ph H H 930. CH₃ Ph H CH₃ 931. H Ph CH₃ H 932. H Ph H CH₃ 933. CH₃ Ph CH H 934. CH₃ Ph H CH₃ 935. H Ph CH₃ CH₃ 936. CH₃ Ph CH₃ CH₃ 937. H Ph

H 938. CH₃ Ph

H 939. H Ph

H 940. H Ph

CH₃ 941. CH₃ Ph

H 942. CH₃ Ph

CH₃ 943. H Ph

CH₃ 944. CH₃ Ph

CH₃ 945.

Ph H H 946.

Ph H CH₃ 947.

Ph CH₃ H 948.

Ph H CH₃ 949.

Ph CH₃ H 950.

Ph H CH₃ 951.

Ph CH₃ CH₃ 952.

Ph CH₃ CH₃ 953. H Ph H H 954. CH₃ Ph H CH₃ 955. H Ph CH₃ H 956. H Ph H CH₃ 957. CH₃ Ph CH₃ H 958. CH₃ Ph H CH₃ 959. H Ph CH₃ CH₃ 960. CH₃ Ph CH₃ CH₃ 961. H Ph

H 962. CH₃ Ph

H 963. H Ph

H 964. H Ph

CH₃ 965. CH₃ Ph

H 966. CH₃ Ph

CH₃ 967. H Ph

CH₃ 968. CH₃ Ph

CH₃ 969.

Ph H H 970.

Ph H CH₃ 971.

Ph CH₃ H 972.

Ph H CH₃ 973.

Ph CH₃ H 974.

Ph H CH₃ 975.

Ph CH₃ CH₃ 976.

Ph CH₃ CH₃ 977. H Ph H H 978. CH₃ Ph H CH₃ 979. H Ph CH₃ H 980. H Ph H CH₃ 981. CH₃ Ph CH₃ H 982. CH₃ Ph H CH₃ 983. H Ph CH₃ CH₃ 984. CH₃ Ph CH₃ CH 985. H Ph

H 986. CH₃ Ph

H 987. H Ph

H 988. H Ph

CH₃ 989. CH₃ Ph

H 990. CH₃ Ph

CH₃ 991. H Ph

CH₃ 992. CH₃ Ph

CH₃ 993.

Ph H H 994.

Ph H CH₃ 995.

Ph CH₃ H 996.

Ph H CH₃ 997.

Ph CH₃ H 998.

Ph H CH₃ 999.

Ph CH₃ CH₃ 1000.

Ph CH₃ CH 1001. H Ph H H 1002. CH₃ Ph H CH₃ 1003. H Ph CH₃ H 1004. H Ph H CH₃ 1005. CH₃ Ph CH₃ H 1006. CH₃ Ph H CH₃ 1007. H Ph CH₃ CH₃ 1008. CH₃ Ph CH₃ CH₃ 1009. H Ph

H 1010. CH₃ Ph

H 1011. H Ph

H 1012. H Ph

CH₃ 1013. CH₃ Ph

H 1014. CH₃ Ph

CH₃ 1015. H Ph

CH₃ 1016. CH₃ Ph

CH₃ 1017. CH(CH₃)₂ Ph CH₂CH₃ H 1018. CH(CH₃)₂ Ph CH(CH₃)₂ H 1019. CH(CH₃)₂ Ph CH₂CH(CH₃)₂ H 1020. CH(CH₃)₂ Ph C(CH₃)₃ H 1021. CH(CH₃)₂ Ph CH₂C(CH₃)₃ H 1022. CH(CH₃)₂ Ph

H 1023. CH(CH₃)₂ Ph

H 1024. CH(CH₃)₂ Ph

H 1025 CH(CH₃)₂ Ph

H 1026. CH(CH₃)₂ Ph

H 1027. CH(CH₃)₂ Ph

H 1028. C(CH₃)₃ Ph CH₂CH₃ H 1029. C(CH₃)₃ Ph CH(CH₃)₂ H 1030. C(CH₃)₃ Ph CH₂CH(CH₃)₂ H 1031. C(CH₃)₃ Ph C(CH₃)₃ H 1032. C(CH₃)₃ Ph CH₂C(CH₃)₃ H 1033. C(CH₃)₃ Ph

H 1034. C(CH₃)₂ Ph

H 1035. C(CH₃)₃ Ph

H 1036. C(CH₃)₃ Ph

H 1037. C(CH₃)₃ Ph

H 1038. C(CH₃)₃ Ph

H 1039. CH₂C(CH₃)₃ Ph CH₂CH₃ H 1040. CH₂C(CH₃)₃ Ph CH(CH₃)₂ H 1041. CH₂C(CH₃)₃ Ph CH₂CH(CH₃)₂ H 1042. CH₂C(CH₃)₃ Ph C(CH₃)₃ H 1043. CH₂C(CH₃)₃ Ph CH₂C(CH₃)₃ H 1044. CH₂C(CH₃)₃ Ph

H 1045. CH₂C(CH₃)₃ Ph

H 1046. CH₂C(CH₃)₃ Ph

H 1047. CH₂C(CH₃)₃ Ph

H 1048. CH₂C(CH₃)₃ Ph

H 1049. CH₂C(CH₃)₃ Ph

H 1050.

Ph CH₂CH₃ H 1051.

Ph CH(CH₃)₂ H 1052.

Ph CH₂CH(CH₃)₂ H 1053.

Ph C(CH₃)₃ H 1054.

Ph CH₂C(CH₃)₃ H 1055.

Ph

H 1056.

Ph

H 1057.

Ph

H 1058.

Ph

H 1059.

Ph

H 1060.

Ph

H 1061.

Ph CH₂CH₃ H 1062.

Ph CH(CH₃)₂ H 1063.

Ph CH₂CH(CH₃)₂ H 1064.

Ph C(CH₃)₃ H 1065.

Ph CH₂C(CH₃)₃ H 1066.

Ph

H 1067.

Ph

H 1068.

Ph

H 1069.

Ph

H 1070.

Ph

H 1071.

Ph

H 1072.

Ph CH₂CH(CH₃)₂ H 1073.

Ph C(CH₃)₃ H 1074.

Ph CH₂C(CH₃)₃ H 1075.

Ph

H 1076.

Ph

H 1077.

Ph

H 1078.

Ph

H 1079.

Ph

H 1080.

Ph

H 1081.

Ph CH₂CH(CH₃)₂ H 1082.

Ph C(CH₃)₃ H 1083.

Ph CH₂C(CH₃)₃ H 1084.

Ph

H 1085.

Ph

H 1086.

Ph

H 1087.

Ph

H 1088.

Ph

H 1089.

Ph

H 1090.

Ph CH₂CH(CH₃)₂ H 1091.

Ph C(CH₃)₃ H 1092.

Ph CH₂C(CH₃)₃ H 1093.

Ph CH₂CH₂CF₃ H 1094.

Ph CH₂C(CH₃)₂CF₃ H 1095.

Ph

H 1096.

Ph

H 1097.

Ph

H 1098.

Ph

H 1099.

Ph

H 1100.

Ph

H 1101. H Ph H H 1102. CD₃ Ph H H 1103. H Ph H H 1104. H Ph CD₃ H 1105. CD₃ Ph H CD₃ 1106. CD₃ Ph CD₃ H 1107. CD Ph H CD₃ 1108. H Ph CH₃ H 1109. H Ph H CD₃ 1110. H Ph CD₃ CD₃ 1111. CD₃ Ph CD₃ H 1112. CD₃ Ph H CD₃ 1113. CD₃ Ph CD₃ CD₃ 1114. H Ph CD₃ CD₃ 1115. CD₃ Ph CD₃ CD₃ 1116. CD₂CH₃ Ph H H 1117. CD₂CH₃ Ph H CD₃ 1118. CD₂CH₃ Ph CD₃ H 1119. CD₂CH₃ Ph H CD₃ 1120. CD₂CH₃ Ph CD₃ H 1121. CD₂CH₃ Ph H CD₃ 1122. CD₂CH₃ Ph CD₃ CD₃ 1123. CD₂CH₃ Ph CD₃ CD₃ 1124. H Ph H H 1125. CH₃ Ph H CD₃ 1126. H Ph CD₃ H 1127. H Ph H CD₃ 1128. CD₃ Ph CD₃ H 1129. CD₃ Ph H CD₃ 1130. H Ph CD₃ CD₃ 1131. CD₃ Ph CD₃ CD₃ 1132. H Ph CD₂CH₃ H 1133. CD₃ Ph CD₂CH₃ H 1134. H Ph CD₂CH₃ H 1135. H Ph CD₂CH₃ CD₃ 1136. CD₃ Ph CD₂CH₃ H 1137. CD₃ Ph CD₂CH₃ CD₃ 1138. H Ph CD₂CH₃ CD₃ 1139. CD₃ Ph CD₂CH₃ CD₃ 1140. CD(CH₃)₂ Ph H H 1141. CD(CH3)₂ Ph H CD₃ 1142. CD(CH₃)₂ Ph CD₃ H 1143. CD(CH₃)₂ Ph H CD₃ 1144. CD(CH₃)₂ Ph CD₃ H 1145. CD(CH₃)₂ Ph H CD₃ 1146. CD(CH₃)₂ Ph CD₃ CD₃ 1147. CD(CH₃)₂ Ph CD₃ CD₃ 1148. H Ph H H 1149. CD₃ Ph H CD₃ 1150. H Ph CD₃ H 1151. H Ph H CD₃ 1152. CD₃ Ph CD₃ H 1153. CD₃ Ph H CD₃ 1154. H Ph CD₃ CD₃ 1155. CD₃ Ph CD₃ CD₃ 1156. H Ph CD(CH₃)₂ H 1157. CD₃ Ph CD(CH₃)₂ H 1158. H Ph CD(CH₃)₂ H 1159. H Ph CD(CH₃)₂ CD₃ 1160. CD₃ Ph CD(CH₃)₂ H 1161. CD₃ Ph CD(CH₃)₂ CD₃ 1162. H Ph CD(CH₃)₂ CD₃ 1163. CD₃ Ph CD(CH₃)₂ CD₃ 1164. CD(CH₃)₂ Ph H H 1165. CD(CD₃)₂ Ph H CD₃ 1166. CD(CD₃)₂ Ph CD₃ H 1167. CD(CD₃)₂ Ph H CD₃ 1168. CD(CD₃)₂ Ph CD₃ H 1169. CD(CD₃)₂ Ph H CD₃ 1170. CD(CD₃)₂ Ph CD₃ CD₃ 1171. CD(CD₃)₂ Ph CD₃ CD₃ 1172. H Ph H H 1173. CH₃ Ph H CD₃ 1174. H Ph CD₃ H 1175. H Ph H CD3 1176. CD₃ Ph CD₃ H 1177. CD₃ Ph H CD₃ 1178. H Ph CD₃ CD₃ 1179. CD₃ Ph CD₃ CD₃ 1180. H Ph CD(CD₃)₂ H 1181. CD₃ Ph CD(CD₃)₂ H 1182. H Ph CD(CD₃)₂ H 1183. H Ph CD(CD₃)₂ CD₃ 1184. CD₃ Ph CD(CD₃)₂ H 1185. CD₃ Ph CD(CD₃)₂ CD₃ 1186. H Ph CD(CD₃)₂ CD₃ 1187. CD₃ Ph CD(CD₃)₂ CD₃ 1188. CD₂CH(CH₃)₂ Ph H H 1189. CD₂CH(CH₃)₂ Ph H CD₃ 1190. CD₂CH(CH₃)₂ Ph CD₃ H 1191. CD₂CH(CH₃)₂ Ph H CD₃ 1192. CD₂CH(CH₃)₂ Ph CD₃ H 1193. CD₂CH(CH₃)₂ Ph H CD₃ 1194. CD₂CH(CH₃)₂ Ph CD₃ CD₃ 1195. CD₂CH(CH₃)₂ Ph CD₃ CD₃ 1196. H Ph H H 1197. CD₃ Ph H CD₃ 1198. H Ph CD₃ H 1199. H Ph H CD₃ 1200. CD₃ Ph CD₃ H 1201. CD₃ Ph H CD₃ 1202. H Ph CD₃ CD₃ 1203. CD₃ Ph CD₃ CD₃ 1204. H Ph CD₂CH(CH₃)₂ H 1205. CD₃ Ph CD₂CH(CH₃)₂ H 1206. H Ph CD₂CH(CH₃)₂ H 1207. H Ph CD₂CH(CH₃)₂ CD₃ 1208. CD₃ Ph CD₂CH(CH₃)₂ H 1209. CD₃ Ph CD₂CH(CH₃)₂ CD₃ 1210. H Ph CD₂CH(CH₃)₂ CD₃ 1211. CD₃ Ph CD₂CH(CH₃)₂ CD₃ 1212. CD₂C(CH₃)₃ Ph H H 1213. CD₂C(CH₃)₃ Ph H CD₃ 1214. CD₂C(CH₃)₃ Ph CD₃ H 1215. CD₂C(CH₂)₃ Ph H CD₃ 1216. CD₂C(CH₃)₃ Ph CD₃ H 1217. CD₂C(CH₃)₃ Ph H CD₃ 1218. CD₂C(CH₃)₃ Ph CD₃ CD₃ 1219. CD₂C(CH₃)₃ Ph CD₃ CD₃ 1220. H Ph H H 1221. CD₃ Ph H CD₃ 1222. H Ph CD₃ H 1223. H Ph H CD₃ 1224. CD₃ Ph CD₃ H 1225. CD₃ Ph H CD₃ 1226. H Ph CD₃ CD₃ 1227. CD₃ Ph CD₃ CD₃ 1228. H Ph CD₂C(CH₃)₃ H 1229. CD₃ Ph CD₂C(CH₃)₃ H 1230. H Ph CD₂C(CH₃)₃ H 1231. H Ph CD₂C(CH₃)₃ CD₃ 1232. CD₃ Ph CD₂C(CH₃)₃ H 1233. CD₃ Ph CD₂C(CH₃)₃ CD₃ 1234. H Ph CD₂C(CH₃)₃ CD₃ 1235. CD₃ Ph CD₂C(CH₃)₃ CD₃ 1236.

Ph H H 1237.

Ph H CD₃ 1238.

Ph CD₃ H 1239.

Ph H CD₃ 1240.

Ph CD₃ H 1241.

Ph H CD₃ 1242.

Ph CD₃ CD₃ 1243.

Ph CD₃ CD₃ 1244. H Ph H H 1245. CD₃ Ph H CD₃ 1246. H Ph CD₃ H 1247. H Ph H CD₃ 1248. CD₃ Ph CD₃ H 1249. CD₃ Ph H CD₃ 1250. H Ph CD₃ CD₃ 1251. CD₃ Ph CD₃ CD₃ 1252. H Ph

H 1253. CD₃ Ph

H 1254. H Ph

H 1255. H Ph

CD₃ 1256. CD₃ Ph

H 1257. CD₃ Ph

CD₃ 1258. H Ph

CD₃ 1259. CD₃ Ph

CD₃ 1260.

Ph H H 1261.

Ph H CD₃ 1262.

Ph CD₃ H 1263.

Ph H CD₃ 1264.

Ph CD₃ H 1265.

Ph H CD₃ 1266.

Ph CD₃ CD₃ 1267.

Ph CD₃ CD₃ 1268. H Ph H H 1269. CH₃ Ph H CD₃ 1270. H Ph CD₃ H 1271. H Ph H CD₃ 1272. CD₃ Ph CD₃ H 1273. CD₃ Ph H CD₃ 1274. H Ph CD₃ CD₃ 1275. CH₃ Ph CD₃ CD3 1276. H Ph

H 1277. CD₃ Ph

H 1278. H Ph

H 1279. H Ph

CD₃ 1280. CD₃ Ph

H 1281. CD₃ Ph

CD₃ 1282. H Ph

CD₃ 1283. CD₃ Ph

CD₃ 1284.

Ph H H 1285.

Ph H CD₃ 1286.

Ph CD₃ H 1287.

Ph H CD₃ 1288.

Ph CD₃ H 1289.

Ph H CD₃ 1290.

Ph CD₃ CD₃ 1291.

Ph CD₃ CD₃ 1292. H Ph H H 1293. CD₃ Ph H CD₃ 1294. H Ph CD₃ H 1295. H Ph H CD₃ 1296. CD₃ Ph CD₃ H 1297. CD₃ Ph H CD₃ 1298. H Ph CD₃ CD₃ 1299. CD₃ Ph CD₃ CD₃ 1300. H Ph

H 1301. CD₃ Ph

H 1302. H Ph

H 1303. H Ph

CD₃ 1304. CD₃ Ph

H 1305. CD₃ Ph

CD₃ 1306. H Ph

CD₃ 1307. CD₃ Ph

CD₃ 1308.

Ph H H 1309.

Ph H CD₃ 1310.

Ph CD₃ H 1311.

Ph H CD₃ 1312.

Ph CD₃ H 1313.

Ph H CD₃ 1314.

Ph CD₃ CD₃ 1315.

Ph CD₃ CD₃ 1316. H Ph H H 1317. CD₃ Ph H CD₃ 1318. H Ph CD₃ H 1319. H Ph H CD₃ 1320. CD₃ Ph CD₃ H 1321. CD₃ Ph H CD₃ 1322. H Ph CD₃ CD₃ 1323. CD₃ Ph CD₃ CD₃ 1324. H Ph

H 1325. CD₃ Ph

H 1326. H Ph

H 1327. H Ph

CD₃ 1328. CD₃ Ph

H 1329. CD₃ Ph

CD₃ 1330. H Ph

CD₃ 1331. CD₃ Ph

CD₃ 1332.

Ph H H 1333.

Ph H CD₃ 1334.

Ph CD₃ H 1335.

Ph H CD₃ 1336.

Ph CD₃ H 1337.

Ph H CD₃ 1338.

Ph CD₃ CD₃ 1339.

Ph CD₃ CD₃ 1340. H Ph H H 1341. CD₃ Ph H CD₃ 1342. H Ph CD₃ H 1343. H Ph H CD₃ 1344. CD₃ Ph CD₃ H 1345. CD₃ Ph H CD₃ 1346. H Ph CD₃ CD₃ 1347. CD₃ Ph CD₃ CD₃ 1348. H Ph

H 1349. CD₃ Ph

H 1350. H Ph

H 1351. H Ph

CD₃ 1352. CD₃ Ph

H 1353. CD₃ Ph

CD₃ 1354. H Ph

CD₃ 1355. CD₃ Ph

CD₃ 1356.

Ph H H 1357.

Ph H CD₃ 1358.

Ph CD₃ H 1359.

Ph H CD₃ 1360.

Ph CH₃ H 1361.

Ph H CD₃ 1362.

Ph CD₃ CD₃ 1363.

Ph CD₃ CD₃ 1364. H Ph H H 1365. CD₃ Ph H CD₃ 1366. H Ph CD₃ H 1367. H Ph H CD₃ 1368. CD₃ Ph CD₃ H 1369. CD₃ Ph H CD₃ 1370. H Ph CD₃ CD₃ 1371. CD₃ Ph CD₃ CD₃ 1372. H Ph

H 1373. CD₃ Ph

H 1374. H Ph

H 1375. H Ph

CH₃ 1376. CD₃ Ph

H 1377. CD₃ Ph

CD₃ 1378. H Ph

CD₃ 1379. CD₃ Ph

CD₃ 1380. CD(CH₃)₂ Ph CD₂CH₃ H 1381. CD(CH₃)₂ Ph CD(CH₃)₂ H 1382. CD(CH₃)₂ Ph CD₂CH(CH₃)₂ H 1383. CD(CH₃)₂ Ph C(CH₃)₃ H 1384. CD(CH₃)₂ Ph CD₂C(CH₃)₃ H 1385. CD(CH₃)₂ Ph CD₂CH₂CF H 1386. CD(CH₃)₂ Ph CD₂C(CH₃)₂CF₃ H 1387. CD(CH₃)₂ Ph

H 1388. CD(CH₃)₂ Ph

H 1389. CD(CH₃)₂ Ph

H 1390. CD(CH₃)₂ Ph

H 1391. CD(CH₃)₂ Ph

H 1392. CD(CH₃)2 Ph

H 1393. C(CH₃)₃ Ph CD₂CH₃ H 1394. C(CH₃)₃ Ph CD(CH₃)₂ H 1395. C(CH₃)₃ Ph CD₂CH(CH₃)₂ H 1396. C(CH₃)₃ Ph C(CH₃)₃ H 1397. C(CH₃)₃ Ph CD₂C(CH₃)₃ H 1398. C(CH₃)₃ Ph

H 1399. C(CH₃)₃ Ph

H 1400. C(CH₃)₃ Ph

H 1401. C(CH₃)₃ Ph

H 1402. C(CH₃)₃ Ph

H 1403. C(CH₃)₃ Ph

H 1404. CD₂C(CH₃)₃ Ph CD₂CH₃ H 1405. CD₂C(CH₃)₃ Ph CD(CH₃)₂ H 1406. CD₂C(CH₃)₃ Ph CD₂CH(CH₃)₂ H 1407. CD₂C(CH₃)₃ Ph C(CH₃)₃ H 1408. CD₂C(CH₃)₃ Ph CD₂C(CH₃)₃ H 1409. CD₂C(CH₃)₃ Ph CD₂CH₂CF₃ H 1410. CD₂C(CH₃)₃ Ph CD₂C(CH₃)₂CF₃ H 1411. CD₂C(CH₃)₃ Ph

H 1412. CD₂C(CH₃)₃ Ph

H 1413. CD₂C(CH₃)₃ Ph

H 1414. CD₂C(CH₃)₃ Ph

H 1415. CD₂C(CH₃)₃ Ph

H 1416. CD₂C(CH₃)₃ Ph

H 1417.

Ph CD₂CH₃ H 1418.

Ph CD(CH₃)₂ H 1419.

Ph CD₂CH(CH₃)₂ H 1420.

Ph C(CH₃)₃ H 1421.

Ph CD₂C(CH₃)₃ H 1422.

Ph

H 1423.

Ph

H 1424.

Ph

H 1425.

Ph

H 1426.

Ph

H 1427.

Ph

H 1428.

Ph CD₂CH₃ H 1429.

Ph CD(CH₃)₂ H 1430.

Ph CD₂CH(CH₃)₂ H 1431.

Ph C(CH₃)₃ H 1432.

Ph CD₂C(CH₃)₃ H 1433.

Ph

H 1434.

Ph

H 1435.

Ph

H 1436.

Ph

H 1437.

Ph

H 1438.

Ph

H 1439.

Ph CD₂CH₃ H 1440.

Ph CD(CH₃)₂ H 1441.

Ph CD₂CH(CH₃)₂ H 1442.

Ph C(CH₃)₃ H 1443.

Ph CD₂C(CH₃)₃ H 1444.

Ph

H 1445.

Ph

H 1446.

Ph

H 1447.

Ph

H 1448.

Ph

H 1449.

Ph

H 1450.

Ph CD₂CH₃ H 1451.

Ph CD(CH₃)₂ H 1452.

Ph CD₂CH(CH₃)₂ H 1453.

Ph C(CH₃)₃ H 1454.

Ph CD₂C(CH₃)₃ H 1455.

Ph

H 1456.

Ph

H 1457.

Ph

H 1458.

Ph

H 1459.

Ph

H 1460.

Ph

H 1461.

Ph CD₂CH₃ H 1462.

Ph CD(CH₃)₂ H 1463.

Ph CD₂CH(CH₃)₂ H 1464.

Ph C(CH₃)₃ H 1465.

Ph CD₂C(CH₃)₃ H 1466.

Ph

H 1467.

Ph

H 1468.

Ph

H 1469.

Ph

H 1470.

Ph

H 1471.

Ph

H

In the embodiments of the compound where L_(B) is one of L_(B1) to L_(B1471) defined above, the compound is selected from the group consisting of Compound A-x having the formula Ir(L_(Ai))(L_(Bj))₂ or Compound B-x having the formula Ir(L_(Ai))₂(L_(Bj)); wherein x is an integer defined by x=1471i+j−1471, wherein i is an integer from 1 to 371, j is an integer from 1 to 1471, and wherein L_(A1) to L_(A371) have the following formula:

wherein R, R¹, R², R³, R⁴, R⁵, and R⁶ are defined as provided below:

L_(Ai), where i is R¹ R R^(A) R^(B) R^(C) R^(D) R^(E) 1. H R^(A1) H H H H H 2. H R^(A2) H H H H H 3. H R^(A3) H H H H H 4. H R^(A4) H H H H H 5. H R^(A5) H H H H H 6. H R^(A6) H H H H H 7. H R^(A7) H H H H H 8. H R^(A8) H H H H H 9. H R^(A9) H H H H H 10. H R^(A10) H H H H H 11. H R^(A11) H H H H H 12. H R^(A12) H H H H H 13. H R^(A13) H H H H H 14. H R^(A14) H H H H H 15. H R^(A15) H H H H H 16. H R^(A16) H H H H H 17. H R^(A17) H H H H H 18. H R^(A18) H H H H H 19. H R^(A19) H H H H H 20. H R^(A20) H H H H H 21. H R^(A21) H H H H H 22. H R^(A22) H H H H H 23. H R^(A23) H H H H H 24. H R^(A24) H H H H H 25. H R^(A25) H H H H H 26. H R^(A26) H H H H H 27. H R^(A27) H H H H H 28. H R^(A28) H H H H H 29. H R^(A29) H H H H H 30. H R^(A30) H H H H H 31. H R^(A31) H H H H H 32. H R^(A32) H H H H H 33. H R^(A33) H H H H H 34. H R^(A34) H H H H H 35. H R^(A35) H H H H H 36. H R^(A36) H H H H H 37. H R^(A37) H H H H H 38. H R^(A38) H H H H H 39. H R^(A39) H H H H H 40. H R^(A40) H H H H H 41. H R^(A41) H H H H H 42. H R^(A42) H H H H H 43. H R^(A43) H H H H H 44. H R^(A44) H H H H H 45. H R^(A45) H H H H H 46. H R^(A46) H H H H H 47. H R^(A47) H H H H H 48. H R^(A48) H H H H H 49. H R^(A49) H H H H H 50. H R^(A50) H H H H H 51. H R^(A51) H H H H H 52. H R^(A52) H H H H H 53. H R^(A53) H H H H H 54. H R^(A54) H H H H H 55. H R^(A55) H H H H H 56. H R^(A56) H H H H H 57. H R^(A57) H H H H H 58. H R^(A58) H H H H H 59. H R^(A59) H H H H H 60. H R^(A60) H H H H H 61. H R^(A61) H H H H H 62. H R^(A62) H H H H H 63. H R^(A63) H H H H H 64. H R^(A64) H H H H H 65. H R^(A65) H H H H H 66. H R^(A66) H H H H H 67. H R^(A67) H H H H H 68. H R^(A68) H H H H H 69. H R^(A69) H H H H H 70. H R^(A70) H H H H H 71. H R^(A71) H H H H H 72. H R^(A72) H H H H H 73. H R^(A73) H H H H H 74. H R^(A74) H H H H H 75. H R^(A75) H H H H H 76. H R^(A76) H H H H H 77. H R^(A77) H H H H H 78. H R^(A78) H H H H H 79. H R^(A79) H H H H H 80. H R^(A80) H H H H H 81. H R^(A81) H H H H H 82. H R^(A82) H H H H H 83. H R^(A83) H H H H H 84. H R^(A84) H H H H H 85. H R^(A85) H H H H H 86. H R^(A86) H H H H H 87. H R^(A87) H H H H H 88. H R^(A88) H H H H H 89. H R^(A89) H H H H H 90. H R^(A90) H H H H H 91. H R^(A91) H H H H H 92. H R^(A92) H H H H H 93. H R^(A93) H H H H H 94. CD₃ R^(A1) H H H H H 95. CD₃ R^(A2) H H H H H 96. CD₃ R^(A3) H H H H H 97. CD₃ R^(A4) H H H H H 98. CD₃ R^(A5) H H H H H 99. CD₃ R^(A6) H H H H H 100. CD₃ R^(A7) H H H H H 101. CD₃ R^(A8) H H H H H 102. CD₃ R^(A9) H H H H H 103. CD₃ R^(A10) H H H H H 104. CD₃ R^(A11) H H H H H 105. CD₃ R^(A12) H H H H H 106. CD₃ R^(A13) H H H H H 107. CD₃ R^(A14) H H H H H 108. CD₃ R^(A15) H H H H H 109. CD₃ R^(A16) H H H H H 110. CD₃ R^(A17) H H H H H 111. CD₃ R^(A18) H H H H H 112. CD₃ R^(A19) H H H H H 113. CD₃ R^(A20) H H H H H 114. CD₃ R^(A21) H H H H H 115. CD₃ R^(A22) H H H H H 116. CD₃ R^(A23) H H H H H 117. CD₃ R^(A24) H H H H H 118. CD₃ R^(A25) H H H H H 119. CD₃ R^(A26) H H H H H 120. CD₃ R^(A27) H H H H H 121. CD₃ R^(A28) H H H H H 122. CD₃ R^(A29) H H H H H 123. CD₃ R^(A30) H H H H H 124. CD₃ R^(A31) H H H H H 125. CD₃ R^(A32) H H H H H 126. CD₃ R^(A33) H H H H H 127. CD₃ R^(A34) H H H H H 128. CD₃ R^(A35) H H H H H 129. CD₃ R^(A36) H H H H H 130. CD₃ R^(A37) H H H H H 131. CD₃ R^(A38) H H H H H 132. CD₃ R^(A39) H H H H H 133. CD₃ R^(A40) H H H H H 134. CD₃ R^(A41) H H H H H 135. CD₃ R^(A42) H H H H H 136. CD₃ R^(A43) H H H H H 137. CD₃ R^(A44) H H H H H 138. CD₃ R^(A45) H H H H H 139. CD₃ R^(A46) H H H H H 140. CD₃ R^(A47) H H H H H 141. CD₃ R^(A48) H H H H H 142. CD₃ R^(A49) H H H H H 143. CD₃ R^(A50) H H H H H 144. CD₃ R^(A51) H H H H H 145. CD₃ R^(A52) H H H H H 146. CD₃ R^(A53) H H H H H 147. CD₃ R^(A54) H H H H H 148. CD₃ R^(A55) H H H H H 149. CD₃ R^(A56) H H H H H 150. CD₃ R^(A57) H H H H H 151. CD₃ R^(A58) H H H H H 152. CD₃ R^(A59) H H H H H 153. CD₃ R^(A60) H H H H H 154. CD₃ R^(A61) H H H H H 155. CD₃ R^(A62) H H H H H 156. CD₃ R^(A63) H H H H H 157. CD₃ R^(A64) H H H H H 158. CD₃ R^(A65) H H H H H 159. CD₃ R^(A66) H H H H H 160. CD₃ R^(A67) H H H H H 161. CD₃ R^(A68) H H H H H 162. CD₃ R^(A69) H H H H H 163. CD₃ R^(A70) H H H H H 164. CD₃ R^(A71) H H H H H 165. CD₃ R^(A72) H H H H H 166. CD₃ R^(A73) H H H H H 167. CD₃ R^(A74) H H H H H 168. CD₃ R^(A75) H H H H H 169. CD₃ R^(A76) H H H H H 170. CD₃ R^(A77) H H H H H 171. CD₃ R^(A78) H H H H H 172. CD₃ R^(A79) H H H H H 173. CD₃ R^(A80) H H H H H 174. CD₃ R^(A81) H H H H H 175. CD₃ R^(A82) H H H H H 176. CD₃ R^(A83) H H H H H 177. CD₃ R^(A84) H H H H H 178. CD₃ R^(A85) H H H H H 179. CD₃ R^(A86) H H H H H 180. CD₃ R^(A87) H H H H H 181. CD₃ R^(A88) H H H H H 182. CD₃ R^(A89) H H H H H 183. CD₃ R^(A90) H H H H H 184. CD₃ R^(A91) H H H H H 185. CD₃ R^(A92) H H H H H 186. CD₃ R^(A93) H H H H H 187. H R^(A1) H CD₃ H H H 188. H R^(A2) H CD₃ H H H 189. H R^(A3) H CD₃ H H H 190. H R^(A4) H CD₃ H H H 191. H R^(A5) H CD₃ H H H 192. H R^(A6) H CD₃ H H H 193. H R^(A7) H CD₃ H H H 194. H R^(A8) H CD₃ H H H 195. H R^(A10) H CD₃ H H H 196. H R^(A11) H CD₃ H H H 197. H R^(A12) H CD₃ H H H 198. H R^(A13) H CD₃ H H H 199. H R^(A14) H CD₃ H H H 200. H R^(A15) H CD₃ H H H 201. H R^(A16) H CD₃ H H H 202. H R^(A17) H CD₃ H H H 203. H R^(A18) H CD₃ H H H 204. H R^(A19) H CD₃ H H H 205. H R^(A20) H CD₃ H H H 206. H R^(A21) H CD₃ H H H 207. H R^(A22) H CD₃ H H H 208. H R^(A23) H CD₃ H H H 209. H R^(A24) H CD₃ H H H 210. H R^(A25) H CD₃ H H H 211. H R^(A26) H CD₃ H H H 212. H R^(A27) H CD₃ H H H 213. H R^(A28) H CD₃ H H H 214. H R^(A29) H CD₃ H H H 215. H R^(A30) H CD₃ H H H 216. H R^(A31) H CD₃ H H H 217. H R^(A32) H CD₃ H H H 218. H R^(A33) H CD₃ H H H 219. H R^(A34) H CD₃ H H H 220. H R^(A35) H CD₃ H H H 221. H R^(A36) H CD₃ H H H 222. H R^(A37) H CD₃ H H H 223. H R^(A38) H CD₃ H H H 224. H R^(A39) H CD₃ H H H 225. H R^(A40) H CD₃ H H H 226. H R^(A41) H CD₃ H H H 227. H R^(A42) H CD₃ H H H 228. H R^(A43) H CD₃ H H H 229. H R^(A44) H CD₃ H H H 230. H R^(A45) H CD₃ H H H 231. H R^(A46) H CD₃ H H H 232. H R^(A47) H CD₃ H H H 233. H R^(A48) H CD₃ H H H 234. H R^(A49) H CD₃ H H H 235. H R^(A50) H CD₃ H H H 236. H R^(A51) H CD₃ H H H 237. H R^(A52) H CD₃ H H H 238. H R^(A53) H CD₃ H H H 239. H R^(A54) H CD₃ H H H 240. H R^(A55) H CD₃ H H H 241. H R^(A56) H CD₃ H H H 242. H R^(A57) H CD₃ H H H 243. H R^(A58) H CD₃ H H H 244. H R^(A59) H CD₃ H H H 245. H R^(A60) H CD₃ H H H 246. H R^(A61) H CD₃ H H H 247. H R^(A62) H CD₃ H H H 248. H R^(A63) H CD₃ H H H 249. H R^(A64) H CD₃ H H H 250. H R^(A65) H CD₃ H H H 251. H R^(A66) H CD₃ H H H 252. H R^(A67) H CD₃ H H H 253. H R^(A68) H CD₃ H H H 254. H R^(A69) H CD₃ H H H 255. H R^(A70) H CD₃ H H H 256. H R^(A71) H CD₃ H H H 257. H R^(A72) H CD₃ H H H 258. H R^(A73) H CD₃ H H H 259. H R^(A74) H CD₃ H H H 260. H R^(A75) H CD₃ H H H 261. H R^(A76) H CD₃ H H H 262. H R^(A77) H CD₃ H H H 263. H R^(A78) H CD₃ H H H 264. H R^(A79) H CD₃ H H H 265. H R^(A80) H CD₃ H H H 266. H R^(A81) H CD₃ H H H 267. H R^(A82) H CD₃ H H H 268. H R^(A83) H CD₃ H H H 269. H R^(A84) H CD₃ H H H 270. H R^(A85) H CD₃ H H H 271. H R^(A86) H CD₃ H H H 272. H R^(A87) H CD₃ H H H 273. H R^(A88) H CD₃ H H H 274. H R^(A89) H CD₃ H H H 275. H R^(A90) H CD₃ H H H 276. H R^(A91) H CD₃ H H H 277. H R^(A92) H CD₃ H H H 278. H R^(A93) H CD₃ H H H 279. CD₃ R^(A1) H CD₃ H H H 280. CD₃ R^(A2) H CD₃ H H H 281. CD₃ R^(A3) H CD₃ H H H 282. CD₃ R^(A4) H CD₃ H H H 283. CD₃ R^(A5) H CD₃ H H H 284. CD₃ R^(A6) H CD₃ H H H 285. CD₃ R^(A7) H CD₃ H H H 286. CD₃ R^(A8) H CD₃ H H H 287. CD₃ R^(A9) H CD₃ H H H 288. CD₃ R^(A10) H CD₃ H H H 289. CD₃ R^(A11) H CD₃ H H H 290. CD₃ R^(A12) H CD₃ H H H 291. CD₃ R^(A13) H CD₃ H H H 292. CD₃ R^(A14) H CD₃ H H H 293. CD₃ R^(A15) H CD₃ H H H 294. CD₃ R^(A16) H CD₃ H H H 295. CD₃ R^(A17) H CD₃ H H H 296. CD₃ R^(A18) H CD₃ H H H 297. CD₃ R^(A19) H CD₃ H H H 298. CD₃ R^(A20) H CD₃ H H H 299. CD₃ R^(A21) H CD₃ H H H 300. CD₃ R^(A22) H CD₃ H H H 301. CD₃ R^(A23) H CD₃ H H H 302. CD₃ R^(A24) H CD₃ H H H 303. CD₃ R^(A25) H CD₃ H H H 304. CD₃ R^(A26) H CD₃ H H H 305. CD₃ R^(A27) H CD₃ H H H 306. CD₃ R^(A28) H CD₃ H H H 307. CD₃ R^(A29) H CD₃ H H H 308. CD₃ R^(A30) H CD₃ H H H 309. CD₃ R^(A31) H CD₃ H H H 310. CD₃ R^(A32) H CD₃ H H H 311. CD₃ R^(A33) H CD₃ H H H 312. CD₃ R^(A34) H CD₃ H H H 313. CD₃ R^(A35) H CD₃ H H H 314. CD₃ R^(A36) H CD₃ H H H 315. CD₃ R^(A37) H CD₃ H H H 316. CD₃ R^(A38) H CD₃ H H H 317. CD₃ R^(A39) H CD₃ H H H 318. CD₃ R^(A40) H CD₃ H H H 319. CD₃ R^(A41) H CD₃ H H H 320. CD₃ R^(A42) H CD₃ H H H 321. CD₃ R^(A43) H CD₃ H H H 322. CD₃ R^(A44) H CD₃ H H H 323. CD₃ R^(A45) H CD₃ H H H 324. CD₃ R^(A46) H CD₃ H H H 325. CD₃ R^(A47) H CD₃ H H H 326. CD₃ R^(A48) H CD₃ H H H 327. CD₃ R^(A49) H CD₃ H H H 328. CD₃ R^(A50) H CD₃ H H H 329. CD₃ R^(A51) H CD₃ H H H 330. CD₃ R^(A52) H CD₃ H H H 331. CD₃ R^(A53) H CD₃ H H H 332. CD₃ R^(A54) H CD₃ H H H 333. CD₃ R^(A55) H CD₃ H H H 334. CD₃ R^(A56) H CD₃ H H H 335. CD₃ R^(A57) H CD₃ H H H 336. CD₃ R^(A58) H CD₃ H H H 337. CD₃ R^(A59) H CD₃ H H H 338. CD₃ R^(A60) H CD₃ H H H 339. CD₃ R^(A61) H CD₃ H H H 340. CD₃ R^(A62) H CD₃ H H H 341. CD₃ R^(A63) H CD₃ H H H 342. CD₃ R^(A64) H CD₃ H H H 343. CD₃ R^(A65) H CD₃ H H H 344. CD₃ R^(A66) H CD₃ H H H 345. CD₃ R^(A67) H CD₃ H H H 346. CD₃ R^(A68) H CD₃ H H H 347. CD₃ R^(A69) H CD₃ H H H 348. CD₃ R^(A70) H CD₃ H H H 349. CD₃ R^(A71) H CD₃ H H H 350. CD₃ R^(A72) H CD₃ H H H 351. CD₃ R^(A73) H CD₃ H H H 352. CD₃ R^(A74) H CD₃ H H H 353. CD₃ R^(A75) H CD₃ H H H 354. CD₃ R^(A76) H CD₃ H H H 355. CD₃ R^(A77) H CD₃ H H H 356. CD₃ R^(A78) H CD₃ H H H 357. CD₃ R^(A79) H CD₃ H H H 358. CD₃ R^(A80) H CD₃ H H H 359. CD₃ R^(A81) H CD₃ H H H 360. CD₃ R^(A82) H CD₃ H H H 361. CD₃ R^(A83) H CD₃ H H H 362. CD₃ R^(A84) H CD₃ H H H 363. CD₃ R^(A85) H CD₃ H H H 364. CD₃ R^(A86) H CD₃ H H H 365. CD₃ R^(A87) H CD₃ H H H 366. CD₃ R^(A88) H CD₃ H H H 367. CD₃ R^(A89) H CD₃ H H H 368. CD₃ R^(A90) H CD₃ H H H 369. CD₃ R^(A91) H CD₃ H H H 370. CD₃ R^(A92) H CD₃ H H H 371. CD₃ R^(A93) H CD₃ H H H

An OLED is also disclosed, where the OLED comprises: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:

Formula I. In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution. X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″. Each of R′, R″, R¹, R², R³, R⁴, and R⁵ is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, alyloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. Any substitutions are optionally joined or fused into a ring. n is 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof. R has at least five carbon atoms.

In some embodiments of the OLED, each of R′, R″, R¹, R², R³, R⁴, and R⁵ is independently selected from the group consisting of hydrogen, deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, alyloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroalyl, nitrile, isonitrile, and combinations thereof.

In some embodiments of the OLED, the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

In some embodiments of the OLED, R in the compound has at least six carbon atoms. In some embodiments, R has at least seven carbon atoms.

A consumer product comprising the OLED is also disclosed. where the OLED comprises: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:

Formula I. In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution. X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. Any substitutions are optionally joined or fused into a ring. n is 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof. R has at least five carbon atoms.

In some embodiments, the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.

In some embodiments, the OLED further comprises a layer comprising a delayed fluorescent emitter. In some embodiments, the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement. In some embodiments, the OLED is a mobile device, a hand held device, or a wearable device. In some embodiments, the OLED is a display panel having less than 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a display panel having at least 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a lighting panel.

An emissive region in an organic light emitting device, the emissive region comprising a compound having the formula:

Formula I. In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution. X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroalyl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. Any substitutions are optionally joined or fused into a ring. n is 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof. R has at least five carbon atoms.

In some embodiments of the emissive region, the compound is an emissive dopant or a non-emissive dopant.

In some embodiments, the emissive region further comprises a host, wherein the host comprises at least one selected from the group consisting of metal complex, triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, aza-triphenylene, aza-carbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

In some embodiments, the emissive region further comprises a host, wherein the host is selected from the group consisting of:

and combinations thereof.

In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.

According to another aspect, a formulation comprising the compound described herein is also disclosed.

The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.

The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used may be a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂), CH═CH—C_(n)H_(2n+1), C≡C—C_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, and C_(n)H_(2n)—Ar₁, or the host has no substitutions. In the preceding substituents n can range from 1 to 10; and Ar₁ and Ar₂ can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound. For example a Zn containing inorganic material e.g. ZnS.

The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the group consisting of:

and combinations thereof. Additional information on possible hosts is provided below.

In yet another aspect of the present disclosure, a formulation that comprises the novel compound disclosed herein is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, and an electron transport layer material, disclosed herein.

Combination with Other Materials

The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804 and US2012146012.

A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphoric acid and silane derivatives; a metal oxide derivative, such as MoO_(x); a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, pelylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, alyloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the group consisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH) or N; Z¹⁰¹ NAr¹, O, or S; Ar¹ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40; (Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independently selected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In another aspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc⁺/Fc couple less than about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

EBL:

An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.

Host:

The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have the following general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴)) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴ are independently selected from C, N, O, P, and S; L¹⁰¹ is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

Examples of other organic compounds used as host are selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chysene, pelylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the following groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, alyloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroalyl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroalyl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20. X¹⁰¹ to X¹⁰⁸ are independently selected from C (including CH) or N. Z¹⁰¹ and Z¹⁰² are independently selected from NR¹⁰¹, O, or S.

Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,

Additional Emitters:

One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.

Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.

HBL:

A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of the following groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is an another ligand, k′ is an integer from 1 to 3. ETL:

Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.

In one aspect, compound used in ETL contains at least one of the following groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, alkoxy, alyloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroalyl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar¹ to Ar³ has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹ to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L¹⁰¹ is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.

EXPERIMENTAL Synthesis of Compound Ir(L_(a96)L_(b370))

Step 1

One 1 L 3-neck flask was charged with 2,4-dichloro-5-methylpyridine (15.28 g, 94 mmol), dibenzo[b,d]furan-4-ylboronic acid (20.0 g, 94 mmol), sodium carbonate (30.0 g, 283 mmol), DME (400 ml), water (40 ml) and tetrakis(triphenylphosphine)palladium(0) (2.180 g, 1.887 mmol). The reaction mixture was heated to reflux for 16 hrs. The reaction was then diluted with 150 ml water and extracted with 3×100 ml EtOAc. The extracts were washed with 100 ml water, dried and evaporated to dryness. The residue was purified by column chromatography (SiO2) to yield the desired product (19.8 g).

Step 2

One 500 ml 3-neck oven dried flask was charged with Pd2(dba)3 (0.411 g, 0.449 mmol), X phos (0.857 g, 1.797 mmol), 4-chloro-2-(dibenzo[b,d]furan-4-yl)-5-methylpyridine (4.4 g, 14.98 mmol), THF (75 ml) and cyclohexylzinc(II) bromide (0.5M in THF) (44.9 ml, 22.47 mmol). The reaction was heated to 65° C. for 24 hours. The reaction was then diluted with 150 ml water and extracted with 3×100 ml EtOAc. The extracts were washed with 100 ml water, dried and evaporated to dryness. The residue was purified by column chromatography (SiO2) to yield the desired product (9.3 g).

Step 3

One 200 ml flask was charged with 4-cyclohexyl-2-(dibenzo[b,d]furan-4-yl)-5-methylpyridine (4.7 g, 13.76 mmol), DMSO-d6 (38.5 ml, 551 mmol) and sodium 2-methylpropan-2-olate (0.661 g, 6.88 mmol). The reaction was heated to 60° C. for overnight. The reaction was then diluted with 150 ml water and extracted with 3×100 ml EtOAc. The extracts were washed with 100 ml water, dried and evaporated to dryness. The residue was purified by column chromatography (SiO2) to yield the desired product (4.2 g).

Step 4

One 250 ml r.b. flask was charged with 4-(cyclohexyl-1-d)-2-(dibenzo[b,d]furan-4-yl)-5-(methyl-d3)pyridine (1.76 g, 5.12 mmol), Iridium metal complexes (2.0 g, 2.56 mmol), Methanol (30 ml) and Ethanol (30.0 ml). The reaction was heated to 80° C. for 5 days. The solvent was evaporated to dryness. The residue was purified by column chromatography (SiO2) to yield the desired product (0.55 g).

DEVICE EXAMPLES

All example devices were fabricated by high vacuum (<10⁻⁷ Torr) thermal evaporation. The anode electrode was 800 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium) followed by 1,000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H₂O and O₂) immediately after fabrication with a moisture getter incorporated inside the package. The organic stack of the device examples consisted of sequentially, from the ITO Surface: 100 Å of HAT-CN as the hole injection layer (HIL); 450 Å of HTM as a hole transporting layer (HTL); emissive layer (EML) with thickness 400 Å. Emissive layer containing H-host (H1): E-host (H2) in 6:4 ratio and 12 weight % of green emitter; 350 Å of Liq (8-hydroxyquinoline lithium) doped with 40% of ETM as the ETL. The device structure is shown in Table 1 below. Table 1 shows the schematic device structure. The chemical structures of the device materials are shown below.

Upon fabrication, electroluminance (EL) and current density-voltage-luminance (J-V-L) of the devices were measured at DC 10 mA/cm². Device performance is tabulated in Table 2 below.

TABLE 1 schematic device structure Layer Material Thickness [Å] Anode ITO 800 HIL HAT-CN 100 HTL HTM 450 Green EML H1:H2: example dopant 400 ETL Liq: ETM 40% 350 EIL Liq 10 Cathode Al 1,000

TABLE 2 Device performance 1931 CIE At 10 mA/cm²* λ max FWHM Voltage LE EQE PE Emitter 12% X Y [nm] [nm] [a.u.] [a.u.] [a.u.] [a.u.] Ir(L_(A96)L_(B370)) 0.323 0.633 520 62 0.97 1.03 1.03 1.04 Comparative 0.325 0.631 520 63 1.00 1.00 1.00 1.00 Example Data are normalized to the comparative example.

Referring to Table 2, comparing Ir(L_(A96)L_(B370)) with the comparative example; the inventive compound has higher efficiency and lower voltage than the comparative compound. Presumbly, the alkyl substitution in the peripheral ring has better alignment with transition dipolar moment of the molecule. The concept is illustrated in the diagram shown in FIG. 3 .

It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting. 

We claim:
 1. A compound having the formula [L_(A)]_(3-n)Ir[L_(B)]_(n), having the structure:

wherein R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution; wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″; wherein R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any substitutions are optionally joined or fused into a ring; wherein n is 1 or 2; wherein R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof; and wherein R has at least five carbon atoms.
 2. The compound of claim 1, wherein R has at least six carbon atoms.
 3. The compound of claim 1, wherein R has at least seven carbon atoms.
 4. The compound of claim 1, wherein n is
 2. 5. The compound of claim 1, wherein X is O.
 6. The compound of claim 1, wherein R comprises a cycloalkyl or heterocycloalkyl.
 7. The compound of claim 1, wherein R¹, R², R³, R⁴ and R⁵ are each independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, aryl, and combinations thereof.
 8. The compound of claim 1, wherein R is selected from the group consisting of:


9. The compound of claim 1, wherein the compound is selected from the group consisting of:

wherein R⁶ is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
 10. The compound of claim 8, wherein L_(A) is selected from the group consisting of L_(A1) to L_(A371) having a structure according to

in which R, R¹, R^(A), R^(B), R^(C), R^(D), and R^(E) are defined as provided below: L_(Ai), where i is R¹ R R^(A) R^(B) R^(C) R^(D) R^(E)
 1. H R^(A1) H H H H H
 2. H R^(A2) H H H H H
 3. H R^(A3) H H H H H
 4. H R^(A4) H H H H H
 5. H R^(A5) H H H H H
 6. H R^(A6) H H H H H
 7. H R^(A7) H H H H H
 8. H R^(A8) H H H H H
 9. H R^(A9) H H H H H
 10. H R^(A10) H H H H H
 11. H R^(A11) H H H H H
 12. H R^(A12) H H H H H
 13. H R^(A13) H H H H H
 14. H R^(A14) H H H H H
 15. H R^(A15) H H H H H
 16. H R^(A16) H H H H H
 17. H R^(A17) H H H H H
 18. H R^(A18) H H H H H
 19. H R^(A19) H H H H H
 20. H R^(A20) H H H H H
 21. H R^(A21) H H H H H
 22. H R^(A22) H H H H H
 23. H R^(A23) H H H H H
 24. H R^(A24) H H H H H
 25. H R^(A25) H H H H H
 26. H R^(A26) H H H H H
 27. H R^(A27) H H H H H
 28. H R^(A28) H H H H H
 29. H R^(A29) H H H H H
 30. H R^(A30) H H H H H
 31. H R^(A31) H H H H H
 32. H R^(A32) H H H H H
 33. H R^(A33) H H H H H
 34. H R^(A34) H H H H H
 35. H R^(A35) H H H H H
 36. H R^(A36) H H H H H
 37. H R^(A37) H H H H H
 38. H R^(A38) H H H H H
 39. H R^(A39) H H H H H
 40. H R^(A40) H H H H H
 41. H R^(A41) H H H H H
 42. H R^(A42) H H H H H
 43. H R^(A43) H H H H H
 44. H R^(A44) H H H H H
 45. H R^(A45) H H H H H
 46. H R^(A46) H H H H H
 47. H R^(A47) H H H H H
 48. H R^(A48) H H H H H
 49. H R^(A49) H H H H H
 50. H R^(A50) H H H H H
 51. H R^(A51) H H H H H
 52. H R^(A52) H H H H H
 53. H R^(A53) H H H H H
 54. H R^(A54) H H H H H
 55. H R^(A55) H H H H H
 56. H R^(A56) H H H H H
 57. H R^(A57) H H H H H
 58. H R^(A58) H H H H H
 59. H R^(A59) H H H H H
 60. H R^(A60) H H H H H
 61. H R^(A61) H H H H H
 62. H R^(A62) H H H H H
 63. H R^(A63) H H H H H
 64. H R^(A64) H H H H H
 65. H R^(A65) H H H H H
 66. H R^(A66) H H H H H
 67. H R^(A67) H H H H H
 68. H R^(A68) H H H H H
 69. H R^(A69) H H H H H
 70. H R^(A70) H H H H H
 71. H R^(A71) H H H H H
 72. H R^(A72) H H H H H
 73. H R^(A73) H H H H H
 74. H R^(A74) H H H H H
 75. H R^(A75) H H H H H
 76. H R^(A76) H H H H H
 77. H R^(A77) H H H H H
 78. H R^(A78) H H H H H
 79. H R^(A79) H H H H H
 80. H R^(A80) H H H H H
 81. H R^(A81) H H H H H
 82. H R^(A82) H H H H H
 83. H R^(A83) H H H H H
 84. H R^(A84) H H H H H
 85. H R^(A85) H H H H H
 86. H R^(A86) H H H H H
 87. H R^(A87) H H H H H
 88. H R^(A88) H H H H H
 89. H R^(A89) H H H H H
 90. H R^(A90) H H H H H
 91. H R^(A91) H H H H H
 92. H R^(A92) H H H H H
 93. H R^(A93) H H H H H
 94. CD₃ R^(A1) H H H H H
 95. CD₃ R^(A2) H H H H H
 96. CD₃ R^(A3) H H H H H
 97. CD₃ R^(A4) H H H H H
 98. CD₃ R^(A5) H H H H H
 99. CD₃ R^(A6) H H H H H
 100. CD₃ R^(A7) H H H H H
 101. CD₃ R^(A8) H H H H H
 102. CD₃ R^(A9) H H H H H
 103. CD₃ R^(A10) H H H H H
 104. CD₃ R^(A11) H H H H H
 105. CD₃ R^(A12) H H H H H
 106. CD₃ R^(A13) H H H H H
 107. CD₃ R^(A14) H H H H H
 108. CD₃ R^(A15) H H H H H
 109. CD₃ R^(A16) H H H H H
 110. CD₃ R^(A17) H H H H H
 111. CD₃ R^(A18) H H H H H
 112. CD₃ R^(A19) H H H H H
 113. CD₃ R^(A20) H H H H H
 114. CD₃ R^(A21) H H H H H
 115. CD₃ R^(A22) H H H H H
 116. CD₃ R^(A23) H H H H H
 117. CD₃ R^(A24) H H H H H
 118. CD₃ R^(A25) H H H H H
 119. CD₃ R^(A26) H H H H H
 120. CD₃ R^(A27) H H H H H
 121. CD₃ R^(A28) H H H H H
 122. CD₃ R^(A29) H H H H H
 123. CD₃ R^(A30) H H H H H
 124. CD₃ R^(A31) H H H H H
 125. CD₃ R^(A32) H H H H H
 126. CD₃ R^(A33) H H H H H
 127. CD₃ R^(A34) H H H H H
 128. CD₃ R^(A35) H H H H H
 129. CD₃ R^(A36) H H H H H
 130. CD₃ R^(A37) H H H H H
 131. CD₃ R^(A38) H H H H H
 132. CD₃ R^(A39) H H H H H
 133. CD₃ R^(A40) H H H H H
 134. CD₃ R^(A41) H H H H H
 135. CD₃ R^(A42) H H H H H
 136. CD₃ R^(A43) H H H H H
 137. CD₃ R^(A44) H H H H H
 138. CD₃ R^(A45) H H H H H
 139. CD₃ R^(A46) H H H H H
 140. CD₃ R^(A47) H H H H H
 141. CD₃ R^(A48) H H H H H
 142. CD₃ R^(A49) H H H H H
 143. CD₃ R^(A50) H H H H H
 144. CD₃ R^(A51) H H H H H
 145. CD₃ R^(A52) H H H H H
 146. CD₃ R^(A53) H H H H H
 147. CD₃ R^(A54) H H H H H
 148. CD₃ R^(A55) H H H H H
 149. CD₃ R^(A56) H H H H H
 150. CD₃ R^(A57) H H H H H
 151. CD₃ R^(A58) H H H H H
 152. CD₃ R^(A59) H H H H H
 153. CD₃ R^(A60) H H H H H
 154. CD₃ R^(A61) H H H H H
 155. CD₃ R^(A62) H H H H H
 156. CD₃ R^(A63) H H H H H
 157. CD₃ R^(A64) H H H H H
 158. CD₃ R^(A65) H H H H H
 159. CD₃ R^(A66) H H H H H
 160. CD₃ R^(A67) H H H H H
 161. CD₃ R^(A68) H H H H H
 162. CD₃ R^(A69) H H H H H
 163. CD₃ R^(A70) H H H H H
 164. CD₃ R^(A71) H H H H H
 165. CD₃ R^(A72) H H H H H
 166. CD₃ R^(A73) H H H H H
 167. CD₃ R^(A74) H H H H H
 168. CD₃ R^(A75) H H H H H
 169. CD₃ R^(A76) H H H H H
 170. CD₃ R^(A77) H H H H H
 171. CD₃ R^(A78) H H H H H
 172. CD₃ R^(A79) H H H H H
 173. CD₃ R^(A80) H H H H H
 174. CD₃ R^(A81) H H H H H
 175. CD₃ R^(A82) H H H H H
 176. CD₃ R^(A83) H H H H H
 177. CD₃ R^(A84) H H H H H
 178. CD₃ R^(A85) H H H H H
 179. CD₃ R^(A86) H H H H H
 180. CD₃ R^(A87) H H H H H
 181. CD₃ R^(A88) H H H H H
 182. CD₃ R^(A89) H H H H H
 183. CD₃ R^(A90) H H H H H
 184. CD₃ R^(A91) H H H H H
 185. CD₃ R^(A92) H H H H H
 186. CD₃ R^(A93) H H H H H
 187. H R^(A1) H CD₃ H H H
 188. H R^(A2) H CD₃ H H H
 189. H R^(A3) H CD₃ H H H
 190. H R^(A4) H CD₃ H H H
 191. H R^(A5) H CD₃ H H H
 192. H R^(A6) H CD₃ H H H
 193. H R^(A7) H CD₃ H H H
 194. H R^(A8) H CD₃ H H H
 195. H R^(A10) H CD₃ H H H
 196. H R^(A11) H CD₃ H H H
 197. H R^(A12) H CD₃ H H H
 198. H R^(A13) H CD₃ H H H
 199. H R^(A14) H CD₃ H H H
 200. H R^(A15) H CD₃ H H H
 201. H R^(A16) H CD₃ H H H
 202. H R^(A17) H CD₃ H H H
 203. H R^(A18) H CD₃ H H H
 204. H R^(A19) H CD₃ H H H
 205. H R^(A20) H CD₃ H H H
 206. H R^(A21) H CD₃ H H H
 207. H R^(A22) H CD₃ H H H
 208. H R^(A23) H CD₃ H H H
 209. H R^(A24) H CD₃ H H H
 210. H R^(A25) H CD₃ H H H
 211. H R^(A26) H CD₃ H H H
 212. H R^(A27) H CD₃ H H H
 213. H R^(A28) H CD₃ H H H
 214. H R^(A29) H CD₃ H H H
 215. H R^(A30) H CD₃ H H H
 216. H R^(A31) H CD₃ H H H
 217. H R^(A32) H CD₃ H H H
 218. H R^(A33) H CD₃ H H H
 219. H R^(A34) H CD₃ H H H
 220. H R^(A35) H CD₃ H H H
 221. H R^(A36) H CD₃ H H H
 222. H R^(A37) H CD₃ H H H
 223. H R^(A38) H CD₃ H H H
 224. H R^(A39) H CD₃ H H H
 225. H R^(A40) H CD₃ H H H
 226. H R^(A41) H CD₃ H H H
 227. H R^(A42) H CD₃ H H H
 228. H R^(A43) H CD₃ H H H
 229. H R^(A44) H CD₃ H H H
 230. H R^(A45) H CD₃ H H H
 231. H R^(A46) H CD₃ H H H
 232. H R^(A47) H CD₃ H H H
 233. H R^(A48) H CD₃ H H H
 234. H R^(A49) H CD₃ H H H
 235. H R^(A50) H CD₃ H H H
 236. H R^(A51) H CD₃ H H H
 237. H R^(A52) H CD₃ H H H
 238. H R^(A53) H CD₃ H H H
 239. H R^(A54) H CD₃ H H H
 240. H R^(A55) H CD₃ H H H
 241. H R^(A56) H CD₃ H H H
 242. H R^(A57) H CD₃ H H H
 243. H R^(A58) H CD₃ H H H
 244. H R^(A59) H CD₃ H H H
 245. H R^(A60) H CD₃ H H H
 246. H R^(A61) H CD₃ H H H
 247. H R^(A62) H CD₃ H H H
 248. H R^(A63) H CD₃ H H H
 249. H R^(A64) H CD₃ H H H
 250. H R^(A65) H CD₃ H H H
 251. H R^(A66) H CD₃ H H H
 252. H R^(A67) H CD₃ H H H
 253. H R^(A68) H CD₃ H H H
 254. H R^(A69) H CD₃ H H H
 255. H R^(A70) H CD₃ H H H
 256. H R^(A71) H CD₃ H H H
 257. H R^(A72) H CD₃ H H H
 258. H R^(A73) H CD₃ H H H
 259. H R^(A74) H CD₃ H H H
 260. H R^(A75) H CD₃ H H H
 261. H R^(A76) H CD₃ H H H
 262. H R^(A77) H CD₃ H H H
 263. H R^(A78) H CD₃ H H H
 264. H R^(A79) H CD₃ H H H
 265. H R^(A80) H CD₃ H H H
 266. H R^(A81) H CD₃ H H H
 267. H R^(A82) H CD₃ H H H
 268. H R^(A83) H CD₃ H H H
 269. H R^(A84) H CD₃ H H H
 270. H R^(A85) H CD₃ H H H
 271. H R^(A86) H CD₃ H H H
 272. H R^(A87) H CD₃ H H H
 273. H R^(A88) H CD₃ H H H
 274. H R^(A89) H CD₃ H H H
 275. H R^(A90) H CD₃ H H H
 276. H R^(A91) H CD₃ H H H
 277. H R^(A92) H CD₃ H H H
 278. H R^(A93) H CD₃ H H H
 279. CD₃ R^(A1) H CD₃ H H H
 280. CD₃ R^(A2) H CD₃ H H H
 281. CD₃ R^(A3) H CD₃ H H H
 282. CD₃ R^(A4) H CD₃ H H H
 283. CD₃ R^(A5) H CD₃ H H H
 284. CD₃ R^(A6) H CD₃ H H H
 285. CD₃ R^(A7) H CD₃ H H H
 286. CD₃ R^(A8) H CD₃ H H H
 287. CD₃ R^(A9) H CD₃ H H H
 288. CD₃ R^(A10) H CD₃ H H H
 289. CD₃ R^(A11) H CD₃ H H H
 290. CD₃ R^(A12) H CD₃ H H H
 291. CD₃ R^(A13) H CD₃ H H H
 292. CD₃ R^(A14) H CD₃ H H H
 293. CD₃ R^(A15) H CD₃ H H H
 294. CD₃ R^(A16) H CD₃ H H H
 295. CD₃ R^(A17) H CD₃ H H H
 296. CD₃ R^(A18) H CD₃ H H H
 297. CD₃ R^(A19) H CD₃ H H H
 298. CD₃ R^(A20) H CD₃ H H H
 299. CD₃ R^(A21) H CD₃ H H H
 300. CD₃ R^(A22) H CD₃ H H H
 301. CD₃ R^(A23) H CD₃ H H H
 302. CD₃ R^(A24) H CD₃ H H H
 303. CD₃ R^(A25) H CD₃ H H H
 304. CD₃ R^(A26) H CD₃ H H H
 305. CD₃ R^(A27) H CD₃ H H H
 306. CD₃ R^(A28) H CD₃ H H H
 307. CD₃ R^(A29) H CD₃ H H H
 308. CD₃ R^(A30) H CD₃ H H H
 309. CD₃ R^(A31) H CD₃ H H H
 310. CD₃ R^(A32) H CD₃ H H H
 311. CD₃ R^(A33) H CD₃ H H H
 312. CD₃ R^(A34) H CD₃ H H H
 313. CD₃ R^(A35) H CD₃ H H H
 314. CD₃ R^(A36) H CD₃ H H H
 315. CD₃ R^(A37) H CD₃ H H H
 316. CD₃ R^(A38) H CD₃ H H H
 317. CD₃ R^(A39) H CD₃ H H H
 318. CD₃ R^(A40) H CD₃ H H H
 319. CD₃ R^(A41) H CD₃ H H H
 320. CD₃ R^(A42) H CD₃ H H H
 321. CD₃ R^(A43) H CD₃ H H H
 322. CD₃ R^(A44) H CD₃ H H H
 323. CD₃ R^(A45) H CD₃ H H H
 324. CD₃ R^(A46) H CD₃ H H H
 325. CD₃ R^(A47) H CD₃ H H H
 326. CD₃ R^(A48) H CD₃ H H H
 327. CD₃ R^(A49) H CD₃ H H H
 328. CD₃ R^(A50) H CD₃ H H H
 329. CD₃ R^(A51) H CD₃ H H H
 330. CD₃ R^(A52) H CD₃ H H H
 331. CD₃ R^(A53) H CD₃ H H H
 332. CD₃ R^(A54) H CD₃ H H H
 333. CD₃ R^(A55) H CD₃ H H H
 334. CD₃ R^(A56) H CD₃ H H H
 335. CD₃ R^(A57) H CD₃ H H H
 336. CD₃ R^(A58) H CD₃ H H H
 337. CD₃ R^(A59) H CD₃ H H H
 338. CD₃ R^(A60) H CD₃ H H H
 339. CD₃ R^(A61) H CD₃ H H H
 340. CD₃ R^(A62) H CD₃ H H H
 341. CD₃ R^(A63) H CD₃ H H H
 342. CD₃ R^(A64) H CD₃ H H H
 343. CD₃ R^(A65) H CD₃ H H H
 344. CD₃ R^(A66) H CD₃ H H H
 345. CD₃ R^(A67) H CD₃ H H H
 346. CD₃ R^(A68) H CD₃ H H H
 347. CD₃ R^(A69) H CD₃ H H H
 348. CD₃ R^(A70) H CD₃ H H H
 349. CD₃ R^(A71) H CD₃ H H H
 350. CD₃ R^(A72) H CD₃ H H H
 351. CD₃ R^(A73) H CD₃ H H H
 352. CD₃ R^(A74) H CD₃ H H H
 353. CD₃ R^(A75) H CD₃ H H H
 354. CD₃ R^(A76) H CD₃ H H H
 355. CD₃ R^(A77) H CD₃ H H H
 356. CD₃ R^(A78) H CD₃ H H H
 357. CD₃ R^(A79) H CD₃ H H H
 358. CD₃ R^(A80) H CD₃ H H H
 359. CD₃ R^(A81) H CD₃ H H H
 360. CD₃ R^(A82) H CD₃ H H H
 361. CD₃ R^(A83) H CD₃ H H H
 362. CD₃ R^(A84) H CD₃ H H H
 363. CD₃ R^(A85) H CD₃ H H H
 364. CD₃ R^(A86) H CD₃ H H H
 365. CD₃ R^(A87) H CD₃ H H H
 366. CD₃ R^(A88) H CD₃ H H H
 367. CD₃ R^(A89) H CD₃ H H H
 368. CD₃ R^(A90) H CD₃ H H H
 369. CD₃ R^(A91) H CD₃ H H H
 370. CD₃ R^(A92) H CD₃ H H H
 371. CD₃ R^(A93) H CD₃ H H  H.


11. The compound of claim 1, wherein L_(B) is selected from the group consisting of L_(B1) to L_(B1471) having a structure according to

wherein R^(B1), R^(B2), R^(B3), and R^(B4) are defined as provided below: L_(Bi), where i is R^(B1) R^(B2) R^(B3) R^(B4)
 1. H H H H
 2. CH₃ H H H
 3. H CH₃ H H
 4. H H CH₃ H
 5. CH₃ CH₃ H CH₃
 6. CH₃ H CH₃ H
 7. CH₃ H H CH₃
 8. H CH₃ CH₃ H
 9. H CH₃ H CH₃
 10. H H CH₃ CH₃
 11. CH₃ CH₃ CH₃ H
 12. CH₃ CH₃ H CH₃
 13. CH₃ H CH₃ CH₃
 14. H CH₃ CH₃ CH₃
 15. CH₃ CH₃ CH₃ CH₃
 16. CH₂CH₃ H H H
 17. CH₂CH₃ CH₃ H CH₃
 18. CH₂CH₃ H CH₃ H
 19. CH₂CH₃ H H CH₃
 20. CH₂CH₃ CH₃ CH₃ H
 21. CH₂CH₃ CH₃ H CH₃
 22. CH₂CH₃ H CH₃ CH₃
 23. CH₂CH₃ CH₃ CH₃ CH₃
 24. H CH₂CH₃ H H
 25. CH₃ CH₂CH₃ H CH₃
 26. H CH₂CH₃ CH₃ H
 27. H CH₂CH₃ H CH₃
 28. CH₃ CH₂CH₃ CH₃ H
 29. CH₃ CH₂CH₃ H CH₃
 30. H CH₂CH₃ CH₃ CH₃
 31. CH₃ CH₂CH₃ CH₃ CH₃
 32. H H CH₂CH₃ H
 33. CH₃ H CH₂CH₃ H
 34. H CH₃ CH₂CH₃ H
 35. H H CH₂CH₃ CH₃
 36. CH₃ CH₃ CH₂CH₃ H
 37. CH₃ H CH₂CH₃ CH₃
 38. H CH₃ CH₂CH₃ CH₃
 39. CH₃ CH₃ CH₂CH₃ CH₃
 40. CH(CH₃)₂ H H H
 41. CH(CH₃)₂ CH₃ H CH₃
 42. CH(CH₃)₂ H CH₃ H
 43. CH(CH₃)₂ H H CH₃
 44. CH(CH₃)₂ CH₃ CH₃ H
 45. CH(CH₃)₂ CH₃ H CH₃
 46. CH(CH₃)₂ H CH₃ CH₃
 47. CH(CH₃)₂ CH₃ CH₃ CH₃
 48. H CH(CH₃)₂ H H
 49. CH₃ CH(CH₃)₂ H CH₃
 50. H CH(CH₃)₂ CH₃ H
 51. H CH(CH₃)₂ H CH₃
 52. CH₃ CH(CH₃)₂ CH₃ H
 53. CH₃ CH(CH₃)₂ H CH₃
 54. H CH(CH₃)₂ CH₃ CH₃
 55. CH₃ CH(CH₃)₂ CH₃ CH₃
 56. H H CH(CH₃)₂ H
 57. CH₃ H CH(CH₃)₂ H
 58. H CH₃ CH(CH₃)₂ H
 59. H H CH(CH₃)₂ CH₃
 60. CH₃ CH₃ CH(CH₃)₂ H
 61. CH₃ H CH(CH₃)₂ CH₃
 62. H CH₃ CH(CH₃)₂ CH₃
 63. CH₃ CH₃ CH(CH₃)₂ CH₃
 64. CH₂CH(CH₃)₂ H H H
 65. CH₂CH(CH₃)₂ CH₃ H CH₃
 66. CH₂CH(CH₃)₂ H CH₃ H
 67. CH₂CH(CH₃)₂ H H CH₃
 68. CH₂CH(CH₃)₂ CH₃ CH₃ H
 69. CH₂CH(CH₃)₂ CH₃ H CH₃
 70. CH₂CH(CH₃)₂ H CH₃ CH₃
 71. CH₂CH(CH₃)₂ CH₃ CH₃ CH₃
 72. H CH₂CH(CH₃)₂ H H
 73. CH₃ CH₂CH(CH₃)₂ H CH₃
 74. H CH₂CH(CH₃)₂ CH₃ H
 75. H CH₂CH(CH₃)₂ H CH₃
 76. CH₃ CH₂CH(CH₃)₂ CH₃ H
 77. CH₃ CH₂CH(CH₃)₂ H CH₃
 78. H CH₂CH(CH₃)₂ CH₃ CH₃
 79. CH₃ CH₂CH(CH₃)₂ CH₃ CH₃
 80. H H CH₂CH(CH₃)₂ H
 81. CH₃ H CH₂CH(CH₃)₂ H
 82. H CH₃ CH₂CH(CH₃)₂ H
 83. H H CH₂CH(CH₃)₂ CH₃
 84. CH₃ CH₃ CH₂CH(CH₃)₂ H
 85. CH₃ H CH₂CH(CH₃)₂ CH₃
 86. H CH₃ CH₂CH(CH₃)₂ CH₃
 87. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃
 88. C(CH₃)₃ H H H
 89. C(CH₃)₃ CH₃ H CH₃
 90. C(CH₃)₃ H CH₃ H
 91. C(CH₃)₃ H H C(CH₃)₃
 92. C(CH₃)₃ CH₃ CH₃ H
 93. C(CH₃)₃ CH₃ H CH₃
 94. C(CH₃)₃ H CH₃ CH₃
 95. C(CH₃)₃ CH₃ CH₃ CH₃
 96. H C(CH₃)₃ H H
 97. CH₃ C(CH₃)₃ H CH₃
 98. H C(CH₃)₃ CH₃ H
 99. H C(CH₃)₃ H CH₃
 100. CH₃ C(CH₃)₃ CH₃ H
 101. CH₃ C(CH₃)₃ H CH₃
 102. H C(CH₃)₃ CH₃ CH₃
 103. CH₃ C(CH₃)₃ CH₃ CH₃
 104. H H C(CH₃)₃ H
 105. CH₃ H C(CH₃)₃ H
 106. H CH₃ C(CH₃)₃ H
 107. H H C(CH₃)₃ CH₃
 108. CH₃ CH₃ C(CH₃)₃ H
 109. CH₃ H C(CH₃)₃ CH₃
 110. H CH₃ C(CH₃)₃ CH₃
 111. CH₃ CH₃ C(CH₃)₃ CH₃
 112. CH₂(CH₃)₃ H H H
 113. CH₂(CH₃)₃ CH₃ H CH₃
 114. CH₂(CH₃)₃ H CH₃ H
 115. CH₂(CH₃)₃ H H CH₃
 116. CH₂(CH₃)₃ CH₃ CH₃ H
 117. CH₂(CH₃)₃ CH₃ H CH₃
 118. CH₂(CH₃)₃ H CH₃ CH₃
 119. CH₂(CH₃)₃ CH₃ CH₃ CH₃
 120. H CH₂(CH₃)₃ H H
 121. CH₃ CH₂(CH₃)₃ H CH₃
 122. H CH₂(CH₃)₃ CH₃ H
 123. H CH₂(CH₃)₃ H CH₃
 124. CH₃ CH₂(CH₃)₃ CH₃ H
 125. CH₃ CH₂(CH₃)₃ H CH₃
 126. H CH₂(CH₃)₃ CH₃ CH₃
 127. CH₃ CH₂(CH₃)₃ CH₃ CH₃
 128. H H CH₂(CH₃)₃ H
 129. CH₃ H CH₂(CH₃)₃ H
 130. H CH₃ CH₂(CH₃)₃ H
 131. H H CH₂(CH₃)₃ CH₃
 132. CH₃ CH₃ CH₂(CH₃)₃ H
 133. CH₃ H CH₂(CH₃)₃ CH₃
 134. H CH₃ CH₂(CH₃)₃ CH₃
 135. CH₃ CH₃ CH₂(CH₃)₃ CH₃
 136.

H H H
 137.

CH₃ H CH₃
 138.

H CH₃ H
 139.

H H CH₃
 140.

CH₃ CH₃ H
 141.

CH₃ H CH₃
 142.

H CH₃ CH₃
 143.

CH₃ CH₃ CH₃
 144. H

H H
 145. CH₃

H CH₃
 146. H

CH₃ H
 147. H

H CH₃
 148. CH₃

CH₃ H
 149. CH₃

H CH₃
 150. H

CH₃ CH₃
 151. CH₃

CH₃ CH₃
 152. H H

H
 153. CH₃ H

H
 154. H CH₃

H
 155. H H

CH₃
 156. CH₃ CH₃

H
 157. CH₃ H

CH₃
 158. H CH₃

CH₃
 159. CH₃ CH₃

CH₃
 160.

H H H
 161.

H CH₃ H
 162.

H CH₃ H
 163.

H H CH₃
 164.

CH₃ CH₃ H
 165.

CH₃ H CH₃
 166.

H CH₃ CH₃
 167.

CH₃ CH₃ CH₃
 168. H

H H
 169. CH₃

H CH₃
 170. H

CH₃ H
 171. H

H CH₃
 172. CH₃

CH₃ H
 173. CH₃

H CH₃
 174. H

CH₃ CH₃
 175. CH₃

CH₃ CH₃
 176. H H

H
 177. CH₃ H

H
 178. H CH₃

H
 179. H H

CH₃
 180. CH₃ CH₃

H
 181. CH₃ H

CH₃
 182. H CH₃

CH₃
 183. CH₃ CH₃

CH₃
 184.

H H H
 185.

CH₃ H CH₃
 186.

H CH₃ H
 187.

H H CH₃
 188.

CH₃ CH₃ H
 189.

CH₃ H CH₃
 190.

H CH₃ CH₃
 191.

CH₃ CH₃ CH₃
 192. H

H H
 193. CH₃

H CH₃
 194. H

CH₃ H
 195. H

H CH₃
 196. CH₃

CH₃ H
 197. CH₃

H CH₃
 198. H

CH₃ CH₃
 199. CH₃

CH₃ CH₃
 200. H H

H
 201. CH₃ H

H
 202. H CH₃

H
 203. H H

CH₃
 204. CH₃ CH₃

H
 205. CH₃ H

CH₃
 206. H CH₃

CH₃
 207. CH₃ CH₃

CH₃
 208.

H H H
 209.

CH₃ H CH₃
 210.

H CH₃ H
 211.

H H CH₃
 212.

CH₃ CH₃ H
 213.

CH₃ H CH₃
 214.

H CH₃ CH₃
 215.

CH₃ CH₃ CH₃
 216. H

H H
 217. CH₃

H CH₃
 218. H

CH₃ H
 219. H

H CH₃
 220. CH₃

CH₃ H
 221. CH₃

H CH₃
 222. H

CH₃ CH₃
 223. CH₃

CH₃ CH₃
 224. H H

H
 225. CH₃ H

H
 226. H CH₃

H
 227. H H

CH₃
 228. CH₃ CH₃

H
 229. CH₃ H

CH₃
 230. H CH₃

CH₃
 231. CH₃ CH₃

CH₃
 232.

H H H
 233.

CH₃ H CH₃
 234.

H CH₃ H
 235.

H H CH₃
 236.

CH₃ CH₃ H
 237.

CH₃ H CH₃
 238.

H CH₃ CH₃
 239.

CH₃ CH₃ CH₃
 240. H

H H
 241. CH₃

H CH₃
 242. H

CH₃ H
 243. H

H CH₃
 244. CH₃

CH₃ H
 245. CH₃

H CH₃
 246. H

CH₃ CH₃
 247. CH₃

CH₃ CH₃
 248. H H

H
 249. CH₃ H

H
 250. H CH₃

H
 251. H H

CH₃
 252. CH₃ CH₃

H
 253. CH₃ H

CH₃
 254. H CH₃

CH₃
 255. CH₃ CH₃

CH₃
 256.

H H H
 257.

CH₃ H CH₃
 258.

H CH₃ H
 259.

H H CH₃
 260.

CH₃ CH₃ H
 261.

CH₃ H CH₃
 262.

H CH₃ CH₃
 263.

CH₃ CH₃ CH₃
 264. H

H H
 265. CH₃

H CH₃
 266. H

CH₃ H
 267. H

H CH₃
 268. CH₃

CH₃ H
 269. CH₃

H CH₃
 270. H

CH₃ CH₃
 271. CH₃

CH₃ CH₃
 272. H H

H
 273. CH₃ H

H
 274. H CH₃

H
 275. H H

CH₃
 276. CH₃ CH₃

H
 277. CH₃ H

CH₃
 278. H CH₃

CH₃
 279. CH₃ CH₃

CH₃
 280. CH(CH₃)₂ H CH₂CH₃ H
 281. CH(CH₃)₂ H CH(CH₃)₂ H
 282. CH(CH₃)₂ H CH₂CH(CH₃)₂ H
 283. CH(CH₃)₂ H C(CH₃)₃ H
 284. CH(CH₃)₂ H CH₂C(CH₃)₂ H
 285. CH(CH₃)₂ H

H
 286. CH(CH₃)₂ H

H
 287. CH(CH₃)₂ H

H
 288. CH(CH₃)₂ H

H
 289. CH(CH₃)₂ H

H
 290. CH(CH₃)₂ H

H
 291. C(CH₃)₃ H CH₂CH₃ H
 292. C(CH₃)₃ H CH(CH₃)₂ H
 293. C(CH₃)₃ H CH₂CH(CH₃)₂ H
 294. C(CH₃)₃ H C(CH₃)₃ H
 295. C(CH₃)₃ H CH₂C(CH₃)₃ H
 296. C(CH₃)₃ H

H
 297. C(CH₃)₃ H

H
 298. C(CH₃)₃ H

H
 299. C(CH₃)₃ H

H
 300. C(CH₃)₃ H

H
 301. C(CH₃)₃ H

H
 302. CH₂C(CH₃)₃ H CH₂CH₃ H
 303. CH₂C(CH₃)₃ H CH(CH₃)₂ H
 304. CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H
 305. CH₂C(CH₃)₃ H C(CH₃)₃ H
 306. CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H
 307. CH₂C(CH₃)₃ H

H
 308. CH₂C(CH₃)₃ H

H
 309. CH₂C(CH₃)₃ H

H
 310. CH₂C(CH₃)₃ H

H
 311. CH₂C(CH₃)₃ H

H
 312. CH₂C(CH₃)₃ H

H
 313.

H CH₂CH₃ H
 314.

H CH(CH₃)₂ H
 315.

H CH₂CH(CH₃)₂ H
 316.

H C(CH₃)₃ H
 317.

H CH₂C(CH₃)₃ H
 318.

H

H
 319.

H

H
 320.

H

H
 321.

H

H
 322.

H

H
 323.

H

H
 324.

H CH₂CH₃ H
 325.

H CH(CH₃)₂ H
 326.

H CH₂CH(CH₃)₂ H
 327.

H C(CH₃)₃ H
 328.

H CH₂C(CH₃)₃ H
 329.

H

H
 330.

H

H
 331.

H

H
 332.

H

H
 333.

H

H
 334.

H

H
 335.

H CH₂CH(CH₃)₂ H
 336.

H C(CH₃)₃ H
 337.

H CH₂C(CH₃)₃ H
 338.

H CH₂CH₂CF₃ H
 339.

H CH₂C(CH₃)₂CF₃ H
 340.

H

H
 341.

H

H
 342.

H

H
 343.

H

H
 344.

H

H
 345.

H

H
 346.

H CH₂CH(CH₃)₂ H
 347.

H C(CH₃)₃ H
 348.

H CH₂C(CH₃)₃ H
 349.

H

H
 350.

H

H
 351.

H

H
 352.

H

H
 353.

H

H
 354.

H

H
 355.

H CH₂CH(CH₃)₂ H
 356.

H C(CH₃)₃ H
 357.

H CH₂C(CH₃)₃ H
 358.

H

H
 359.

H

H
 360.

H

H
 361.

H

H
 362.

H

H
 363.

H

H
 364. H H H H
 365. CD₃ H H H
 366. H CD₃ H H
 367. H H CD₃ H
 368. CD₃ CD₃ H CD₃
 369. CD₃ H CD₃ H
 370. CD₃ H H CD₃
 371. H CD₃ CH₃ H
 372. H CD₃ H CD₃
 373. H H CD₃ CD₃
 374. CD₃ CD₃ CD₃ H
 375. CD₃ CD₃ H CD₃
 376. CD₃ H CD₃ CD₃
 377. H CD₃ CD₃ CD₃
 378. CD₃ CD₃ CD₃ CD₃
 379. CD₂CH₃ H H H
 380. CD₂CH₃ CD₃ H CD₃
 381. CD₂CH₃ H CD₃ H
 382. CD₂CH₃ H H CD₃
 383. CD₂CH₃ CD₃ CD₃ H
 384. CD₂CH₃ CD₃ H CD₃
 385. CD₂CH₃ H CD₃ CD₃
 386. CD₂CH₃ CD₃ CD₃ CD₃
 387. H CD₂CH₃ H H
 388. CH₃ CD₂CH₃ H CD₃
 389. H CD₂CH₃ CD₃ H
 390. H CD₂CH₃ H CD₃
 391. CD₃ CD₂CH₃ CD₃ H
 392. CD₃ CD₂CH₃ H CD₃
 393. H CD₂CH₃ CD₃ CD₃
 394. CD₃ CD₂CH₃ CD₃ CD₃
 395. H H CD₂CH₃ H
 396. CD₃ H CD₂CH₃ H
 397. H CD₃ CD₂CH₃ H
 398. H H CD₂CH₃ CD₃
 399. CD₃ CD₃ CD₂CH₃ H
 400. CD₃ H CD₂CH₃ CD₃
 401. H CD₃ CD₂CH₃ CD₃
 402. CD₃ CD₃ CD₂CH₃ CD₃
 403. CD(CH₃)₂ H H H
 404. CD(CH₃)₂ CD₃ H CD₃
 405. CD(CH₃)₂ H CD₃ H
 406. CD(CH₃)₂ H H CD₃
 407. CD(CH₃)₂ CD₃ CD₃ H
 408. CD(CH₃)₂ CD₃ H CD₃
 409. CD(CH₃)₂ H CD₃ CD₃
 410. CD(CH₃)₂ CD₃ CD₃ CD₃
 411. H CD(CH₃)₂ H H
 412. CD₃ CD(CH₃)₂ H CD₃
 413. H CD(CH₃)₂ CD₃ H
 414. H CD(CH₃)₂ H CD₃
 415. CD₃ CD(CH₃)₂ CD₃ H
 416. CD₃ CD(CH₃)₂ H CD₃
 417. H CD(CH₃)₂ CD₃ CD₃
 418. CD₃ CD(CH₃)₂ CD₃ CD₃
 419. H H CD(CH₃)₂ H
 420. CD₃ H CD(CH₃)₂ H
 421. H CD₃ CD(CH₃)₂ H
 422. H H CD(CH₃)₂ CD₃
 423. CD₃ CD₃ CD(CH₃)₂ H
 424. CD₃ H CD(CH₃)₂ CD₃
 425. H CD₃ CD(CH₃)₂ CD₃
 426. CD₃ CD₃ CD(CH₃)₂ CD₃
 427. CD(CD₃)₂ H H H
 428. CD(CD₃)₂ CD₃ H CD₃
 429. CD(CD₃)₂ H CD₃ H
 430. CD(CD₃)₂ H H CD₃
 431. CD(CD₃)₂ CD₃ CD₃ H
 432. CD(CD₃)₂ CD₃ H CD₃
 433. CD(CD₃)₂ H CD₃ CD₃
 434. CD(CD₃)₂ CD₃ CD₃ CD₃
 435. H CD(CD₃)₂ H H
 436. CH₃ CD(CD₃)₂ H CD₃
 437. H CD(CD₃)₂ CD₃ H
 438. H CD(CD₃)₂ H CD₃
 439. CD₃ CD(CD₃)₂ CD₃ H
 440. CD₃ CD(CD₃)₂ H CD₃
 441. H CD(CD₃)₂ CD₃ CD₃
 442. CD₃ CD(CD₃)₂ CD₃ CD₃
 443. H H CD(CD₃)₂ H
 444. CD₃ H CD(CD₃)₂ H
 445. H CD₃ CD(CD₃)₂ H
 446. H H CD(CD₃)₂ CD₃
 447. CD₃ CD₃ CD(CD₃)₂ H
 448. CD₃ H CD(CD₃)₂ CD₃
 449. H CD₃ CD(CD₃)₂ CD₃
 450. CD₃ CD₃ CD(CD₃)₂ CD₃
 451. CD₂CH(CH₃)₂ H H H
 452. CD₂CH(CH₃)₂ CD₃ H CD₃
 453. CD₂CH(CH₃)₂ H CD₃ H
 454. CD₂CH(CH₃)₂ H H CD₃
 455. CD₂CH(CH₃)₂ CD₃ CD₃ H
 456. CD₂CH(CH₃)₂ CD₃ H CD₃
 457. CD₂CH(CH₃)₂ H CD₃ CD₃
 458. CD₂CH(CH₃)₂ CD₃ CD₃ CD₃
 459. H CD₂CH(CH₃)₂ H H
 460. CD₃ CD₂CH(CH₃)₂ H CD₃ 461 H CD₂CH(CH₃)₂ CD₃ H
 462. H CD₂CH(CH₃)₂ H CD₃
 463. CD₃ CD₂CH(CH₃)₂ CD₃ H
 464. CD₃ CD₂CH(CH₃)₂ H CD₃
 465. H CD₂CH(CH₃)₂ CD₃ CD₃
 466. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃
 467. H H CD₂CH(CH₃)₂ H
 468. CD₃ H CD₂CH(CH₃)₂ H
 469. H CD₃ CD₂CH(CH₃)₂ H
 470. H H CD₂CH(CH₃)₂ CD₃
 471. CD₃ CD₃ CD₂CH(CH₃)₂ H
 472. CD₃ H CD₂CH(CH₃)₂ CD₃
 473. H CD₃ CD₂CH(CH₃)₂ CD₃
 474. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃
 475. CD₂C(CH₃)₃ H H H
 476. CD₂C(CH₃)₃ CD₃ H CD₃
 477. CD₂C(CH₃)₃ H CD₃ H
 478. CD₂C(CH₃)₃ H H CD₃
 479. CD₂C(CH₃)₃ CD₃ CD₃ H
 480. CD₂C(CH₃)₃ CD₃ H CD₃
 481. CD₂C(CH₃)₃ H CD₃ CD₃
 482. CD₂C(CH₃)₃ CH₃ CD₃ CD₃
 483. H CD₂C(CH₃)₃ H H
 484. CD₃ CD₂C(CH₃)₃ H CD₃
 485. H CD₂C(CH₃)₃ CD₃ H
 486. H CD₂C(CH₃)₃ H CD₃
 487. CD₃ CD₂C(CH₃)₃ CD₃ H
 488. CD₃ CD₂C(CH₃)₃ H CD₃
 489. H CD₂C(CH₃)₃ CD₃ CD₃
 490. CD₃ CD₂C(CH₃)₃ CD₃ CD₃
 491. H H CD₂C(CH₃)₃ H
 492. CD₃ H CD₂C(CH₃)₃ H
 493. H CD₃ CD₂C(CH₃)₃ H
 494. H H CD₂C(CH₃)₃ CD₃
 495. CD₃ CD₃ CD₂C(CH₃)₃ H
 496. CD₃ H CD₂C(CH₃)₃ CD₃
 497. H CD₃ CD₂C(CH₃)₃ CD₃
 498. CD₃ CD₃ CD₂C(CH₃)₃ CD₃
 499.

H H H
 500.

CD₃ H CD₃
 501.

H CD₃ H
 502.

H H CD₃
 503.

CD₃ CD₃ H
 504.

CD₃ H CD₃
 505.

H CD₃ CD₃
 506.

CD₃ CD₃ CD₃
 507. H

H H
 508. CD₃

H CD₃
 509. H

CD₃ H
 510. H

H CD₃
 511. CD₃

CD₃ H
 512. CD₃

H CD₃
 513. H

CD₃ CD₃
 514. CD₃

CD₃ CD₃
 515. H H

H
 516. CD₃ H

H
 517. H CD₃

H
 518. H H

CD₃
 519. CD₃ CD₃

H
 520. CD₃ H

CD₃
 521. H CD₃

CD₃
 522. CD₃ CD₃

CD₃
 523.

H H H
 524.

CD₃ H CD₃
 525.

H CD₃ H
 526.

H H CD₃
 527.

CD₃ CD₃ H
 528.

CD₃ H CD₃
 529.

H CD₃ CD₃
 530.

CD₃ CD₃ CD₃
 531. H

H H
 532. CH₃

H CD₃
 533. H

CD₃ H
 534. H

H CD₃
 535. CD₃

CD₃ H
 536. CD₃

H CD₃
 537. H

CD₃ CD₃
 538. CH₃

CD₃ CD₃
 539. H H

H
 540. CD₃ H

H
 541. H CD₃

H
 542. H H

CD₃
 543. CD₃ CD₃

H
 544. CD₃ H

CD₃
 545. H CD₃

CD₃
 546. CD₃ CD₃

CD₃
 547.

H H H
 548.

CD₃ H CD₃
 549.

H CD₃ H
 550.

H H CD₃
 551.

CD₃ CD₃ H
 552.

CD₃ H CD₃
 553.

H CD₃ CD₃
 554.

CD₃ CD₃ CD₃
 555. H

H H
 556. CD₃

H CD₃
 557. H

CD₃ H
 558. H

H CD₃
 559. CD₃

CD₃ H
 560. CD₃

H CD₃
 561. H

CD₃ CD₃
 562. CD₃

CD₃ CD₃
 563. H H

H
 564. CD₃ H

H
 565. H CD₃

H
 566. H H

CD₃
 567. CD₃ CD₃

H
 568. CD₃ H

CD₃
 569. H CD₃

CD₃
 570. CD₃ CD₃

CD₃
 571.

H H H
 572.

CD₃ H CD₃
 573.

H CD₃ H
 574.

H H CD₃
 575.

CD₃ CD₃ H
 576.

CD₃ H CD₃
 577.

H CD₃ CD₃
 578.

CD₃ CD₃ CD₃
 579. H

H H
 580. CD₃

H CD₃
 581. H

CD₃ H
 582. H

H CD₃
 583. CD₃

CD₃ H
 584. CD₃

H CD₃
 585. H

CD₃ CD₃
 586. CD₃

CD₃ CD₃
 587. H H

H
 588. CD₃ H

H
 589. H CD₃

H
 590. H H

CD₃
 591. CD₃ CD₃

H
 592. CD₃ H

H
 593. H CD₃

CD₃
 594. CD₃ CD₃

CD₃
 595.

H H H
 596.

CD₃ H CD₃
 597.

H CD₃ H
 598.

H H CD₃
 599.

CD₃ CD₃ H
 600.

CD₃ H CD₃
 601.

H CD₃ CD₃
 602.

CD₃ CD₃ CD₃
 603. H

H H
 604. CD₃

H CD₃
 605. H

CD₃ H
 606. H

H CD₃
 607. CD₃

CD₃ H
 608. CD₃

H CD₃
 609. H

CD₃ CD₃
 610. CD₃

CD₃ CD₃
 611. H H

H
 612. CD₃ H

H
 613. H CD₃

H
 614. H H

CD₃
 615. CD₃ CD₃

H
 616. CD₃ H

CD₃
 617. H CD₃

CD₃
 618. CD₃ CD₃

CD₃
 619.

H H H
 620.

CD₃ H CD₃
 621.

H CD₃ H
 622.

H H CD₃
 623.

CH₃ CH₃ H
 624.

CD₃ H CD₃
 625.

H CD₃ CD₃
 626.

CD₃ CD₃ CD₃
 627. H

H H
 628. CD₃

H CD₃
 629. H

CD₃ H
 630. H

H CD₃
 631. CD₃

CD₃ H
 632. CD₃

H CD₃
 633. H

CD₃ CD₃
 634. CD₃

CD₃ CD₃
 635. H H

H
 636. CD₃ H

H
 637. H CD₃

H
 638. H H

CH₃
 639. CD₃ CD₃

H
 640. CD₃ H

CD₃
 641. H CD₃

CD₃
 642. CD₃ CD₃

CD₃
 643. CD(CH₃)₂ H CD₂CH₃ H
 644. CD(CH₃)₂ H CD(CH₃)₂ H
 645. CD(CH₃)₂ H CD₂CH(CH₃)₂ H
 646. CD(CH₃)₂ H C(CH₃)₃ H
 647. CD(CH₃)₂ H CD₂C(CH₃)₃ H
 648. CD(CH₃)₂ H

H
 649. CD(CH₃)₂ H

H
 650. CD(CH₃)₂ H

H
 651. CD(CH₃)₂ H

H
 652. CD(CH₃)₂ H

H
 653. CD(CH₃)₂ H

H
 654. C(CH₃)₃ H CD₂CH₃ H
 655. C(CH₃)₃ H CD(CH₃)₂ H
 656. C(CH₃)₃ H CD₂CH(CH₃)₂ H
 657. C(CH₃)₃ H C(CH₃)₃ H
 658. C(CH₃)₃ H CD₂C(CH₃)₃ H
 659. C(CH₃)₃ H

H
 660. C(CH₃)₃ H

H
 661. C(CH₃)₃ H

H
 662. C(CH₃)₃ H

H
 663. C(CH₃)₃ H

H
 664. C(CH₃)₃ H

H
 665. CD₂C(CH₃)₃ H CD₂CH₃ H
 666. CD₂C(CH₃)₃ H CD(CH₃)₂ H
 667. CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H
 668. CD₂C(CH₃)₃ H C(CH₃)₃ H
 669. CD₂C(CH₃)₃ H CD₂C(CH₃)₃ H
 670. CD₂C(CH₃)₃ H

H
 671. CD₂C(CH₃)₃ H

H
 672. CD₂C(CH₃)₃ H

H
 673. CD₂C(CH₃)₃ H

H
 674. CD₂C(CH₃)₃ H

H
 675. CD₂C(CH₃)₃ H

H
 676.

H CD₂CH₃ H
 677.

H CD(CH₃)₂ H
 678.

H CD₂CH(CH₃)₂ H
 679.

H C(CH₃)₃ H
 680.

H CD₂C(CH₃)₃ H
 681.

H


682.

H

H
 683.

H

H
 684.

H

H
 685.

H

H
 686.

H

H
 687.

H CD₂CH₃ H
 688.

H CD(CH₃)₂ H
 689.

H CD₂CH(CH₃)₂ H
 690.

H C(CH₃)₃ H
 691.

H CD₂C(CH₃)₃ H
 692.

H CD₂CH₂CF₃ H
 693.

H CD₂C(CH₃)₂CF₃ H
 694.

H

H
 695.

H

H
 696.

H

H
 697.

H

H
 698.

H

H
 699.

H

H
 700.

H CD₂CH₃ H
 701.

H CD(CH₃)₂ H
 702.

H CD₂CH(CH₃)₂ H
 703.

H C(CH₃)₃ H
 704.

H CD₂C(CH₃)₃ H
 705.

H CD₂CH₂CF₃ H
 706.

H CD₂C(CH₃)₂CF₃ H
 707.

H

H
 708.

H

H
 709.

H

H
 710.

H

H
 711.

H

H
 712.

H

H
 713.

H CD₂CH₃ H
 714.

H CD(CH₃)₂ H
 715.

H CD₂CH(CH₃)₂ H
 716.

H C(CH₃)₃ H
 717.

H CD₂C(CH₃)₃ H
 718.

H CD₂CH₂CF₃ H
 719.

H CD₂C(CH₃)₂CF₃ H
 720.

H

H
 721.

H

H
 722.

H

H
 723.

H

H
 724.

H

H
 725.

H

H
 726.

H CD₂CH₃ H
 727.

H CD(CH₃)₂ H
 728.

H CD₂CH(CH₃)₂ H
 729.

H C(CH₃)₃ H
 730.

H CD₂C(CH₃)₃ H
 731.

H CD₂CH₂CF₃ H
 732.

H CD₂C(CH₃)₂CF₃ H
 733.

H

H
 734.

H

H
 735.

H

H
 736.

H

H
 737.

H

H
 738. H H H H
 739. CH₃ Ph H H
 740. H Ph H H
 741. H Ph CH₃ H
 742. CH₃ Ph H CH₃
 743. CH₃ Ph CH₃ H
 744. CH₃ Ph H CH₃
 745. H Ph CH₃ H
 746. H Ph H CH₃
 747. H Ph CH₃ CH₃
 748. CH₃ Ph CH₃ H
 749. CH₃ Ph H CH₃
 750. CH₃ Ph CH₃ CH₃
 751. H Ph CH₃ CH₃
 752. CH₃ Ph CH₃ CH₃
 753. CH₂CH₃ Ph H H
 754. CH₂CH₃ Ph H CH₃
 755. CH₂CH₃ Ph CH₃ H
 756. CH₂CH₃ Ph H CH₃
 757. CH₂CH₃ Ph CH₃ H
 758. CH₂CH₃ Ph H CH₃
 759. CH₂CH₃ Ph CH₃ CH₃
 760. CH₂CH₃ Ph CH₃ CH₃
 761. H Ph H H
 762. CH₃ Ph H CH₃
 763. H Ph CH₃ H
 764. H Ph H CH₃
 765. CH₃ Ph CH₃ H
 766. CH₃ Ph H CH₃
 767. H Ph CH₃ CH₃
 768. CH₃ Ph CH₃ CH₃
 769. H Ph CH₂CH₃ H
 770. CH₃ Ph CH₂CH₃ H
 771. H Ph CH₂CH₃ H
 772. H Ph CH₂CH₃ CH₃
 773. CH₃ Ph CH₂CH₃ H
 774. CH₃ Ph CH₂CH₃ CH₃
 775. H Ph CH₂CH₃ CH₃
 776. CH₃ Ph CH₂CH₃ CH₃
 777. CH(CH₃)₂ Ph H H
 778. CH(CH₃)₂ P H CH₃
 779. CH(CH₃)₂ Ph CH₃ H
 780. CH(CH₃)₂ Ph H CH₃
 781. CH(CH₃)₂ Ph CH₃ H
 782. CH(CH₃)₂ Ph H CH₃
 783. CH(CH₃)₂ Ph CH₃ CH₃
 784. CH(CH₃)₂ Ph CH₃ CH₃
 785. H Ph H H
 786. CH₃ Ph H CH₃
 787. H Ph CH₃ H
 788. H Ph H CH₃
 789. CH₃ Ph CH₃ H
 790. CH₃ Ph H CH₃
 791. H Ph CH₃ CH₃
 792. CH₃ Ph CH₃ CH₃
 793. H Ph CH(CH₃)₂ H
 794. CH₃ Ph CH(CH₃)₂ H
 795. H Ph CH(CH₃)₂ H
 796. H Ph CH(CH₃)₂ CH₃
 797. CH₃ Ph CH(CH₃)₂ H
 798. CH₃ Ph CH(CH₃)₂ CH₃
 799. H Ph CH(CH₃)₂ CH₃
 800. CH₃ Ph CH(CH₃)₂ CH₃
 801. CH₂CH(CH₃)₂ Ph H H
 802. CH₂CH(CH₃)₂ Ph H CH₃
 803. CH₂CH(CH₃)₂ Ph CH₃ H
 804. CH₂CH(CH₃)₂ Ph H CH₃
 805. CH₂CH(CH₃)₂ Ph CH₃ H
 806. CH₂CH(CH₃)₂ Ph H CH₃
 807. CH₂CH(CH₃)₂ Ph CH₃ CH₃
 808. CH₂CH(CH₃)₂ Ph CH₃ CH₃
 809. H Ph H H
 810. CH₃ Ph H CH₃
 811. H Ph CH₃ H
 812. H Ph H CH₃
 813. CH₃ Ph CH₃ H
 814. CH₃ Ph H CH₃
 815. H Ph CH₃ CH₃
 816. CH₃ Ph CH₃ CH₃
 817. H Ph CH₂CH(CH₃)₂ H
 818. CH₃ Ph CH₂CH(CH₃)₂ H
 819. H Ph CH₂CH(CH₃)₂ H
 820. H Ph CH₂CH(CH₃)₂ CH₃
 821. CH₃ Ph CH₂CH(CH₃)₂ H
 822. CH₃ Ph CH₂CH(CH₃)₂ CH₃
 823. H Ph CH₂CH(CH₃)₂ CH₃
 824. CH₃ Ph CH₂CH(CH₃)₂ CH₃
 825. C(CH₃)₃ Ph H H
 826. C(CH₃)₃ Ph H CH₃
 827. C(CH₃)₃ Ph CH₃ H
 828. C(CH₃)₃ Ph H CH₃
 829. C(CH₃)₃ Ph CH₃ H
 830. C(CH₃)₃ Ph H CH₃
 831. C(CH₃)₃ Ph CH₃ CH₃
 832. C(CH₃)₃ Ph CH₃ CH₃
 833. H Ph H H
 834. CH₃ Ph H CH₃
 835. H Ph CH₃ H
 836. H Ph H CH₃
 837. CH₃ Ph CH₃ H
 838. CH₃ Ph H CH₃
 839. H Ph CH₃ CH₃
 840. CH₃ Ph CH₃ CH₃
 841. H Ph C(CH₃)₃ H
 842. CH₃ Ph C(CH₃)₃ H
 843. H Ph C(CH₃)₃ H
 844. H Ph C(CH₃)₃ CH₃
 845. CH₃ Ph C(CH₃)₃ H
 846. CH₃ Ph C(CH₃)₃ CH₃
 847. H Ph C(CH₃)₃ CH₃
 848. CH₃ Ph C(CH₃)₃ CH₃
 849. CH₂C(CH₃)₃ Ph H H
 850. CH₂C(CH₃)₃ Ph H CH₃
 851. CH₂C(CH₃)₃ Ph CH₃ H
 852. CH₂C(CH₃)₃ Ph H CH₃
 853. CH₂C(CH₃)₃ Ph CH₃ H
 854. CH₂C(CH₃)₃ Ph H CH₃
 855. CH₂C(CH₃)₃ Ph CH₃ CH₃
 856. CH₂C(CH₃)₃ Ph CH₃ CH₃
 857. H Ph H H
 858. CH₃ Ph H CH₃
 859. H Ph CH₃ H
 860. H Ph H CH₃
 861. CH₃ Ph CH₃ H
 862. CH₃ Ph H CH₃
 863. H Ph CH₃ CH₃
 864. CH₃ Ph CH₃ CH₃
 865. H Ph CH₂C(CH₃)₃ H
 866. CH₃ Ph CH₂C(CH₃)₃ H
 867. H Ph CH₂C(CH₃)₃ H
 868. H Ph CH₂C(CH₃)₃ CH₃
 869. CH₃ Ph CH₂C(CH₃)₃ H
 870. CH₃ Ph CH₂C(CH₃)₃ CH₃
 871. H Ph CH₂C(CH₃)₃ CH₃
 872. CH₃ Ph CH₂C(CH₃)₃ CH₃
 873.

Ph H H
 874.

Ph H CH₃
 875.

Ph H CH₃
 876.

Ph H CH₃
 877.

Ph CH₃ H
 878.

Ph H CH₃
 879.

Ph CH₃ CH₃
 880.

Ph CH₃ CH₃
 881. H Ph H H
 882. CH₃ Ph H CH₃
 883. H Ph CH₃ H
 884. H Ph H CH₃
 885. CH₃ Ph CH₃ H
 886. CH₃ Ph H CH₃
 887. H Ph CH₃ CH₃
 888. CH₃ Ph CH₃ CH₃
 889. H Ph

H
 890. CH₃ Ph

H
 891. H Ph

H
 892. H Ph

CH₃
 893. CH₃ Ph

H
 894. CH₃ Ph

CH₃
 895. H Ph

CH₃
 896. CH₃ Ph

CH₃
 897.

Ph H H
 898.

Ph H CH₃
 899.

Ph CH₃ H
 900.

Ph H CH₃
 901.

Ph CH₃ H
 902.

Ph H CH₃
 903.

Ph CH₃ CH₃
 904.

Ph CH₃ CH₃
 905. H Ph H H
 906. CH₃ Ph H CH₃
 907. H Ph CH₃ H
 908. H Ph H CH₃
 909. CH₃ Ph CH₃ H
 910. CH₃ Ph H CH₃
 911. H Ph CH₃ CH₃
 912. CH₃ Ph CH₃ CH₃
 913. H Ph

H
 914. CH₃ Ph

H
 915. H Ph

H
 916. H Ph

CH₃
 917. CH₃ Ph

H
 918. CH₃ Ph

CH₃
 919. H Ph

CH₃
 920. CH₃ Ph

CH₃
 921.

Ph H H
 922.

Ph H CH₃
 923.

Ph CH₃ H
 924.

Ph H CH₃
 925.

Ph CH₃ H
 926.

Ph H CH₃
 927.

Ph CH₃ CH₃
 928.

Ph CH₃ CH₃
 929. H Ph H H
 930. CH₃ Ph H CH₃
 931. H Ph CH₃ H
 932. H Ph H CH₃
 933. CH₃ Ph CH₃ H
 934. CH₃ Ph H CH₃
 935. CH₃ Ph CH₃ CH₃
 936. CH₃ Ph CH₃ CH₃
 937. H Ph

H
 938. CH₃ Ph

H
 939. H Ph

H
 940. CH₃ Ph

CH₃
 941. CH₃ Ph

H
 942. CH₃ Ph

CH₃
 943. H Ph

CH₃
 944. CH₃ Ph

CH₃
 945.

Ph H H
 946.

Ph H CH₃
 947.

Ph CH₃ H
 948.

Ph H CH₃
 949.

Ph CH₃ H
 950.

Ph H CH₃
 951.

Ph CH₃ CH₃
 952.

Ph CH₃ CH₃
 953. H Ph H H
 954. CH₃ Ph H CH₃
 955. H Ph CH₃ H
 956. H Ph H CH₃
 957. CH₃ Ph CH₃ H
 958. CH₃ Ph H CH₃
 959. H Ph CH₃ CH₃
 960. CH₃ Ph CH₃ CH₃
 961. H Ph

H
 962. H Ph

H
 963. H Ph

H
 964. H Ph

CH₃
 965. CH₃ Ph

H
 966. CH₃ Ph

CH₃
 967. H Ph

CH₃
 968. CH₃ Ph

CH₃
 969.

Ph H H
 970.

Ph H CH₃
 971.

Ph CH₃ H
 972.

Ph H CH₃
 973.

Ph CH₃ H
 974.

Ph H CH₃
 975.

Ph CH₃ CH₃
 976.

Ph CH₃ CH₃
 977. H Ph H H
 978. CH₃ Ph H CH₃
 979. H Ph CH₃ H
 980. H Ph H CH₃
 981. CH₃ Ph CH₃ H
 982. CH₃ Ph H CH₃
 983. H Ph CH₃ CH₃
 984. CH₃ Ph CH₃ CH₃
 985. H Ph

H
 986. CH₃ Ph

H
 987. H Ph

H
 988. H Ph

CH₃
 989. CH₃ Ph

H
 990. CH₃ Ph

CH₃
 991. H Ph

CH₃
 992. CH₃ Ph

CH₃
 993.

Ph H H
 994.

Ph H CH₃
 995.

Ph CH₃ H
 996.

Ph H CH₃
 997.

Ph CH₃ H
 998.

Ph H CH₃
 999.

Ph CH₃ CH₃
 1000.

Ph CH₃ CH₃
 1001. H Ph H H
 1002. CH₃ Ph H CH₃
 1003. H Ph CH₃ H
 1004. H Ph H CH₃
 1005. CH₃ Ph CH₃ H
 1006. CH₃ Ph H CH₃
 1007. H Ph CH₃ CH₃
 1008. CH₃ Ph CH₃ CH₃
 1009. H Ph

H
 1010. CH₃ Ph

H
 1011. H Ph

H
 1012. H Ph

CH₃
 1013. CH₃ Ph

CH₃
 1014. CH₃ Ph

CH₃
 1015. H Ph

CH₃
 1016. CH₃ Ph

CH₃
 1017. CH(CH₃)₂ Ph CH₂CH₃ H
 1018. CH(CH₃)₂ Ph CH(CH₃)₂ H
 1019. CH(CH₃)₂ Ph CH₂CH(CH₃)₂ H
 1020. CH(CH₃)₂ Ph C(CH₃)₃ H
 1021. CH(CH₃)₂ Ph CH₂C(CH₃)₃ H
 1022. CH(CH₃)₂ Ph

H
 1023. CH(CH₃)₂ Ph

H
 1024. CH(CH₃)₂ Ph

H
 1025. CH(CH₃)₂ Ph

H
 1026. CH(CH₃)₂ Ph

H
 1027. CH(CH₃)₂ Ph

H
 1028. C(CH₃)₃ Ph CH₂CH₃ H
 1029. C(CH₃)₃ Ph CH(CH₃)₂ H
 1030. C(CH₃)₃ Ph CH₂CH(CH₃)₂ H
 1031. C(CH₃)₃ Ph C(CH₃)₃ H
 1032. C(CH₃)₃ Ph CH₂C(CH₃)₃ H
 1033. C(CH₃)₃ Ph

H
 1034. C(CH₃)₃ Ph

H
 1035. C(CH₃)₃ Ph

H
 1036. C(CH₃)₃ Ph

H
 1037. C(CH₃)₃ Ph

H
 1038. C(CH₃)₃ Ph

H
 1039. CH₂C(CH₃)₃ Ph CH₂CH₃ H
 1040. CH₂C(CH₃)₃ Ph CH(CH₃)₂ H
 1041. CH₂C(CH₃)₃ Ph CH₂CH(CH₃)₂ H
 1042. CH₂C(CH₃)₃ Ph C(CH₃)₃ H
 1043. CH₂C(CH₃)₃ Ph CH₂C(CH₃)₃ H
 1044. CH₂C(CH₃)₃ Ph

H
 1045. CH₂C(CH₃)₃ Ph

H
 1046. CH₂C(CH₃)₃ Ph

H
 1047. CH₂C(CH₃)₃ Ph

H
 1048. CH₂C(CH₃)₃ Ph

H
 1049. CH₂C(CH₃)₃ Ph

H
 1050.

Ph CH₂CH₃ H
 1051.

Ph CH(CH₃)₂ H
 1052.

Ph CH₂CH(CH₃)₂ H
 1053.

Ph C(CH₃)₃ H
 1054.

Ph CH₂C(CH₃)₃ H
 1055.

Ph

H
 1056.

Ph

H
 1057.

Ph

H
 1058.

Ph

H
 1059.

Ph

H
 1060.

Ph

H
 1061.

Ph CH₂CH₃ H
 1062.

Ph CH(CH₃)₂ H
 1063.

Ph CH₂CH(CH₃)₂ H
 1064.

Ph C(CH₃)₃ H
 1065.

Ph CH₂C(CH₃)₃ H
 1066.

Ph

H
 1067.

Ph

H
 1068.

Ph

H
 1069.

Ph

H
 1070.

Ph

H
 1071.

Ph

H
 1072.

Ph CH₂CH(CH₃)₂ H
 1073.

Ph C(CH₃)₃ H
 1074.

Ph CH₂C(CH₃)₃ H
 1075.

Ph

H
 1076.

Ph

H
 1077.

Ph

H
 1078.

Ph

H
 1079.

Ph

H
 1080.

Ph

H
 1081.

Ph CH₂CH(CH₃)₂ H
 1082.

Ph C(CH₃)₃ H
 1083.

Ph CH₂C(CH₃)₃ H
 1084.

Ph

H
 1085.

Ph

H
 1086.

Ph

H
 1087.

Ph

H
 1088.

Ph

H
 1089.

Ph

H
 1090.

Ph CH₂CH(CH₃)₂ H
 1091.

Ph C(CH₃)₃ H
 1092.

Ph CH₂C(CH₃)₃ H
 1093.

Ph CH₂CH₂CF₃ H
 1094.

Ph CH₂C(CH₃)₂CF₃ H
 1095.

Ph

H
 1096.

Ph

H
 1097.

Ph

H
 1098.

Ph

H
 1099.

Ph

H
 1100.

Ph

H
 1101. H Ph H H
 1102. CD₃ Ph H H
 1103. H Ph H H
 1104. H Ph CD₃ H
 1105. CD₃ Ph H CD₃
 1106. CD₃ Ph CD₃ H
 1107. CD₃ Ph H CD₃
 1108. H Ph CH₃ H
 1109. H Ph H CD₃
 1110. H Ph CD₃ CD₃
 1111. CD₃ Ph CD₃ H
 1112. CD₃ Ph H CD₃
 1113. CD₃ Ph CD₃ CD₃
 1114. H Ph CD₃ CD₃
 1115. CD₃ Ph CD₃ CD₃
 1116. CD₂CH₃ Ph H
 1117. CD₂CH₃ Ph H CD₃
 1118. CD₂CH₃ Ph CD₃ H
 1119. CD₂CH₃ Ph H CD₃
 1120. CD₂CH₃ Ph CD₃ H
 1121. CD₂CH₃ Ph H CD₃
 1122. CD₂CH₃ Ph CD₃ CD₃
 1123. CD₂CH₃ Ph CD₃ CD₃
 1124. H Ph H H
 1125. CH₃ Ph H CD₃
 1126. H Ph CD₃ H
 1127. H Ph H CD₃
 1128. CD₃ Ph CD₃ H
 1129. CD₃ Ph H CD₃
 1130. H Ph CD₃ CD₃
 1131. CD₃ Ph CD₃ CD₃
 1132. H Ph CD₂CH₃ H
 1133. CD₃ Ph CD₂CH₃ H
 1134. H Ph CD₂CH₃ H
 1135. H Ph CD₂CH₃ CD₃
 1136. CD₃ Ph CD₂CH₃ H
 1137. CD₃ Ph CD₂CH₃ CD₃
 1138. H Ph CD₂CH₃ CD₃
 1139. CD₃ Ph CD₂CH₃ CD₃
 1140. CD(CH₃)₂ Ph H H
 1141. CD(CH₃)₂ Ph H CD₃
 1142. CD(CH₃)₂ Ph CD₃ H
 1143. CD(CH₃)₂ Ph H CD₃
 1144. CD(CH₃)₂ Ph CD₃ H
 1145. CD(CH₃)₂ Ph H CD₃
 1146. CD(CH₃)₂ Ph CD₃ CD₃
 1147. CD(CH₃)₂ Ph CD₃ CD₃
 1148. H Ph H H
 1149. CD₃ Ph H CD₃
 1150. H Ph CD₃ H
 1151. H Ph H CD₃
 1152. CD₃ Ph CD₃ H
 1153. CD₃ Ph H CD₃
 1154. H Ph CD₃ CD₃
 1155. CD₃ Ph CD₃ CD₃
 1156. H Ph CD(CH₃)₂ H
 1157. CD₃ Ph CD(CH₃)₂ H
 1158. H Ph CD(CH₃)₂ H
 1159. H Ph CD(CH₃)₂ CD₃
 1160. CD₃ Ph CD(CH₃)₂ H
 1161. CD₃ Ph CD(CH₃)₂ CD₃
 1162. H Ph CD(CH₃)₂ CD₃
 1163. CD₃ Ph CD(CH₃)₂ CD₃
 1164. CD(CH₃)₂ Ph H H
 1165. CD(CH₃)₂ Ph H CD₃
 1166. CD(CH₃)₂ Ph CD₃ H
 1167. CD(CH₃)₂ Ph H CD₃
 1168. CD(CH₃)₂ Ph CD₃ H
 1169. CD(CH₃)₂ Ph H CD₃
 1170. CD(CH₃)₂ Ph CD₃ CD₃
 1171. CD(CH₃)₂ Ph CD₃ CD₃
 1172. H Ph H H
 1173. CH₃ Ph H CD₃
 1174. H Ph CD₃ H
 1175. H Ph H CD₃
 1176. CD₃ Ph CD₃ H
 1177. CD₃ Ph H CD₃
 1178. H Ph CD₃ CD₃
 1179. CD₃ Ph CD₃ CD₃
 1180. H Ph CD(CD₃)₂ H
 1181. CD₃ Ph CD(CD₃)₂ H
 1182. H Ph CD(CD₃)₂ H
 1183. H Ph CD(CD₃)₂ CD₃
 1184. CD₃ Ph CD(CD₃)₂ H
 1185. CD₃ Ph CD(CD₃)₂ CD₃
 1186. H Ph CD(CD₃)₂ CD₃
 1187. CD₃ Ph CD(CD₃)₂ CD₃
 1188. CD₂CH(CH₃)₂ Ph H H
 1189. CD₂CH(CH₃)₂ Ph H CD₃
 1190. CD₂CH(CH₃)₂ Ph CD₃ H
 1191. CD₂CH(CH₃)₂ Ph H CD₃
 1192. CD₂CH(CH₃)₂ Ph CD₃ H
 1193. CD₂CH(CH₃)₂ Ph H CD₃
 1194. CD₂CH(CH₃)₂ Ph CD₃ CD₃
 1195. CD₂CH(CH₃)₂ Ph CD₃ CD₃
 1196. H Ph H H
 1197. CD₃ Ph H CD₃
 1198. H Ph CD₃ H
 1199. H Ph H CD₃
 1200. CD₃ Ph CD₃ H
 1201. CD₃ Ph H CD₃
 1202. H Ph CD₃ CD₃
 1203. CD₃ Ph CD₃ CD₃
 1204. H Ph CD₂CH(CH₃)₂ H
 1205. CD₃ Ph CD₂CH(CH₃)₂ H
 1206. H Ph CD₂CH(CH₃)₂ H
 1207. H Ph CD₂CH(CH₃)₂ CD₃
 1208. CD₃ Ph CD₂CH(CH₃)₂ H
 1209. CD₃ Ph CD₂CH(CH₃)₂ CD₃
 1210. H Ph CD₂CH(CH₃)₂ CD₃
 1211. CD₃ Ph CD₂CH(CH₃)₂ CD₃
 1212. CD₂C(CH₃)₃ Ph H H
 1213. CD₂C(CH₃)₃ Ph H CD₃
 1214. CD₂C(CH₃)₃ Ph CD₃ H
 1215. CD₂C(CH₃)₃ Ph H CD₃
 1216. CD₂C(CH₃)₃ Ph CD₃ H
 1217. CD₂C(CH₃)₃ Ph H CD₃
 1218. CD₂C(CH₃)₃ Ph CD₃ CD₃
 1219. CD₂C(CH₃)₃ Ph CD₃ CD₃
 1220. H Ph H H
 1221. CD₃ Ph H CD₃
 1222. H Ph CD₃ H
 1223. H Ph H CD₃
 1224. CD₃ Ph CD₃ H
 1225. CD₃ Ph H CD₃
 1226. H Ph CD₃ CD₃
 1227. CD₃ Ph CD₃ CD₃
 1228. H Ph CD₂C(CH₃)₃ H
 1229. CD₃ Ph CD₂C(CH₃)₃ H
 1230. H Ph CD₂C(CH₃)₃ H
 1231. H Ph CD₂C(CH₃)₃ CD₃
 1232. CD₃ Ph CD₂C(CH₃)₃ H
 1233. CD₃ Ph CD₂C(CH₃)₃ CD₃
 1234. H Ph CD₂C(CH₃)₃ CD₃
 1235. CD₃ Ph CD₂C(CH₃)₃ CD₃
 1236.

Ph H H
 1237.

Ph H CD₃
 1238.

Ph CD₃ H
 1239.

Ph H CD₃
 1240.

Ph CD₃ H
 1241.

Ph H CD₃
 1242.

Ph CD₃ CD₃
 1243.

Ph CD₃ CD₃
 1244. H Ph H H
 1245. CD₃ Ph H CD₃
 1246. H Ph CD₃ H
 1247. H Ph H CD₃
 1248. CD₃ Ph CD₃ H
 1249. CD₃ Ph H CD₃
 1250. H Ph CD₃ CD₃
 1251. CD₃ Ph CD₃ CD₃
 1252. H Ph

H
 1253. CD₃ Ph

H
 1254. H Ph

H
 1255. H Ph

CD₃
 1256. CD₃ Ph

H
 1257. CD₃ Ph

CD₃
 1258. H Ph

CD₃
 1259. CD₃ Ph

CD₃
 1260.

Ph H H
 1261.

Ph H CD₃
 1262.

Ph CD₃ H
 1263.

Ph H CD₃
 1264.

Ph CD₃ H
 1265.

Ph H CD₃
 1266.

Ph CD₃ CD₃
 1267.

Ph CD₃ CD₃
 1268. H Ph H H
 1269. CH₃ Ph H CD₃
 1270. H Ph CD₃ H
 1271. H Ph H CD₃
 1272. CD₃ Ph CD₃ H
 1273. CD₃ Ph H CD₃
 1274. H Ph CD₃ CD₃
 1275. CH₃ Ph CD₃ CD₃
 1276. H Ph

H
 1277. CD₃ Ph

H
 1278. H Ph

H
 1279. H Ph

CD₃
 1280. CD₃ Ph

H
 1281. CD₃ Ph

CD₃
 1282. H Ph

CD₃
 1283. CD₃ Ph

CD₃
 1284.

Ph H H
 1285.

Ph H CD₃
 1286.

Ph CD₃ H
 1287.

Ph H CD₃
 1288.

Ph CD₃ H
 1289.

Ph H CD₃
 1290.

Ph CD₃ CD₃
 1291.

Ph CD₃ CD₃
 1292. H Ph H H
 1293. CD₃ Ph H CD₃
 1294. H Ph CD₃ H
 1295. H Ph H CD₃
 1296. CD₃ Ph CD₃ H
 1297. CD₃ Ph H CD₃
 1298. H Ph CD₃ CD₃
 1299. CD₃ Ph CD₃ CD₃
 1300. H Ph

H
 1301. CD₃ Ph

H
 1302. H Ph

H
 1303. H Ph

H
 1304. CD₃ Ph

H
 1305. CD₃ Ph

CD₃
 1306. H Ph

CD₃
 1307. CD₃ Ph

CD₃
 1308.

Ph H H
 1309.

Ph H CD₃
 1310.

Ph CD₃ H
 1311.

Ph H CD₃
 1312.

Ph CD₃ H
 1313.

Ph H CD₃
 1314.

Ph CD₃ CD₃
 1315.

Ph CD₃ CD₃
 1316. H Ph H H
 1317. CD₃ Ph H CD₃
 1318. H Ph CD₃ H
 1319. H Ph H CD₃
 1320. CD₃ Ph CD₃ H
 1321. CD₃ Ph H CD₃
 1322. H Ph CD₃ CD₃
 1323. CD₃ Ph CD₃ CD₃
 1324. H Ph

H
 1325. CD₃ Ph

H
 1326. H Ph

H
 1327. H Ph

CD₃
 1328. CD₃ Ph

H
 1329. CD₃ Ph

CD₃
 1330. H Ph

CD₃
 1331. CD₃ Ph

CD₃
 1332.

Ph H H
 1333.

Ph H CD₃
 1334.

Ph CD₃ H
 1335.

Ph H CD₃
 1336.

Ph CD₃ H
 1337.

Ph H CD₃
 1338.

Ph CD₃ CD₃
 1339.

Ph CD₃ CD₃
 1340. H Ph H H
 1341. CD₃ Ph H CD₃
 1342. H Ph CD₃ H
 1343. H Ph H CD₃
 1344. CD₃ Ph CD₃ H
 1345. CD₃ Ph H CD₃
 1346. H Ph CD₃ CD₃
 1347. CD₃ Ph CD₃ CD₃
 1348. H Ph

H 1349 CD₃ Ph

H
 1350. H Ph

H
 1351. H Ph

CD₃
 1352. CD₃ Ph

H
 1353. CD₃ Ph

CD₃
 1354. H Ph

CD₃
 1355. CD₃ Ph

CD₃
 1356.

Ph H H
 1357.

Ph H CD₃
 1358.

Ph CD₃ H
 1359.

Ph H CD₃
 1360.

Ph CH₃ H
 1361.

Ph H CD₃
 1362.

Ph CD₃ CD₃
 1363.

Ph CD₃ CD₃
 1364. H Ph H H
 1365. CD₃ Ph H CD₃
 1366. H Ph CD₃ H
 1367. H Ph H CD₃
 1368. CD₃ Ph CD₃ H
 1369. CD₃ Ph H CD₃
 1370. H Ph CD₃ CD₃
 1371. CD₃ Ph CD₃ CD₃
 1372. H Ph

H
 1373. CD₃ Ph

H
 1374. H Ph

H
 1375. H Ph

CH₃
 1376. CD₃ Ph

H
 1377. CD₃ Ph

CD₃
 1378. H Ph

CD₃
 1379. CD₃ Ph

CD₃
 1380. CD(CH₃)₂ Ph CD₂CH₃ H
 1381. CD(CH₃)₂ Ph CD(CH₃)₂ H
 1382. CD(CH₃)₂ Ph CD₂CH(CH₃)₂ H
 1383. CD(CH₃)₂ Ph C(CH₃)₃ H
 1384. CD(CH₃)₂ Ph CD₂C(CH₃)₃ H
 1385. CD(CH₃)₂ Ph CD₂CH₂CF₃ H
 1386. CD(CH₃)₂ Ph CD₂C(CH₃)₂CF₃ H
 1387. CD(CH₃)₂ Ph

H
 1388. CD(CH₃)₂ Ph

H
 1389. CD(CH₃)₂ Ph

H
 1390. CD(CH₃)₂ Ph

H
 1391. CD(CH₃)₂ Ph

H
 1392. CD(CH₃)₂ Ph

H
 1393. C(CH₃)₃ Ph CD₂CH₃ H
 1394. C(CH₃)₃ Ph CD(CH₃)₂ H
 1395. C(CH₃)₃ Ph CD₂CH(CH₃)₂ H
 1396. C(CH₃)₃ Ph C(CH₃)₃ H
 1397. C(CH₃)₃ Ph CD₂C(CH₃)₃ H
 1398. C(CH₃)₃ Ph

H
 1399. C(CH₃)₃ Ph

H
 1400. C(CH₃)₃ Ph

H
 1401. C(CH₃)₃ Ph

H
 1402. C(CH₃)₃ Ph

H
 1403. C(CH₃)₃ Ph

H
 1404. CD₂C(CH₃)₃ Ph CD₂CH₃ H
 1405. CD₂C(CH₃)₃ Ph CD(CH₃)₂ H
 1406. CD₂C(CH₃)₃ Ph CD₂CH(CH₃)₂ H
 1407. CD₂C(CH₃)₃ Ph C(CH₃)₃ H
 1408. CD₂C(CH₃)₃ Ph CD₂C(CH₃)₃ H
 1409. CD₂C(CH₃)₃ Ph CD₂CH₂CF₃ H
 1410. CD₂C(CH₃)₃ Ph CD₂C(CH₃)₂CF₃ H
 1411. CD₂C(CH₃)₃ Ph

H
 1412. CD₂C(CH₃)₃ Ph

H
 1413. CD₂C(CH₃)₃ Ph

H
 1414. CD₂C(CH₃)₃ Ph

H
 1415. CD₂C(CH₃)₃ Ph

H
 1416. CD₂C(CH₃)₃ Ph

H
 1417.

Ph CD₂CH₃ H
 1418.

Ph CD(CH₃)₂ H
 1419.

Ph CD₂(CH₃)₂ H
 1420.

Ph C(CH₃)₃ H
 1421.

Ph CD₂C(CH₃)₃ H
 1422.

Ph

H
 1423.

Ph

H
 1424.

Ph

H
 1425.

Ph

H
 1426.

Ph

H
 1427.

Ph

H
 1428.

Ph CD₂CH₃ H
 1429.

Ph CD(CH₃)₂ H
 1430.

Ph CD₂CH(CH₃)₂ H
 1431.

Ph C(CH₃)₃ H
 1432.

Ph CD₂C(CH₃)₃ H
 1433.

Ph

H
 1434.

Ph

H
 1435.

Ph

H
 1436.

Ph

H
 1437.

Ph

H
 1438.

Ph

H
 1439.

Ph CD₂CH₃ H
 1440.

Ph CD(CH₃)₂ H
 1441.

Ph CD₂CH(CH₃)₂ H
 1442.

Ph C(CH₃)₃ H
 1443.

Ph CD₂C(CH₃)₃ H
 1444.

Ph

H
 1445.

Ph

H
 1446.

Ph

H
 1447.

Ph

H
 1448.

Ph

H
 1449.

Ph

H
 1450.

Ph CD₂CH₃ H
 1451.

Ph CD(CH₃)₂ H
 1452.

Ph CD₂CH(CH₃)₂ H
 1453.

Ph C(CH₃)₃ H
 1454.

Ph CD₂C(CH₃)₃ H
 1455.

Ph

H
 1456.

Ph

H
 1457.

Ph

H
 1458.

Ph

H
 1459.

Ph

H
 1460.

Ph

H
 1461.

Ph CD₂CH₃ H
 1462.

Ph CD(CH₃)₂ H
 1463.

Ph CD₂CH(CH₃)₂ H
 1464.

Ph C(CH₃)₃ H
 1465.

Ph CD₂C(CH₃)₃ H
 1466.

Ph

H
 1467.

Ph

H
 1468.

Ph

H
 1469.

Ph

H
 1470.

Ph

H
 1471.

Ph

H.


12. The compound of claim 11, wherein the compound is selected from the group consisting of Compound A-x having the formula Ir(L_(Ai))(L_(Bj))₂ or Compound B-x having the formula Ir(L_(Ai))₂(L_(Bj)); wherein x is an integer defined by x=1471i+j−1471, wherein i is an integer from 1 to 371, j is an integer from 1 to 1471, and wherein L_(A1) to L_(A371) have the following formula:

 wherein R, R¹, R², R³, R⁴, R⁵, and R⁶ are defined as provided below: L_(Ai), where i is R¹ R R² R³ R⁴ R⁵ R⁶
 1. H R^(A1) H H H H H
 2. H R^(A2) H H H H H
 3. H R^(A3) H H H H H
 4. H R^(A4) H H H H H
 5. H R^(A5) H H H H H
 6. H R^(A6) H H H H H
 7. H R^(A7) H H H H H
 8. H R^(A8) H H H H H
 9. H R^(A9) H H H H H
 10. H R^(A10) H H H H H
 11. H R^(A11) H H H H H
 12. H R^(A12) H H H H H
 13. H R^(A13) H H H H H
 14. H R^(A14) H H H H H
 15. H R^(A15) H H H H H
 16. H R^(A16) H H H H H
 17. H R^(A17) H H H H H
 18. H R^(A18) H H H H H
 19. H R^(A19) H H H H H
 20. H R^(A20) H H H H H
 21. H R^(A21) H H H H H
 22. H R^(A22) H H H H H
 23. H R^(A23) H H H H H
 24. H R^(A24) H H H H H
 25. H R^(A25) H H H H H
 26. H R^(A26) H H H H H
 27. H R^(A27) H H H H H
 28. H R^(A28) H H H H H
 29. H R^(A29) H H H H H
 30. H R^(A30) H H H H H
 31. H R^(A31) H H H H H
 32. H R^(A32) H H H H H
 33. H R^(A33) H H H H H
 34. H R^(A34) H H H H H
 35. H R^(A35) H H H H H
 36. H R^(A36) H H H H H
 37. H R^(A37) H H H H H
 38. H R^(A38) H H H H H
 39. H R^(A39) H H H H H
 40. H R^(A40) H H H H H
 41. H R^(A41) H H H H H
 42. H R^(A42) H H H H H
 43. H R^(A43) H H H H H
 44. H R^(A44) H H H H H
 45. H R^(A45) H H H H H
 46. H R^(A46) H H H H H
 47. H R^(A47) H H H H H
 48. H R^(A48) H H H H H
 49. H R^(A49) H H H H H
 50. H R^(A50) H H H H H
 51. H R^(A51) H H H H H
 52. H R^(A52) H H H H H
 53. H R^(A53) H H H H H
 54. H R^(A54) H H H H H
 55. H R^(A55) H H H H H
 56. H R^(A56) H H H H H
 57. H R^(A57) H H H H H
 58. H R^(A58) H H H H H
 59. H R^(A59) H H H H H
 60. H R^(A60) H H H H H
 61. H R^(A61) H H H H H
 62. H R^(A62) H H H H H
 63. H R^(A63) H H H H H
 64. H R^(A64) H H H H H
 65. H R^(A65) H H H H H
 66. H R^(A66) H H H H H
 67. H R^(A67) H H H H H
 68. H R^(A68) H H H H H
 69. H R^(A69) H H H H H
 70. H R^(A70) H H H H H
 71. H R^(A71) H H H H H
 72. H R^(A72) H H H H H
 73. H R^(A73) H H H H H
 74. H R^(A74) H H H H H
 75. H R^(A75) H H H H H
 76. H R^(A76) H H H H H
 77. H R^(A77) H H H H H
 78. H R^(A78) H H H H H
 79. H R^(A79) H H H H H
 80. H R^(A80) H H H H H
 81. H R^(A81) H H H H H
 82. H R^(A82) H H H H H
 83. H R^(A83) H H H H H
 84. H R^(A84) H H H H H
 85. H R^(A85) H H H H H
 86. H R^(A86) H H H H H
 87. H R^(A87) H H H H H
 88. H R^(A88) H H H H H
 89. H R^(A89) H H H H H
 90. H R^(A90) H H H H H
 91. H R^(A91) H H H H H
 92. H R^(A92) H H H H H
 93. H R^(A93) H H H H H
 94. CD₃ R^(A1) H H H H H
 95. CD₃ R^(A2) H H H H H
 96. CD₃ R^(A3) H H H H H
 97. CD₃ R^(A4) H H H H H
 98. CD₃ R^(A5) H H H H H
 99. CD₃ R^(A6) H H H H H
 100. CD₃ R^(A7) H H H H H
 101. CD₃ R^(A8) H H H H H
 102. CD₃ R^(A9) H H H H H
 103. CD₃ R^(A10) H H H H H
 104. CD₃ R^(A11) H H H H H
 105. CD₃ R^(A12) H H H H H
 106. CD₃ R^(A13) H H H H H
 107. CD₃ R^(A14) H H H H H
 108. CD₃ R^(A15) H H H H H
 109. CD₃ R^(A16) H H H H H
 110. CD₃ R^(A17) H H H H H
 111. CD₃ R^(A18) H H H H H
 112. CD₃ R^(A19) H H H H H
 113. CD₃ R^(A20) H H H H H
 114. CD₃ R^(A21) H H H H H
 115. CD₃ R^(A22) H H H H H
 116. CD₃ R^(A23) H H H H H
 117. CD₃ R^(A24) H H H H H
 118. CD₃ R^(A25) H H H H H
 119. CD₃ R^(A26) H H H H H
 120. CD₃ R^(A27) H H H H H
 121. CD₃ R^(A28) H H H H H
 122. CD₃ R^(A29) H H H H H
 123. CD₃ R^(A30) H H H H H
 124. CD₃ R^(A31) H H H H H
 125. CD₃ R^(A32) H H H H H
 126. CD₃ R^(A33) H H H H H
 127. CD₃ R^(A34) H H H H H
 128. CD₃ R^(A35) H H H H H
 129. CD₃ R^(A36) H H H H H
 130. CD₃ R^(A37) H H H H H
 131. CD₃ R^(A38) H H H H H
 132. CD₃ R^(A39) H H H H H
 133. CD₃ R^(A40) H H H H H
 134. CD₃ R^(A41) H H H H H
 135. CD₃ R^(A42) H H H H H
 136. CD₃ R^(A43) H H H H H
 137. CD₃ R^(A44) H H H H H
 138. CD₃ R^(A45) H H H H H
 139. CD₃ R^(A46) H H H H H
 140. CD₃ R^(A47) H H H H H
 141. CD₃ R^(A48) H H H H H
 142. CD₃ R^(A49) H H H H H
 143. CD₃ R^(A50) H H H H H
 144. CD₃ R^(A51) H H H H H
 145. CD₃ R^(A52) H H H H H
 146. CD₃ R^(A53) H H H H H
 147. CD₃ R^(A54) H H H H H
 148. CD₃ R^(A55) H H H H H
 149. CD₃ R^(A56) H H H H H
 150. CD₃ R^(A57) H H H H H
 151. CD₃ R^(A58) H H H H H
 152. CD₃ R^(A59) H H H H H
 153. CD₃ R^(A60) H H H H H
 154. CD₃ R^(A61) H H H H H
 155. CD₃ R^(A62) H H H H H
 156. CD₃ R^(A63) H H H H H
 157. CD₃ R^(A64) H H H H H
 158. CD₃ R^(A65) H H H H H
 159. CD₃ R^(A66) H H H H H
 160. CD₃ R^(A67) H H H H H
 161. CD₃ R^(A68) H H H H H
 162. CD₃ R^(A69) H H H H H
 163. CD₃ R^(A70) H H H H H
 164. CD₃ R^(A71) H H H H H
 165. CD₃ R^(A72) H H H H H
 166. CD₃ R^(A73) H H H H H
 167. CD₃ R^(A74) H H H H H
 168. CD₃ R^(A75) H H H H H
 169. CD₃ R^(A76) H H H H H
 170. CD₃ R^(A77) H H H H H
 171. CD₃ R^(A78) H H H H H
 172. CD₃ R^(A79) H H H H H
 173. CD₃ R^(A80) H H H H H
 174. CD₃ R^(A81) H H H H H
 175. CD₃ R^(A82) H H H H H
 176. CD₃ R^(A83) H H H H H
 177. CD₃ R^(A84) H H H H H
 178. CD₃ R^(A85) H H H H H
 179. CD₃ R^(A86) H H H H H
 180. CD₃ R^(A87) H H H H H
 181. CD₃ R^(A88) H H H H H
 182. CD₃ R^(A89) H H H H H
 183. CD₃ R^(A90) H H H H H
 184. CD₃ R^(A91) H H H H H
 185. CD₃ R^(A92) H H H H H
 186. CD₃ R^(A93) H H H H H
 187. H R^(A1) H CD₃ H H H
 188. H R^(A2) H CD₃ H H H
 189. H R^(A3) H CD₃ H H H
 190. H R^(A4) H CD₃ H H H
 191. H R^(A5) H CD₃ H H H
 192. H R^(A6) H CD₃ H H H
 193. H R^(A7) H CD₃ H H H
 194. H R^(A8) H CD₃ H H H
 195. H R^(A10) H CD₃ H H H
 196. H R^(A11) H CD₃ H H H
 197. H R^(A12) H CD₃ H H H
 198. H R^(A13) H CD₃ H H H
 199. H R^(A14) H CD₃ H H H
 200. H R^(A15) H CD₃ H H H
 201. H R^(A16) H CD₃ H H H
 202. H R^(A17) H CD₃ H H H
 203. H R^(A18) H CD₃ H H H
 204. H R^(A19) H CD₃ H H H
 205. H R^(A20) H CD₃ H H H
 206. H R^(A21) H CD₃ H H H
 207. H R^(A22) H CD₃ H H H
 208. H R^(A23) H CD₃ H H H
 209. H R^(A24) H CD₃ H H H
 210. H R^(A25) H CD₃ H H H
 211. H R^(A26) H CD₃ H H H
 212. H R^(A27) H CD₃ H H H
 213. H R^(A28) H CD₃ H H H
 214. H R^(A29) H CD₃ H H H
 215. H R^(A30) H CD₃ H H H
 216. H R^(A31) H CD₃ H H H
 217. H R^(A32) H CD₃ H H H
 218. H R^(A33) H CD₃ H H H
 219. H R^(A34) H CD₃ H H H
 220. H R^(A35) H CD₃ H H H
 221. H R^(A36) H CD₃ H H H
 222. H R^(A37) H CD₃ H H H
 223. H R^(A38) H CD₃ H H H
 224. H R^(A39) H CD₃ H H H
 225. H R^(A40) H CD₃ H H H
 226. H R^(A41) H CD₃ H H H
 227. H R^(A42) H CD₃ H H H
 228. H R^(A43) H CD₃ H H H
 229. H R^(A44) H CD₃ H H H
 230. H R^(A45) H CD₃ H H H
 231. H R^(A46) H CD₃ H H H
 232. H R^(A47) H CD₃ H H H
 233. H R^(A48) H CD₃ H H H
 234. H R^(A49) H CD₃ H H H
 235. H R^(A50) H CD₃ H H H
 236. H R^(A51) H CD₃ H H H
 237. H R^(A52) H CD₃ H H H
 238. H R^(A53) H CD₃ H H H
 239. H R^(A54) H CD₃ H H H
 240. H R^(A55) H CD₃ H H H
 241. H R^(A56) H CD₃ H H H
 242. H R^(A57) H CD₃ H H H
 243. H R^(A58) H CD₃ H H H
 244. H R^(A59) H CD₃ H H H
 245. H R^(A60) H CD₃ H H H
 246. H R^(A61) H CD₃ H H H
 247. H R^(A62) H CD₃ H H H
 248. H R^(A63) H CD₃ H H H
 249. H R^(A64) H CD₃ H H H
 250. H R^(A65) H CD₃ H H H
 251. H R^(A66) H CD₃ H H H
 252. H R^(A67) H CD₃ H H H
 253. H R^(A68) H CD₃ H H H
 254. H R^(A69) H CD₃ H H H
 255. H R^(A70) H CD₃ H H H
 256. H R^(A71) H CD₃ H H H
 257. H R^(A72) H CD₃ H H H
 258. H R^(A73) H CD₃ H H H
 259. H R^(A74) H CD₃ H H H
 260. H R^(A75) H CD₃ H H H
 261. H R^(A76) H CD₃ H H H
 262. H R^(A77) H CD₃ H H H
 263. H R^(A78) H CD₃ H H H
 264. H R^(A79) H CD₃ H H H
 265. H R^(A80) H CD₃ H H H
 266. H R^(A81) H CD₃ H H H
 267. H R^(A82) H CD₃ H H H
 268. H R^(A83) H CD₃ H H H
 269. H R^(A84) H CD₃ H H H
 270. H R^(A85) H CD₃ H H H
 271. H R^(A86) H CD₃ H H H
 272. H R^(A87) H CD₃ H H H
 273. H R^(A88) H CD₃ H H H
 274. H R^(A89) H CD₃ H H H
 275. H R^(A90) H CD₃ H H H
 276. H R^(A91) H CD₃ H H H
 277. H R^(A92) H CD₃ H H H
 278. H R^(A93) H CD₃ H H H
 279. CD₃ R^(A1) H CD₃ H H H
 280. CD₃ R^(A2) H CD₃ H H H
 281. CD₃ R^(A3) H CD₃ H H H
 282. CD₃ R^(A4) H CD₃ H H H
 283. CD₃ R^(A5) H CD₃ H H H
 284. CD₃ R^(A6) H CD₃ H H H
 285. CD₃ R^(A7) H CD₃ H H H
 286. CD₃ R^(A8) H CD₃ H H H
 287. CD₃ R^(A9) H CD₃ H H H
 288. CD₃ R^(A10) H CD₃ H H H
 289. CD₃ R^(A11) H CD₃ H H H
 290. CD₃ R^(A12) H CD₃ H H H
 291. CD₃ R^(A13) H CD₃ H H H
 292. CD₃ R^(A14) H CD₃ H H H
 293. CD₃ R^(A15) H CD₃ H H H
 294. CD₃ R^(A16) H CD₃ H H H
 295. CD₃ R^(A17) H CD₃ H H H
 296. CD₃ R^(A18) H CD₃ H H H
 297. CD₃ R^(A19) H CD₃ H H H
 298. CD₃ R^(A20) H CD₃ H H H
 299. CD₃ R^(A21) H CD₃ H H H
 300. CD₃ R^(A22) H CD₃ H H H
 301. CD₃ R^(A23) H CD₃ H H H
 302. CD₃ R^(A24) H CD₃ H H H
 303. CD₃ R^(A25) H CD₃ H H H
 304. CD₃ R^(A26) H CD₃ H H H
 305. CD₃ R^(A27) H CD₃ H H H
 306. CD₃ R^(A28) H CD₃ H H H
 307. CD₃ R^(A29) H CD₃ H H H
 308. CD₃ R^(A30) H CD₃ H H H
 309. CD₃ R^(A31) H CD₃ H H H
 310. CD₃ R^(A32) H CD₃ H H H
 311. CD₃ R^(A33) H CD₃ H H H
 312. CD₃ R^(A34) H CD₃ H H H
 313. CD₃ R^(A35) H CD₃ H H H
 314. CD₃ R^(A36) H CD₃ H H H
 315. CD₃ R^(A37) H CD₃ H H H
 316. CD₃ R^(A38) H CD₃ H H H
 317. CD₃ R^(A39) H CD₃ H H H
 318. CD₃ R^(A40) H CD₃ H H H
 319. CD₃ R^(A41) H CD₃ H H H
 320. CD₃ R^(A42) H CD₃ H H H
 321. CD₃ R^(A43) H CD₃ H H H
 322. CD₃ R^(A44) H CD₃ H H H
 323. CD₃ R^(A45) H CD₃ H H H
 324. CD₃ R^(A46) H CD₃ H H H
 325. CD₃ R^(A47) H CD₃ H H H
 326. CD₃ R^(A48) H CD₃ H H H
 327. CD₃ R^(A49) H CD₃ H H H
 328. CD₃ R^(A50) H CD₃ H H H
 329. CD₃ R^(A51) H CD₃ H H H
 330. CD₃ R^(A52) H CD₃ H H H
 331. CD₃ R^(A53) H CD₃ H H H
 332. CD₃ R^(A54) H CD₃ H H H
 333. CD₃ R^(A55) H CD₃ H H H
 334. CD₃ R^(A56) H CD₃ H H H
 335. CD₃ R^(A57) H CD₃ H H H
 336. CD₃ R^(A58) H CD₃ H H H
 337. CD₃ R^(A59) H CD₃ H H H
 338. CD₃ R^(A60) H CD₃ H H H
 339. CD₃ R^(A61) H CD₃ H H H
 340. CD₃ R^(A62) H CD₃ H H H
 341. CD₃ R^(A63) H CD₃ H H H
 342. CD₃ R^(A64) H CD₃ H H H
 343. CD₃ R^(A65) H CD₃ H H H
 344. CD₃ R^(A66) H CD₃ H H H
 345. CD₃ R^(A67) H CD₃ H H H
 346. CD₃ R^(A68) H CD₃ H H H
 347. CD₃ R^(A69) H CD₃ H H H
 348. CD₃ R^(A70) H CD₃ H H H
 349. CD₃ R^(A71) H CD₃ H H H
 350. CD₃ R^(A72) H CD₃ H H H
 351. CD₃ R^(A73) H CD₃ H H H
 352. CD₃ R^(A74) H CD₃ H H H
 353. CD₃ R^(A75) H CD₃ H H H
 354. CD₃ R^(A76) H CD₃ H H H
 355. CD₃ R^(A77) H CD₃ H H H
 356. CD₃ R^(A78) H CD₃ H H H
 357. CD₃ R^(A79) H CD₃ H H H
 358. CD₃ R^(A80) H CD₃ H H H
 359. CD₃ R^(A81) H CD₃ H H H
 360. CD₃ R^(A82) H CD₃ H H H
 361. CD₃ R^(A83) H CD₃ H H H
 362. CD₃ R^(A84) H CD₃ H H H
 363. CD₃ R^(A85) H CD₃ H H H
 364. CD₃ R^(A86) H CD₃ H H H
 365. CD₃ R^(A87) H CD₃ H H H
 366. CD₃ R^(A88) H CD₃ H H H
 367. CD₃ R^(A89) H CD₃ H H H
 368. CD₃ R^(A90) H CD₃ H H H
 369. CD₃ R^(A91) H CD₃ H H H
 370. CD₃ R^(A92) H CD₃ H H H
 371. CD₃ R^(A93) H CD₃ H H  H.


13. An organic light emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:

wherein R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution; wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″; wherein R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any substitutions are optionally joined or fused into a ring; wherein n is 1 or 2; wherein R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof; and wherein R has at least five carbon atoms.
 14. The OLED of claim 13, wherein R has at least six carbon atoms.
 15. The OLED of claim 13, wherein R has at least seven carbon atoms.
 16. The OLED of claim 13, wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
 17. The OLED of claim 13, wherein the organic layer further comprises a host, wherein the host is selected from the group consisting of:

and combinations thereof.
 18. The OLED of claim 13, wherein the organic layer further comprises a host, wherein the host comprises a metal complex.
 19. A consumer product comprising an organic light-emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:

wherein R¹, R², R³, R⁴, and R⁵ each independently represents mono, to a maximum possible number of substitutions, or no substitution; wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″; wherein R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any substitutions are optionally joined or fused into a ring; wherein n is 1 or 2; wherein R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof; and wherein R has at least five carbon atoms.
 20. The consumer product of claim 19, wherein the consumer product is one of a flat panel display, a curved display, a computer monitor, a medical monitor, OLEDs used in photodynamic therapy, near IR (NIR) OLEDs, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a rollable display, a foldable display, a stretchable display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, or a sign. 